Inorganic Syntheses, Volume 16

Copyright © 1976 by McGraw-Hill, Inc.

Inorganic Syntheses, Volume 16

Editor(s): Fred Basolo

Published Online: 5 JAN 2007

Print ISBN: 9780470131787

Online ISBN: 9780470132470

DOI: 10.1002/9780470132470

About this Book

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About The Product

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.

Table of contents

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      Frontmatter (pages i–xii)

  2. Part 1: chapter One METAL NITROSYL COMPLEXES

    1. Tetranitrosylchromium and Carbonyltrinitrosylmanganese (pages 1–5)

      S. K. Satija, B. I. Swanson and C. E. Strouse

  3. Part 1: Chapter One METAL NITROSYL COMPLEXES

    1. Dithiocarbamate Complexes of Iron and Cobalt Nitrosyls (pages 5–8)

      O. A. Ileperuma, R. D. Feltham and E. D. Johnson

    2. Ammine Complexes of Osmium, Including Amminenitrosyls (pages 9–13)

      F. Bottomley, S. B. Tong, R. O. Harris and N. K. Hota

    3. Nitrosylammineruthenium Complexes (pages 13–16)

      A. F. Schreiner, S. W. Lin, F. Bottomley and M. Mangat

    4. Dinitrosylcobalt Complexes (pages 16–20)

      D. Gwost, K. G. Caulton, J. R. Nappier, O. A. Ileperuma and R. D. Feltham

    5. Bis(Triphenylphosphine)Chlorodinitrosylruthenium(1+) Tetrafluoroborate (pages 21–24)

      J. Reed, C. G. Pierpont, R. Eisenberg and E. D. Johnson

    6. Dicarbonyl-η-Cyclopentadienylnitrosyl-Molybdenum and bis(Dihalo-η-Cyclopentadienylnitrosyl-Molybdenum) Derivatives (pages 24–29)

      D. Seddon, W. G. Kita, J. Bray, J. A. Mccleverty, S. P. Anand and R. B. King

    7. Bis(Methyldiphenylphosphine)Dichloro-Nitrosylcobalt (pages 29–32)

      G. Dolcetti, M. Ghedim, C. A. Reed, T. E. Nappier and R. D. Feltham

    8. Tris(Triphenylphosphine)Nitrosylcobalt and Tris(Triphenylphosphine)Nitrosylrhodium (pages 32–35)

      G. Dolcetti, O. Gandolfi, M. Ghedini, N. W. Hoffman, O. A. Ileperuma, T. E. Nappier and R. D. Feltham

    9. Carbonylchloronitrosylrhenium Compounds (pages 35–38)

      G. Dolcetti, J. R. Norton, M. C. Fredette and C. J. L. Lock

    10. Decacarbonyl-Di-μ-Nitrosyl-Trimetal Compounds (pages 39–41)

      J. R. Norton, G. Dolcetti, B. F. G. Johnson and A. Forster

    11. trans-Bis-(Triphenylphosphine)Chloronitrosyl-Iridium(1+) Tetrafluoroborate (pages 41–43)

      R. J. Fitzgerald, H.-M. W. Lin and B. L. Haymore

  4. Part 2: Chapter Two METAL CARBONYL COMPOUNDS

    1. Dodecacarbonyltriruthenium (pages 45–47)

      B. R. James, G. L. Rempel, W. K. Teo, C. Eady, A. Forster and B. F. G. Johnson

    2. Dodecacarbonyltriruthenium (pages 47–48)

      A. Mantovani, S. Cenini, B. R. James and D. V. Plackett

    3. Hexadecacarbonylhexarhodium (pages 49–51)

      B. R. James, G. L. Rempel, W. K. Teo and G. Caglio

    4. Dicarbonyl(η-Cyclopentadienyl)-(Thiocarbonyl)Manganese(I) (pages 53–55)

      I. S. Butler, N. J. Coville, A. E. Fenster and J. S. Kristoff

    5. Transition Metal Carbonyl Derivatives of Magnesium (pages 56–61)

      G. B. Mcvicker, T. J. Marks and A. M. Seyam

    6. Tris(Pentacarbonylmanganese)-Thallium(III) (pages 61–63)

      A. T. T. Hsieh, M. J. Mays, J. S. Kristoff and D. F. Shriver

    7. (Alkylamino)Difluorophosphine- and Halodifluorophosphinetetracarbonyliron Complexes (pages 63–68)

      D. P. Bauer, W. M. Douglas, J. K. Ruff, P. J. Russo, H. Schäfer and A. G. MacDiarmid

    8. Tris[Bis(2-Methoxyethyl)Ether]Potassium and Tetraphenylarsonium Hexacarbonylmetallates(1–) of Niobium and Tantalum (pages 68–73)

      J. E. Ellis, A. Davison, G. W. Parshall and E. R. Wonchoba

  5. Part 2: chapter Two METAL CARBONYL COMPOUNDS

    1. Di-μ-Chloro-Bis[Tricarbonylchloro-Ruthenium(II)] (pages 51–53)

      A. Mantovani, S. Cenini, R. M. Heintz and D. E. Morris

  6. Part 3: Chapter Three WERNER TYPE METAL COMPLEXES

    1. (Dinitrogen Oxide)Pentaammineruthenium(II) Salts (pages 75–77)

      F. Bottomley and J. N. Armor

    2. Tetrakis(Isothiocyanato)Bis(2,2′-Bipyridine)-Niobium(IV) (pages 78–80)

      J. N. Smith, T. M. Brown, J. B. Hamilton and K. Kirksey

    3. Malonato Complexes of Chromium(III) (pages 80–83)

      J. C. Chang, R. Goddard and J. H. Worrell

    4. Selenoureametal Complexes (pages 83–87)

      G. B. Aitken, G. P. Mcquillan, G. L. Seebach and J. R. Wasson

    5. Nickel Tetrafluorooxovanadate(IV) Heptahydrate (pages 87–89)

      A. Klein, P. Carroll, G. Mitra, J. Selbin, J. H. Nibert and H. J. Sherrill

    6. Polymeric Chromium(III)-bis(Phosphinates) (pages 89–92)

      H. D. Gillman, P. Nannelli, B. P. Block and E. E. Flagg

    7. Resolution of the cis-Bromoamminebis-(Ethylenediamine)Cobalt(III) Ion (pages 93–97)

      G. B. Kauffman, E. V. Lindley, M. P. Granchi and B. E. Douglas

    8. Bis(Alkylphosphine)Trichlorotitanium(III) Complexes (pages 97–102)

      C. H. Kolich, C. D. Schmulbach, J. Towarnicky and E. P. Schram

  7. Part 4: Chapter Four OTHER TRANSITION METAL COMPLEXES

    1. Reagents for the Synthesis of η-Diene Complexes of Tricarbonyliron and Tricarbonylruthenium (pages 103–107)

      A. J. P. Domingos, J. A. S. Howell, B. F. G. Johnson, J. Lewis, N. Grice and R. Pettit

    2. Bis(η-Cyclopentadienyl)Niobium Complexes (pages 107–113)

      C. R. Lucas, J. A. Labinger and J. Schwartz

    3. Dichloro(1,3-Propanediyl)Platinum and trans-Dichlorobis(Pyridine)(1,3-Propanediyl)-Platinum Derivatives (pages 113–116)

      G. W. Littlecott, F. J. Mcquillin, K. G. Powell and S. D. Ittel

    4. Olefin(β-Diketonato)Silver(I) Compounds (pages 117–119)

      W. Partenheimer, E. H. Johnson and H. A. Tayim

    5. Trichloromethyltitanium and Tribromomethyltitanium (pages 120–126)

      R. J. H. Clark, M. A. Coles and P. W. Smith

    6. Ethylenebis(Triphenylphosphine)Palladium(0) and Related Complexes (pages 127–130)

      A. Visser, R. Van Der Linde, R. O. De Jongh, H. Selbeck, M. Molin and G. Wilke

  8. Part 5: Chapter Five MAIN-GROUP AND ACTINIDE COMPOUNDS

    1. Tetraethylammonium, Tetraphenylarsonium, and Ammonium Cyanates and Cyanides (pages 131–137)

      R. L. Dieck, E. J. Peterson, A. Galliart, T. M. Brown, T. Moeller, A. Ruckenstein and J. L. Burmeister

    2. Diindenylmagnesium (pages 137–138)

      K. D. Smith, J. L. Atwood, E. C. Ashby and H. S. Prasad

    3. Fluoromethylsilanes (pages 139–143)

      A. P. Hagen, L. L. Mcamis, D. J. Sepelak and C. H. Van Dyke

    4. Uranium Hexachloride: (Hexachlorouranium) (pages 143–147)

      T. A. O'Donnell, P. W. Wilson and H. J. Hurst

    5. Chlorotris(η-Cyclopentadienyl)Complexes of Uranium(IV) and Thorium(IV) (pages 147–151)

      T. J. Marks, A. M. Seyam, W. A. Wachter, G. W. Halstead and K. N. Raymond

  9. Part 6: Chapter Six LIGANDS USED TO PREPARE METAL COMPLEXES

    1. Trimethylphosphine (pages 153–155)

      R. T. Markham, E. A. Dietz, D. R. Martin, O. Stelzer and R. Schmutzler

    2. Tertiary Phosphines (pages 155–161)

      V. D. Bianco, S. Doronzo, K. J. Reimer, A. G. Shaver, P. Fiess and H. C. Clark

    3. Diphenylphosphine (pages 161–163)

      V. D. Bianco, S. Doronzo, J. Chan and M. A. Bennett

    4. Methyl Difluorophosphite (pages 166–167)

      L. F. Centofanti, L. Lines and R. J. Clark

    5. Bi-, tri-, and Tetradentate Phosphorus-Sulfur Ligands (pages 168–174)

      D. W. Meek, G. Dyer, M. O. Workman, P. S. K. Chia and S. E. Livingstone

    6. Tetradentate Tripod Ligands Containing Nitrogen, Sulfur, Phosphorus, and Arsenic as Donor Atoms (pages 174–180)

      R. Morassi, L. Sacconi, C. A. Mcauliffe and W. Levason

    7. Dimethyl(Pentafluorophenyl)Phosphine and Dimethyl(Pentafluorophenyl)Arsine Ligands (pages 180–184)

      J. L. Peterson, D. W. Meek, D. P. Shah and S. O. Grim

    8. Tris(O-Dimethylarsinophenyl)Arsine and Tris(O-Dimethylarsinophenyl)Stibine (pages 184–188)

      W. Levason, C. A. Mcauliffe, A. I. Plaza and S. O. Grim

    9. Cis-2-Diphenylarsinovinyldiphenylphosphine and 2-Diphenylarsinoethyldiphenylphosphine (pages 188–192)

      W. Levason, C. A. Mcauliffe, R. C. Barth and S. O. Grim

    10. [2-(Isopropylphenylphosphino)Ethyl]-Diphenylphosphine (pages 192–195)

      J. Del Gaudio, S. O. Grim and T. G. Attig

    11. [(Phenylisopropylphosphino)Methyl]-Diphenylphosphine Sulfide (pages 195–197)

      J. D. Mitchell, S. O. Grim and L. Sacconi

    12. N,N,N′,N′-Tetrakis(Diphenylphosphinomethyl)-Ethylenediamine (pages 198–199)

      L. J. Matienzo, S. O. Grim, R. Uriarte and D. W. Meek

    13. Ethylenebis(Nitrilodimethylene)Tetrakis-(Phenylphosphinic Acid) (pages 199–202)

      A. I. Plaza, S. O. Grim, R. J. Motekaitis and A. E. Martell

    14. [2-(Phenylphosphino)Ethyl]Diphenylphosphine (pages 202–206)

      J. C. Cloyd, R. B. King, T. L. Dubois and D. W. Meek

    15. 1,1,1-Trifluoro-4-Mercapto-4-(2-Thienyl)-3-Buten-2-One: 1,1,1-Trifluoro-3-thiothenoylacetone (pages 206–211)

      M. Das, S. E. Livingstone, B. C. Pestel and S. C. Cummings

  10. Part 6: chapter Six LIGANDS USED TO PREPARE METAL COMPLEXES

    1. Tri(Phenyl-D5)Phosphine (pages 164–166)

      V. D. Bianco, S. Doronzo, S. Downie and M. A. Bennett

  11. Part 7: Chapter Seven COMPOUNDS OF BIOLOGICAL INTEREST

    1. Metalloporphyrins (pages 213–220)

      A. D. Adler, F. R. Longo, V. Váradi and R. G. Little

    2. (1,4,8,11-Tetraazacyclotetradecane)Nickel(II) Perchlorate and 1,4,8,11-Tetraazacyclotetradecane (pages 220–225)

      E. K. Barefield, F. Wagner, A. W. Herlinger, A. R. Dahl and S. Holt

    3. N,N′-Ethylenebis(Monothioacetyl-Acetoniminato)Cobalt(II) and Related Metal Complexes (pages 225–228)

      P. R. Blum, R. M. C. Wei, S. C. Cummings, M. Das and S. E. Livingstone

    4. Metallatranes (pages 229–234)

      J. Ochs, M. Zeldin, M. Zeldin, R. Gsell, L. Hill, C. D. Schmulbach, J. Branca, C. D. Schmulbach, R. Scobell, J. L. Darin and T. Ballantine

    5. Cis-Bis(Diethyldithiocarbamato)-Dinitrosylmolybdenum (pages 235–237)

      J. A. Broomhead, J. Budge, W. Grumley and J. W. Mcdonald

    6. Some η-Cyclopentadienyl Complexes of Titanium(III) (pages 237–240)

      C. R. Lucas, M. L. H. Green, B. H. Taylor and F. N. Tebbe

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      Index of Contributers (pages 243–245)

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      Subject Index (pages 247–252)

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      Formula Index (pages 253–257)

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