Handbook of Free Radical Initiators

Copyright © 2003 John Wiley & Sons, Inc. All rights reserved.

Handbook of Free Radical Initiators

Author(s): E. T. Denisov, T. G. Denisova, T. S. Pokidova

Published Online: 28 JAN 2005

Print ISBN: 9780471207535

Online ISBN: 9780471721475

DOI: 10.1002/0471721476

About this Book

Product Information

About The Product

Free radical initiators-chemical molecules which easily decompose into free radicals-serve as reactive intermediates in synthetic methodologies such as organic and polymer synthesis as well as in technological processes, oligomerization, network formation, and kinetic research. The Handbook of Free Radical Initiators presents an up-to-date account of the physicochemical data on radical initiators and reactions of radical generation. Individual chapters include:

  • Dialkyl Peroxides and Hydroperoxides
  • Diacyl Peroxides, Peresters, and Organic Polyoxides
  • Azo-Compounds
  • Bimolecular Reactions of Free Radical Generation by Ozone, Dioxygen, Hydroperoxides, and Haloid Molecules
  • Free Radical Abstraction Reactions
  • Free Radical Addition Reactions
  • Free Radical Recombination and Disproportoination Reactions

Professionals and academic researchers in chemical engineering, pharmaceuticals, biotechnology, plastics, and rubbers will find the Handbook of Free Radical Initiators to be a distinguished, vital resource.

Table of contents

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      Frontmatter (pages i–xxii)

  2. Part I: Initiators

    1. Mechanisms of Decomposition of Initiators (pages 1–15)

    1. Cage Effect (pages 17–40)

    1. Methods of Study of Initiator Decomposition and Free Radical Generation (pages 41–60)

    1. Dialkyl Peroxides and Hydroperoxides (pages 61–127)

    1. Diacyl Peroxides, Peroxy Esters, Polyatomic, and Organometallic Peroxides (pages 129–282)

    1. Organic Polyoxides (pages 283–302)

    1. Azo Compounds (pages 303–358)

    1. Compounds with Weak C[BOND]C, N[BOND]N, C[BOND]N, and N[BOND]O Bonds (pages 359–419)

  10. Part II: Bimolecular Reactions of Free Radical Generation

    1. Parabolic Model of Bimolecular Homolytic Reaction (pages 421–478)

    1. Bimolecular and Trimolecular Reactions of Free Radical Generation by Dioxygen (pages 479–501)

    1. Bimolecular Reactions of Free Radical Generation by Ozone (pages 503–523)

    1. Bimolecular Reactions of Hydroperoxides with Free Radical Generation (pages 525–545)

    1. Free Radical Generation by Olefins (pages 547–564)

    1. Initiation by Haloid Molecules and Nitrogen Dioxide (pages 565–589)

    1. Free Radical Generation by Reactions of Ions with Molecules (pages 591–653)

  17. Part III: Reactions of Free Radicals

    1. Isomerization and Decomposition of Free Radicals (pages 655–718)

    1. Free Radical Abstraction Reactions (pages 719–756)

    1. Free Radical Reactions for Hydrogen Transfer and Substitution (pages 757–779)

    1. Free Radical Addition (pages 781–815)

    1. Recombination and Disproportionation of Free Radicals (pages 817–848)

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      Index (pages 849–879)

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