The Chemistry of Organic Silicon Compounds, Volume 2

Copyright © 1998 John Wiley & Sons, Ltd

The Chemistry of Organic Silicon Compounds, Volume 2

Editor(s): Zvi Rappoport, Yitzhak Apeloig

Published Online: 7 OCT 2003

Print ISBN: 9780471967576

Online ISBN: 9780470857250

DOI: 10.1002/0470857250

Series Editor(s): Zvi Rappoport

About this Book

Product Information

About The Product

Organosilicon compounds are key organometallic compounds (R-Si) which have many uses in materials science and in metallurgy. Their applications include the synthesis of sugars and in the synthesis of organic compounds for the pharmaceutical industry. This volume will contain both updated chapters on key topics included in the original volumes as well as a number of new chapters reflecting the rapid developments made in silicon chemistry and its applications to organometallic chemistry, materials science, and semiconductors, over the last five years. As for the majority of volumes in this series, chapters will be prepared by leading scientists in the field.

This volume is now available in electronic format from Books Online. 

Table of contents

    1. You have free access to this content
      Front Matter (pages i–xxiii)

    2. Chapter 1

      Theoretical Aspects and Quantum Mechanical Calculations of Silaaromatic Compounds (pages 1–101)

      Yitzhak Apeloig and Miriam Karni

    3. Chapter 2

      A Molecular Modeling of the Bonded Interactions of Crystalline Silica (pages 103–118)

      G. V. Gibbs and M. B. Boisen

    4. Chapter 3

      Polyhedral Silicon Compounds (pages 119–152)

      Akira Sekiguchi and Shigeru Nagase

    5. Chapter 4

      Thermochemistry (pages 153–180)

      Rosa Becerra and Robin Walsh

    6. Chapter 5

      The Structural Chemistry of Organosilicon Compounds (pages 181–265)

      Menahem Kaftory, Moshe Kapon and Mark Botoshansky

    7. Chapter 6

      29Si NMR Spectroscopy of Organosilicon Compounds (pages 267–354)

      Yoshito Takeuchi and Toshio Takayama

    8. Chapter 7

      Activating and Directive Effects of Silicon (pages 355–430)

      Alan R. Bassindale, Simon J. Glynn and Peter G. Taylor

    9. Chapter 8

      Steric Effects of Silyl Groups (pages 431–494)

      R. Jih-Ru Hwu, Shwu-Chen Tsay and Buh-Luen Cheng

    10. Chapter 9

      Reaction Mechanisms of Nucleophilic Attack at Silicon (pages 495–511)

      Alan R. Bassindale, Simon J. Glynn and Peter G. Taylor

    11. Chapter 10

      Silicenium Ions: Quantum Chemical Computations (pages 513–555)

      Christoph Maerker and Paul von Ragué Schleyer

    12. Chapter 11

      Silicenium Ions—Experimental Aspects (pages 557–594)

      Paul D. Lickiss

    13. Chapter 12

      Silyl-Substituted Carbocations (pages 595–701)

      Hans-Ullrich Siehl and Thomas Müller

    14. Chapter 13

      Silicon-Substituted Carbenes (pages 703–778)

      Gerhard Maas

    15. Chapter 14

      Alkaline and Alkaline Earth Silyl Compounds—Preparation and Structure (pages 779–825)

      Johannes Belzner and Uwe Dehnert

    16. Chapter 15

      Mechanism and Structures in Alcohol Addition Reactions of Disilenes and Silenes (pages 827–855)

      Hideki Sakurai

    17. Chapter 16

      Silicon–Carbon and Silicon–Nitrogen Multiply Bonded Compounds (pages 857–1062)

      Thomas Müller, Wolfgang Ziche and Norbert Auner

    18. Chapter 17

      Recent Advances in the Chemistry of Silicon–Heteroatom Multiple Bonds (pages 1063–1103)

      Norihiro Tokitoh and Renji Okazaki

    19. Chapter 18

      Gas-Phase Ion Chemistry of Silicon-Containing Molecules (pages 1105–1142)

      Norman Goldberg and Helmut Schwarz

    20. Chapter 19

      Matrix Isolation Studies of Silicon Compounds (pages 1143–1185)

      Günther Maier, Andreas Meudt, Jörg Jung and Harald Pacl

    21. Chapter 20

      Electrochemistry of Organosilicon Compounds (pages 1187–1232)

      Toshio Fuchigami

    22. Chapter 21

      The Photochemistry of Organosilicon Compounds (pages 1233–1310)

      A. G. Brook

    23. Chapter 22

      Mechanistic Aspects of the Photochemistry of Organosilicon Compounds (pages 1311–1337)

      Mitsuo Kira and Takashi Miyazawa

    24. Chapter 23

      Hypervalent Silicon Compounds (pages 1339–1445)

      Daniel Kost and Inna Kalikhman

    25. Chapter 24

      Silatranes and Their Tricyclic Analogs (pages 1447–1537)

      Vadim Pestunovich, Svetlana Kirpichenko and Mikhail Voronkov

    26. Chapter 25

      Tris(trimethylsilyl)silane in Organic Synthesis (pages 1539–1579)

      C. Chatgilialoglu, C. Ferreri and T. Gimisis

    27. Chapter 26

      Recent Advances in the Direct Process (pages 1581–1597)

      Larry N. Lewis

    28. Chapter 27

      Acyl Silanes (pages 1599–1665)

      Philip C. Bulman Page, Michael J. McKenzie, Sukhbinder S. Klair and Stephen Rosenthal

    29. Chapter 28

      Recent Synthetic Applications of Organosilicon Reagents (pages 1667–1685)

      Ernest W. Colvin

    30. Chapter 29

      Recent Advances in the Hydrosilylation and Related Reactions (pages 1687–1792)

      Iwao Ojima, Zhaoyang Li and Jiawang Zhu

    31. Chapter 30

      Synthetic Applications of Allylsilanes and Vinylsilanes (pages 1793–1868)

      Tien-Yau Luh and Shiuh-Tzung Liu

    32. Chapter 31

      Chemistry of Compounds with Silicon–Sulphur, Silicon–Selenium and Silicon–Tellurium Bonds (pages 1869–1894)

      D. A. (‘Fred’) Armitage

    33. Chapter 32

      Cyclic Polychalcogenide Compounds with Silicon (pages 1895–1928)

      Nami Choi and Wataru Ando

    34. Chapter 33

      Organosilicon Derivatives of Fullerenes (pages 1929–1960)

      Wataru Ando and Takahiro Kusukawa

    35. Chapter 34

      Group 14 Metalloles, Ionic Species and Coordination Compounds (pages 1961–2036)

      Jacques Dubac, Christian Guérin and Philippe Meunier

    36. Chapter 35

      Transition-Metal Silyl Complexes (pages 2037–2128)

      Moris S. Eisen

    37. Chapter 36

      Cyclopentadienyl Silicon Compounds (pages 2129–2175)

      Peter Jutzi

    38. Chapter 37

      Recent Advances in the Chemistry of Cyclopolysilanes (pages 2177–2216)

      Edwin Hengge and Harald Stüger

    39. Chapter 38

      Recent Advances in the Chemistry of Siloxane Polymers and Copolymers (pages 2217–2244)

      Robert Drake, Iain MacKinnon and Richard Taylor

    40. Chapter 39

      Si-Containing Ceramic Precursors (pages 2245–2316)

      R. M. Laine and A. Sellinger

    41. Chapter 40

      Organo-Silica Sol–Gel Materials (pages 2317–2362)

      David Avnir, Lisa C. Klein, David Levy, Ulrich Schubert and Anna B. Wojcik

    42. Chapter 41

      Chirality in Bioorganosilicon Chemistry (pages 2363–2400)

      Reinhold Tacke and Stephan A. Wagner

    43. Chapter 42

      Highly Reactive Small-Ring Monosilacycles and Medium-Ring Oligosilacycles (pages 2401–2461)

      Wataru Ando and Yoshio Kabe

    44. Chapter 43

      Silylenes (pages 2463–2568)

      Peter P. Gaspar and Robert West

    45. You have free access to this content
      Author Index (pages 2569–2720)

    46. You have free access to this content
      Subject Index (pages 2721–2758)

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