Inorganic Syntheses, Volume 6

Copyright © 1960 by McGraw-Hill Book Company, Inc.

Inorganic Syntheses, Volume 6

Editor(s): Eugene G. Rochow

Published Online: 5 JAN 2007

Print ISBN: 9780470131657

Online ISBN: 9780470132371

DOI: 10.1002/9780470132371

About this Book

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About The Product

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.

 

Table of contents

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      Frontmatter (pages i–xi)

  2. Part IA: CHAPTER IA

    1. Potassium Dioxalatocuprate(II) 2-Hydrate (pages 1–2)

      Stanley Kirschner, John A. Mclean and Gerardine Meerman

  3. Part IB: CHAPTER IB

    1. Copper(I) Iodide (pages 3–6)

      George B. Kauffman, Robert P. Pinnell, James Peterson, David Williams and A. L. Allred

    2. Dipyridinesilver(I) Perchlorate (pages 6–8)

      George B. Kauffman, Robert P. Pinnell and Robert D. Stone

  4. Part IIA: CHAPTER IIA

    1. Anhydrous Magnesium Chloride (pages 9–11)

      D. Bryce-Smith and R. M. Hunt

    2. Magnesium Cyclopentadienide (pages 11–15)

      W. A. Barber and William L. Jolly

    3. Crystalline Basic Calcium Orthophosphate (Hydroxyapatite) (pages 16–18)

      A. Perloff, A. S. Posner and Norman E. Miller

    4. Calcium Metal Powder (pages 18–23)

      T. P. Whaley and W. J. Mccreary

    5. Finely Divided Calcium Metal (pages 24–25)

      R. H. Marshall, T. P. Whaley and W. J. Mccreary

  5. Part IIB: CHAPTER IIB

    1. Mercury(II) Chloride Thiourea Complexes (pages 26–30)

      I. Aucken and Russell S. Drago

  6. Part III: CHAPTER III

    1. Gallium(III) Bromide (pages 31–33)

      N. N. Greenwood, I. J. Worrall, T. C. Ichniowski, A. Martin and Alan F. Clifford

    2. Gallium(I) Tetrabromogallate(III) (pages 33–36)

      N. N. Greenwood, I. J. Worrall, T. C. Ichniowski, A. Martin and Alan F. Clifford

  7. Part IVA: CHAPTER IVA

    1. Halomethyl Derivatives of Silicon, Germanium, and Tin by the Diazomethane Method (pages 37–42)

      Dietmar Seyferth, Eugene G. Rochow, Julian B. Honeycutt and Robert C. Bryan

    2. The Diazotization of Thiosemicarbazide and 4-Alkyl and 4-Aryl Thiosemicarbazides (pages 42–46)

      Eugene Lieber, C. N. Pillai, Edwin Oftedahl, Ralph D. Hites and J. A. Chandler

  8. Part IVB: CHAPTER IVB

    1. Refractory Metal Powders (pages 47–50)

      T. P. Whaley and W. J. Mccreary

    2. Cesium Titanium Alum (pages 50–51)

      Burl E. Bryant, Edward Paul, L. A. Hiller and Ernesto Giesbrecht

    3. Titanium(III) Chloride (pages 52–56)

      T. R. Ingraham, K. W. Downes, P. Marier, Z. Z. Hugus and Stanley Steiger

    4. Titanium(III) Chloride and Titanium(III) Bromide (pages 57–61)

      J. M. Sherfey and Rolf B. Johannesen

  9. Part VA: CHAPTER VA

    1. Tetrazolone (pages 62–65)

      Eugene Lieber, Taskashi Enkoji and Raymond C. Burrows

    2. Metal Biguanide Complexes (pages 65–68)

      Priyadaranjan Rây and W. Conard Fernelius

    3. Chromium(III) Biguanide Complexes (pages 68–71)

      Priyadaranjan Rây and W. Conard Fernelius

    4. Tris(1-Phenylbiguanide)cobalt(III) Salts (pages 71–74)

      Priyadaranjan Rây and W. Conard Fernelius

    5. Ethylenebisbiguanidesilver(III) Compounds (pages 74–79)

      Priyadaranjan Rây, W. Conard Fernelius and Sam N. Holter

    6. Trimetaphosphimic Acid (pages 79–80)

      Morris L. Nielsen and Oscar T. Quimby

    7. Anhydrous Deuterophosphoric Acid (pages 81–84)

      N. N. Greenwood, A. Thompson, Henry F. Holtzclaw, Gordon A. Gallup and Jack L. Swanson

    8. Phosphorus(III) Cyanide (pages 84–87)

      P. A. Staats, H. W. Morgan and Harvey M. Cohen

    9. Tri-n-Butylphosphine (pages 87–90)

      George B. Kauffman, Larry A. Teter and E. O. Brimm

    10. An Improved All-Glass Apparatus for the Preparation of Phosphonium Iodide (pages 91–94)

      Nicky Beredjick and Kirby Scherer

    11. Trimeric Phosphonitrile Chloride and Tetrameric Phosphonitrile Chloride (pages 94–97)

      Morris L. Nielsen, Garland Cranford and Oscar T. Quimby

    12. Tripotassium Trimetaphosphimate (pages 97–98)

      Morris L. Nielsen, T. J. Morrow and Oscar T. Quimby

    13. Trisodium Trimetaphosphimate 1-Hydrate (page 99)

      Morris L. Nielsen, T. J. Morrow and Oscar T. Quimby

    14. Disodium Monoamidophosphate (Disodium Phosphoramidate) (pages 100–101)

      R. Klement and Oscar T. Quimby

    15. Tetrasodium Imidodiphosphate (pages 101–103)

      R. Klement and Oscar T. Quimby

    16. Pentasodium Diimidotriphosphate 6-Hydrate (pages 104–108)

      O. T. Quimby, A. Narath and Robert L. Gerteis

    17. Phosphoryl Triamide PO(NH2)3 (pages 108–111)

      R. Klement and Morris L. Nielsen

    18. Thiophosphoryl Triamide PS(NH2)3 (pages 111–112)

      R. Klement and Morris L. Nielsen

    19. Methyldiiodoarsine (pages 113–115)

      I. T. Millar, H. Heaney, D. M. Heinekey, W. Conard Fernelius, Ludwig Maier and E. G. Rochow

    20. Dimethyliodoarsine (pages 116–118)

      I. T. Millar, H. Heaney, D. M. Heinekey, W. Conard Fernelius, Ludwig Maier and E. G. Rochow

  10. Part VB: CHAPTER VB

    1. Vanadium Oxytrichloride (pages 119–120)

      Rolf B. Johannesen, Guy H. Dority and J. Brown Goehring

  11. Part VIA: CHAPTER VIA

    1. Anhydrous Deuterosulfuric Acid (pages 121–123)

      N. N. Greenwood, A. Thompson, Henry F. Holtzclaw, Robert H. Harris and Lawrence Rakestraw

    2. Sulfur Nitrides (pages 123–128)

      Margot Becke-Goehring, William L. Jolly, Ulrich De La Camp, James D. Macomber and H. Fritz Woeller

  12. Part VIB: CHAPTER VIB

    1. Anhydrous Chromium(III) Chloride (pages 129–132)

      A. Vavoulis, T. E. Austin, S. Y. Tyree, Charles W. Hoppesch and R. J. Trimble

    2. Bisbenzenechromium(0) and Bisbenzenechromium(I) Iodide (pages 132–137)

      E. O. Fischer and Roy Pruett

    3. Chloropentamminechromium(III) Chloride (pages 138–141)

      G. Schlessinger, Richard L. South and Mark M. Chamberlain

    4. Chromium(III) O,O′-Diethyl Dithiophosphate (pages 142–143)

      David E. Coldbery, W. Conard Fernelius, Maurice Shamma, F. P. Dwyer, J. W. Hogarth and I. K. Reid

    5. Preparation of Labile Compounds Under Protective Conditions. Chromium(II) Salts (pages 144–146)

      Maksymikian Kranz, Anna Witkowska and John T. Yoke

    6. Molybdenum(VI) Dioxyacetylacetonate (pages 147–148)

      W. Conard Fernelius, Kazuji Terada, Burl E. Bryant, Mary L. Mcgowan and Robert West

    7. Tripotassium Enneachloroditungstate(III) and Pentapotassium Tetradecachlorotritungstate(III) (pages 149–154)

      Robert A. Laudise, Ralph C. Young and Ronn N. Minnê

  13. Part VIIA: CHAPTER VIIA

    1. Carbonyl Fluoride (pages 155–158)

      M. W. Farlow, E. H. Man, C. W. Tullock and Ronald D. Richardson

    2. Sulfuryl Fluoride (pages 158–161)

      E. L. Muetterties and Ronald D. Richardson

    3. Thionyl Fluoride (pages 162–163)

      W. C. Smith, E. L. Muetterties, J. D. Park and Robert Settine

  14. Part VIIB: CHAPTER VIIB

    1. Manganese(II) Acetylacetonate (pages 164–166)

      Robert G. Charles, Sam N. Holter and W. Conard Fernelius

    2. Potassium Nitridorhenate(VII) (pages 167–169)

      A. F. Clifford, R. R. Olsen, Soter G. Kokalis and Therald Moeller

  15. Part VIII: CHAPTER VIII

    1. Potassium Dithioferrate(III) (pages 170–172)

      John L. Deutsch, Hans B. Jonassen and R. F. Trimble

    2. Iron(II) Chloride (pages 172–173)

      Peter Kovacic, Neal O. Brace, T. M. Stanley, David Williams and A. L. Allred

    3. Carbonatotetramminecobalt(III) Nitrate (pages 173–175)

      G. Schlessinger, John W. Simmons, Gerhardt Jabs and Mark M. Chamberlain

    4. Tris[tetrammine-μ-dihydroxo-cobalt(III)]cobalt(III) Sulfate 4-Hydrate (pages 176–179)

      George B. Kauffman, Robert P. Pinnell, Jack K. Crandall and William L. Jolly

    5. Dichloroaquotriamminecobalt(III) Chloride (pages 180–182)

      G. Schlessinger, John Stuehr and Mark M. Chamberlain

    6. Resolution of the Tris(ethylenediamine)cobalt(III) Ion (pages 183–186)

      J. A. Broomhead, F. P. Dwyer, J. W. Hogarth and Robert E. Sievers

    7. Dextro-Tris(ethylenediamine)cobalt(III) Iodide by a Partial Asymmetric Synthesis (pages 186–188)

      J. A. Broomhead, F. P. Dwyer, J. W. Hogarth and Ronald D. Archer

    8. Trinitrotriamminecobalt(III) (pages 189–191)

      G. Schlessinger, Wilma Faye Barker and Mark M. Chamberlain

    9. Resolution of the Ethylenediaminetetraacetatocobaltate(III) Ion (pages 192–194)

      F. P. Dwyer, F. L. Garvan and Stanley Kirschner

    10. Resolution of cis-Dinitrobis(ethylenediamine)cobalt Ion (pages 195–197)

      F. P. Dwyer, F. L. Garvan and Stanley Kirschner

    11. Bis(ethylenediamine)nickel(II) Chloride (pages 198–199)

      Harold M. State, F. P. Dwyer, I. K. Reid and J. W. Hogarth

    12. Tris(ethylenediamine)nickel(II) Chloride 2-Hydrate Tris(Propylenediamine)Nickel(II) Chloride 2-Hydrate (pages 200–201)

      Harold M. State, I. K. Reid and F. P. Dwyer

    13. Tetrakis[phosphorus(III) Chloride] (pages 201–204)

      W. C. Smith and E. O. Brimm

    14. Nitrido Osmium Compounds (pages 204–208)

      A. F. Clifford, C. S. Kobayashi, J. Wuller and Therald Moeller

    15. Platinum(II) Chloride (pages 209–210)

      Alvin J. Cohen and B. A. Ferrone

    16. cis- and trans-Dichlorobis(Diethyl Sulfide)Platinum(II) (pages 211–215)

      George B. Kauffman, Dwaine O. Cowan, F. P. Dwyer, J. W. Hogarth and A. M. Sargeson

    17. Metal-Diolefin Coordination Compounds (pages 216–219)

      John R. Doyle, Phillip E. Slade, Hans B. Jonassen and Richard N. Rhoda

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      Index of Contributers (pages 221–222)

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      Subject Index (pages 223–253)

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      Formula Index (pages 255–272)

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