Inorganic Syntheses, Volume 13

Copyright © 1972 by McGraw-Hill, Inc.

Inorganic Syntheses, Volume 13

Editor(s): F. A. Cotton

Published Online: 5 JAN 2007

Print ISBN: 9780470131725

Online ISBN: 9780470132449

DOI: 10.1002/9780470132449

About this Book

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About The Product

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.

Table of contents

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      Frontmatter (pages i–xvii)

  2. Part I: Chapter one COMPOUNDS OF THE NONTRANSITION ELEMENTS

    1. Perbromic Acid and Potassium Perbromate (pages 1–9)

      Evan H. Appelman and John R. Brand

    2. α-Sulfanuric Chloride—Cyclic Trimer (1,3,5-Trichloro-1 H,3H,5H-1,3,5,2,4,6-Trithiatriazine 1,3,5-Trioxide) (pages 9–13)

      Therald Moeller, Tiao-Hsu Chang, Akira Ouchi, Antonio Vandi, Amedeo Failli and W. E. Hill

    3. Arsine and Arsine-d3 (pages 14–17)

      John E. Drake, Chris Riddle, John R. Webster and William L. Jolly

    4. Ammonium Cyanate (pages 17–20)

      Rodger B. Baird, Robert P. Pinnell, A. L. Allred, D. V. Stynes and D. L. Diemante

    5. Phosphorus (III) Isocyanate Phosphorus Triisocyanate (pages 20–23)

      Robert E. Zobel, Robert P. Pinnell, Mary F. Swiniarski and Robert R. Holmes

    6. Phosphoramidic Acid and its Salts (pages 23–26)

      R. C. Sheridan, J. F. Mccullough, Z. T. Wakefield, H. R. Allcock and E. J. Walsh

    7. Diphenyl (Trimethylsilyl) Phosphine and Dimethyl (Trimethylsilyl) Phosphine (pages 26–32)

      R. Goldsberry, Kim Cohn, M. F. Hawthorne, G. B. Dunks and R. J. Wilson

    8. Exchange Reactions for the Syntheses of Phenylboron Chlorides and Tetrafluoromethylphosphorane (pages 32–41)

      P. M. Treichel, J. Benedict, Ruth Goodrich Haines, B. Gassenheimer and T. Wartik

    9. 2,4,6-Trichloroborazine (pages 41–43)

      D. T. Haworth, W. G. Peet and E. L. Muetterties

    10. 2,4,6-Trichloro-1,3,5-Trimethylborazine (pages 43–45)

      D. T. Haworth, W. G. Peet and E. L. Muetterties

  3. Part II: Chapter two ORGANOMETALLIC COMPOUNDS

    1. Cyclic-Diolefin Complexes of Platinum and Palladium (pages 47–55)

      D. Drew, J. R. Doyle and Alan G. Shaver

    2. Cationic Diene Complexes of Palladium (II) and Platinum (II) (pages 55–65)

      D. A. White, J. R. Doyle and H. Lewis

    3. Trichloro-, Trimethyl-, and Trifluorosilylcobalt Tetracarbonyl: [Tetracarbonyl(Trichloro-, Trifluoro-, and Trimethyl-Silyl)Cobalt Complexes] (pages 65–73)

      David L. Morrison, Arnulf P. Hagen, N. Viswanathan and C. H. Van Dyke

    4. Isoleptic Allyl Derivatives of Various Metals (pages 73–79)

      S. O'Brien, M. Fishwick, B. Mcdermott, M. G. H. Wallbridge, G. A. Wright, G. W. Parshall and E. R. Wonchoba

  4. Part III: Chapter three COMPOUNDS CONTAINING METAL-TO-METAL BONDS

    1. Rhenium and Molybdenum Compounds Containing Quadruple Bonds (pages 81–89)

      Alicia B. Brignole, F. A. Cotton, Z. Dori, Z. Dori, Z. Dori and G. Wilkinson

    2. Tetrakis (Acetato) Dirhodium (II) and Similar Carboxylato Compounds (pages 90–91)

      G. A. Rempel, P. Legzdins, H. Smith, G. Wilkinson and D. A. Ucko

    3. Dodecacarbonyltriruthenium and -Triosmium (pages 92–95)

      Brian F. G. Johnson, Jack Lewis and C. W. Bradford

    4. Dodecacarbonyltetrairidium (pages 95–99)

      L. Malatesta, G. Caglio, M. Angoletta, E. M. Kaiser and M. F. Farona

    5. Disodium Hexaalkoxy-Octa-μ3-Chloro-Hexamolybdates (pages 99–103)

      Piero Nannelli, B. P. Block, D. Lissy and B. B. Wayland

  5. Part IV: Chapter four PHOSPHINE AND PHOSPHITE COMPLEXES OF LOW-VALENT METALS

    1. Triaryl Phosphite Complexes of Cobalt, Nickel, Platinum, and Rhodium (pages 105–112)

      J. J. Levison, S. D. Robinson and J. G. Verkade

    2. Tetrakis(Triethyl Phosphite) Nickel (0), Palladium (0), and Platinum (0) Complexes (pages 112–117)

      Max Meier, Fred Basolo, W. R. Kroll, D. Moy and M. G. Romanelli

    3. Low-Valent Metal Complexes of Diethyl Phenylphosphonite (pages 117–121)

      D. Titus, A. A. Orio, Harry B. Gray, G. W. Parshall and J. J. Mrowca

    4. Tetrakis (Triphenylphosphine) Palladium (0) (pages 121–124)

      D. R. Coulson, L. C. Satek and S. O. Grim

    5. Tetrakis (Triphenylphosphine) Nickel (0) (pages 124–126)

      R. A. Schunn, E. C. Ashby and J. Dilts

    6. Carbonylhydridotris(Triphenyl-Phosphine)Iridium (I) (pages 126–131)

      G. Wilkinson, R. A. Schunn and G. L. Henry

    7. Chlorohydridotris(Triphenylphosphine)-Ruthenium (II) (pages 131–134)

      R. A. Schunn, E. R. Wonchoba and G. Wilkinson

  6. Part V: Chapter five BINARY COMPOUNDS OF THE TRANSITION METALS

    1. Single Crystals of Transition-Metal Dioxides (pages 135–145)

      D. B. Rogers, S. R. Butler, R. D. Shannon, A. Wold and R. Kershaw

    2. Molybdenum (V) Fluoride Molybdenum Pentafluoride (pages 146–150)

      T. J. Ouellette, C. T. Ratcliffe, D. W. A. Sharp, A. M. Steven and F. Schreiner

    3. Tungsten (V) Chloride Tungsten Pentachloride (pages 150–154)

      E. L. , Mccann III, T. M. Brown, C. Djordjevic and R. E. Morris

    4. Anhydrous Nickel (II) Halides and their Tetrakis(Ethanol) and 1,2-Dimethoxyethane Complexes (pages 154–164)

      Laird G. L. Ward and J. R. Pipal

  7. Part VI: Chapter Six HALO COMPLEXES OF SOME METALS

    1. Tetraphenylarsonium Tetrachlorovanadate (III) (pages 165–168)

      A. T. Casey, R. J. H. Clark, R. S. Nyholm, D. E. Scaife, T. E. Boyd, W. Rhine and G. Stucky

    2. Tris (Tetraethylammonium) Nonachlorodivanadate (III) (pages 168–170)

      A. T. Casey, R. J. H. Clark, W. Rhine, T. E. Boyd and G. Stucky

    3. Ammonium, Rubidium, and Cesium Salts of the Aquapentachloromolybdate (III) and Hexachloromolybdate (III) Anions (pages 170–173)

      J. V. Brencic, F. A. Cotton, J. A. Jaecker and R. A. Walton

    4. Disodium Hexachloroplatinate (IV) (pages 173–176)

      Lawrence E. Cox, Dennis G. Peters, J. Halpern and M. Pribanic

  8. Part VII: Chapter Seven VARIOUS TRANSITION-METAL COMPOUNDS

    1. Dichlorotetrakis(2-Propanol)-Vanadium(III) Chloride (pages 177–179)

      A. T. Casey, R. J. H. Clark, T. E. Boyd, W. Rhine and G. Stucky

    2. Trichlorobis(Trimethylamine)Vanadium(III) (pages 179–181)

      A. T. Casey, R. J. H. Clark, K. J. Pidgeon, W. Rhine and G. Stucky

    3. Vanadyl (IV) Acetate, Vo(ch3co2)2 [Bis(Acetato)Oxovanadium(IV)] (pages 181–183)

      Ram Chand Paul, Saroj Bhatia, Ashok Kumar, J. T. Mague and C. W. Weston

    4. Tris(Diamine)Chromium(III) Salts (pages 184–186)

      R. D. Gillard, P. R. Mitchell, D. H. Busch, C. R. Sperati, H. B. Jonassen and C. W. Weston

    5. Bis[cis-1,2-Dicyanoethene-1,2-Dithiolato-(1- or 2-)] Complexes of Cobalt and Iron (pages 187–195)

      J. Bray, J. Locke, J. A. Mccleverty, D. Coucouvanis, J. P. Fackler and R. Jackson

    6. Resolution of the (Ethylenediamine)-Bis (Oxalato)Cobaltate(III) Ion (pages 195–202)

      J. H. Worrell, E. B. Kipp and R. A. Haines

    7. Nitrito Complexes of Nickel(II) and Cobalt(II) (pages 202–207)

      Richard H. Buchi, Laila El-Sayed, Ronald O. Ragsdale, F. Basolo, D. Diemente and D. V. Stynes

    8. Ruthenium Ammines (pages 208–213)

      J. E. Fergusson, J. L. Love and J. N. Armor

    9. Pentaamminechlororhodium (III) Dichloride and Pentaamminehydridorhodium (III) Sulfate (pages 213–215)

      J. A. Osborn, K. Thomas, G. Wilkinson and H. M. Neumann

    10. Dichloro (Ethylenediamine)Palladium(II) and (2,2′-Bipyridine)Dichloropalladium (II) (pages 216–218)

      B. Jack Mccormick, Edgar N. Jaynes, Roy I. Kaplan, H. C. Clark and J. D. Ruddick

    11. Nonahydridorhenate Salts (pages 219–225)

      A. P. Ginsberg, C. R. Sprinkle, J. F. Russell, F. N. Tebbe and E. L. Muetterties

    12. Potassium Hexakis (Isothiocyanato)-Niobate(V) (pages 226–231)

      G. F. Knox, T. M. Brown, W. A. G. Graham and G. O. Evans

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      Index of Contributers (pages 235–237)

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      Subject Index (pages 239–255)

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      Formula Index (pages 257–267)

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