Inorganic Syntheses, Volume 24

Copyright © 1986 Inorganic Syntheses, Inc.

Inorganic Syntheses, Volume 24

Editor(s): Jean'ne M. Shreeve

Published Online: 5 JAN 2007

Print ISBN: 9780471834410

Online ISBN: 9780470132555

DOI: 10.1002/9780470132555

About this Book

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The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.

Table of contents

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      Frontmatter (pages i–xxii)

  2. Part 1: Chapter One FLUORINE-CONTAINING COMPOUNDS

    1. Chlorine Fluoride (pages 1–3)

      Carl J. Schack, R. D. Wilson and Darryl D. Desmarteau

    2. Chloryl Fluoride (pages 3–6)

      Karl O. Christe, Richard D. Wilson, Carl J. Schack and D. D. Desmarteau

    3. Chlorine Fluorosulfate (pages 6–8)

      Carl J. Schack, Richard D. Wilson and W. Totsch

    4. Sulfur Chloride Pentafluoride (pages 8–10)

      Carl J. Schack, Richard D. Wilson, Michael G. Warner and A. Waterfeld

    5. (Fluorocarbonyl)Imidosulfurous Difluoride (pages 10–12)

      Joseph S. Thrasher and Dieter Lentz

    6. Acyclic Sulfur Nitrogen Fluorine Compounds (pages 12–17)

      Rudiger Mews, Klaus Keller, Oskar Glemser, K. Seppelt and J. Thrasher

    7. Haloimidosulfurous Difluorides, XNSF2 (pages 18–21)

      R. Mews, K. Keller, O. Glemser, K. Seppelt and J. Thrasher

    8. Cesium Fluoroxysulfate (Cesium Fluorine Sulfate) (pages 22–27)

      Evan H. Appelman, Karl O. Christe, Richard D. Wilson and Carl J. Schack

    9. Selenium Tetrafluoride, Selenium Difluoride Oxide (Seleninyl Fluoride), and Xenon Bis[Pentafluorooxoselenate(VI)] (pages 27–31)

      Konrad Seppelt, Dieter Lentz, Gerhard Klöter and Carl J. Schack

    10. Tellurium Chloride Pentafluoride (pages 31–33)

      M. Murchie, J. Passmore and K. Seppelt

    11. Pentafluorooxotellurates(VI) (pages 33–37)

      F. Sladky and Carl J. Schack

    12. Tungsten Tetrafluoride Oxide (pages 37–38)

      William W. Wilson, Karl O. Christe and Roland Bougon

    13. Tetrafluoroammonium Salts (pages 39–48)

      Karl O. Christe, William W. Wilson, Carl J. Schack, Richard D. Wilson and R. Bougon

    14. Cesium Hexfluoromanganate(IV) (pages 48–50)

      William W. Wilson, Karl O. Christe and Roland Bougon

    15. Ammonium Pentafluoromanganate(III) and Potassium Pentafluoromanganate(III) Hydrate (pages 50–52)

      Manabendra N. Bhattacharjee, Mihir K. Chandhuri and Helen M. Marsden

    16. Bis(Trifluoromethyl)Mercury (pages 52–54)

      Reint Eujen, Gerard Gomes and John A. Morrison

    17. Bis(Trifluoromethyl)Cadmium.1,2-Dimethoxyethane (pages 55–58)

      C. D. Ontiveros, J. A. Morrison, R. Hani and R. A. Geanangel

    18. Trifluoromethyl Hypochlorite and Perfluoro-Tert-Butyl Hypochlorite (2,2,2-Trifluoro-1,1-Bis(Trifluoromethyl)Ethyl Hypochlorite) (pages 58–62)

      Fritz Haspel-Hentrich, Jean'ne M. Shreeve, Jo Ann M. Canich and Gary L. Gard

    19. Difluorophosphoranes, Diethyl Phosphorofluoridate, Fluorotriphenylmethane, and N-Fluorodimethylamine (pages 62–67)

      Stanley M. Williamson, O. D. Gupta, Jean'ne M. Shreeve, Megan E. Lerchen and Gary L. Gard

    20. Chromium Difluoride Dioxide (Chromyl Fluoride) (pages 67–69)

      Gary L. Gard and Stanley M. Williamson

    21. Nitryl Hexafluoroarsenate (pages 69–72)

      Michael J. Moran, Joann Milliken, Ronald A. De Marco and Scott A. Kinkead

    22. Tribromosulfur(IV) Hexafluoroarsenate(V) (pages 76–79)

      Mike Murchie, Jack Passmore and Robert C. Thompson

    23. Osmium(VI) Fluoride (pages 79–81)

      Robert C. Burns, Thomas A. O'donnell and Roland Bougon

  3. Part 1: FLUORINE-CONTAINING COMPOUNDS

    1. Silver Hexafluoroarsenate and Bis(Cyclo-Octasulfur)Silver(1+) Hexafluoroarsenate(1-) (pages 72–76)

      Herbert W. Roesky, Michael Witt, K. C. Malhotra and R. J. Gillespie

  4. Part 2: Chapter Two MAIN GROUP COMPOUNDS

    1. Ethylboronic Acid and Tetraethyldiboroxane/Triethylboroxin (3:1) (pages 83–87)

      Roland Köster, Peter Idelmann, Gary M. Edvenson and Donald F. Gaines

    2. Indium(III) Iodide (pages 87–89)

      J. P. Kopasz, R. B. Hallock, O. T. Beachley and W. Rodger Nutt

    3. Tris[(Trimethylsilyl)Methyl]Indium (pages 89–91)

      J. P. Kopasz, R. B. Hallock, O. T. Beachley and R. A. Andersen

    4. Tris[(Trimethylsilyl)Methyl]Aluminum (pages 92–93)

      Claire Tessier-Youngs, O. T. Beachley, John P. Oliver and Kathaleen Butcher

    5. Bromobis[(Trimethylsilyl)Methyl]Aluminum (pages 94–95)

      Claire Tessier-Youngs, O. T. Beachley, John P. Oliver and Kathaleen Butcher

    6. [(Trimethylsilyl)Methyl]Lithium (pages 95–97)

      Claire Tessier-Youngs, O. T. Beachley, John P. Oliver and Kathaleen Butcher

    7. Cyclopentadienylthallium (Thallium Cyclopentadienide) (pages 97–99)

      A. J. Nielson, C. E. F. Rickard, J. M. Smith and Bruce N. Diel

    8. Tetraisocyanatosilane (pages 99–101)

      Joseph S. Thrasher and Dieter Lentz

    9. Dialkyl [(N,N-Diethylcarbamoyl)Methyl]Phosphonates (pages 101–106)

      S. M. Bowen, R. T. Paine and Louis Kaplan

    10. Triphenyl(Trichloromethyl)Phosphonium Chloride and (Dichloromethylene)Triphenylphosphorane (pages 107–109)

      Rolf Appel and Fritz Haspel-Hentrich

    11. [Phenyl(Trimethylsilyl)Methylene]-Phosphinous Chloride [Chloro-[Phenyl(Trimethylsilyl)Methylene]Phosphine] (pages 110–113)

      Rolf Appel, Li-Bei-Li and Robert H. Neilson

    12. Methanetetraylbis(Phosphoranes) (Carbodiphosphoranes) (pages 113–117)

      Rolf Appel and Joseph G. Morse

    13. Bis[Bis(Trimethylsilyl)Methylene]-Chlorophosphorane (pages 117–120)

      Rolf Appel and Robert T. Paine

    14. N,N′-Dimethyl-N,N′-Bis(Trimethylsilyl)Urea (pages 120–121)

      H. W. Roesky, J. Lucas and Arlan D. Norman

    15. 1,3,5,7-Tetramethyl-1H,5H-[1,4,2,3]Diazadiphospholo-[2,3-B][1,4,2,3]Diazadiphosphole-2,6(3H,7H)-Dione and a Molybdenum Complex (pages 122–125)

      H. W. Roesky, J. Lucas and Arland D. Norman

    16. Sulfur Dicyanide (pages 125–126)

      Ramesh C. Kumar, Jean'Ne M. Shreeve and Jerry Foropoulos

    17. Disilyl Selenide (Disilaselenane) (pages 127–129)

      John E. Drake, Boris M. Glavincevski, E. A. V. Ebsworth and S. G. Henderson

    18. Organic Superconducting Solids (pages 130–143)

    19. Methylmercury(II) Nitrate and Methylmercury (II) Trifluoroacetate (pages 143–146)

      Robert D. Bach, Harsha B. Vardhan, Donald W. Goebel and John P. Oliver

  5. Part 3: Chapter Three TRANSITION METAL ORGANOMETALLIC COMPOUNDS

    1. Dicarbonylbis(η5-Cyclopentadienyl) Complexes of Titanium, Zirconium, and Hafnium (pages 147–157)

      David J. Sikora, Kevin J. Moriarty, Marvin D. Rausch, A. Ray Bulls, John E. Bercaw, Vikram D. Patel and Arthur J. Carty

    2. Sodium Carbonyl Ferrates, Na2[Fe(Co)4], Na2[Fe2(Co)8], and Na2[Fe3(Co)11]. Bis[μ-Nitridobis(Triphenylphosphorus)(1+)] Undecacarbonyltriferrate(2-), [(Ph3P)2N]2[Fe3(Co)11] (pages 157–161)

      Henry Strong, Paul J. Krusic, Joseph San Filippo, Scott Keenan and Richard G. Finke

    3. Tricarbonyl (η5-Cyclopentadienyl)Iron(1+)Trifluoromethanesulfonate, [CpFe(CO)3](Cf3So3) (pages 161–163)

      Mono M. Singh, Robert J. Angelici and Colin P. Horwitz

    4. Dicarbonyl(η5-Cyclopentadienyl) (2-Methyl-1-Propenyl-ηKC1)Iron and Dicarbonyl(η5-Cyclopentadienyl)(η2-2-Methyl-1-Propene)Iron(1+) Tetrafluoroborate (pages 163–167)

      Myron Rosenblum, Warren P. Giering, Sari-Beth Samuels and Paul J. Fagan

    5. Tetraethylammonium μ-Carbonyl-1κC:2κC-Decacarbonyl-1κ3C,2κ3C,3κ4C-μ-Hydrido-1κ:2κ-Triangulo-Triruthenate(1–) (pages 168–169)

      Georg Süss-Fink, Nancy Jones, Herbert D. Kaesz and Joseph W. Kolis

    6. Bromo(η5-Cyclopentadienyl)-[1,2-Ethanediylbis(Diphenylphosphine)]Iron and Bromo(η5-Cyclopentadienyl)-[1,2-Ethanediylbis(Diphenylphosphine)]-Bis(Tetrahydrofuran)Ironmagnesium(Fe-Mg) (pages 170–173)

      S. G. Davies, H. Felkin, O. Watts and S. J. Simpson

    7. [η4-1,5-Cyclooctadiene)(Pyridine)-(Tricyclohexylphosphine)Iridium(I)Hexafluorophosphate (pages 173–176)

      Robert H. Crabtree, Sheila M. Morehouse and Jennifer M. Quirk

    8. Tetracarbonyl(η2-Methyl Acrylate)Ruthenium (pages 176–180)

      F.-W. Grevels, J. G. A. Reuvers, J. Takats and B. F. G. Johnson

  6. Part 4: Chapter Four TRANSITION METAL COMPOUNDS AND COMPLEXES

    1. Titanium(II) Chloride (pages 181–182)

      Suraj P. Narula, Hemant K. Sharma and Om Dutt Gupta

    2. Tris(2,2,6,6-Tetramethyl-3,5-Heptanedionato)Chromium(III) (pages 183–184)

      Dale Stille, J. R. Doyle, James E. Finholt and Gretchen E. Mcguire

    3. Cis-Bis(1,2-Ethanediamine)Difluorochromium(III) Iodide (pages 185–187)

      Danny T. Fagan, Joann S. Frigerio, Joe W. Vaughn, Ani Hyslop and James E. Finholt

    4. Organic Intercalated Ionic Ferromagnets of Chromium(II): Bis(Alkylammonium) Tetrachlorochromate(II) Compounds (pages 188–190)

      Carlo Bellitto and Gary L. Gard

    5. Yellow Molybdenum(VI) Oxide Dihydrate (pages 191–192)

      J. B. B. Heyns, J. J. Cruywagen and Scott A. Kinkead

    6. Trichlorotris(Tetrahydrofuran)-Molybdenum(III) (pages 193–194)

      Jonathan R. Dilworth, Jon Zubieta, T. Adrian George and John Smith

    7. Phenylimido Complexes of Tungsten and Rhenium (pages 194–200)

      A. J. Nielson, R. E. Mccarley, S. L. Laughlin and C. D. Carlson

    8. Lithium Insertion Compounds (pages 200–206)

      D. W. Murphy, S. M. Zahurak, C. J. Chen and M. Greenblatt

    9. Dinitrogen Complexes of Iron(II) with (1,2-Ethanediyldinitrilo)Tetraacetate and Trans-(1,2-Cyclohexanediyldinitrilo)Tetraacetate (pages 207–211)

      M. Garcia Basallote, J. M. Lopez Alcala, M. C. Puerta Vizcaino, F. Gonzalez Vilchez, Carrie Woodcock and Duward F. Shriver

    10. Potassium Tetrakis[Dihydrogen Diphosphito(2–)]Diplatinate(II) (pages 211–213)

      K. A. Alexander, S. A. Bryan, M. K. Dickson, D. Hedden, D. M. Roundhill, C.-M. Che, L. G. Butler and H. B. Gray

    11. Ethene Complexes of Bis(Trialkylphosphine)Platinum(0) (pages 213–216)

      R. A. Head, D. M. Roundhill and D. Hedden

    12. Nitrosyl Hexachloroplatinate(IV) (pages 217–220)

      Richard T. Moravek, George B. Kauffman and Tariq Mahmood

    13. Cis-Tetraammine and Cis-Bis (1,2-Ethanediamine) Complexes of Rhodium(III) (pages 220–233)

      Martin Hancock, Bente Nielsen, Johan Springborg, Alan Friedman, P. C. Ford and Michael J. Saliby

    14. μ3-Thio-Trisilver(1+) Nitrate (pages 234–236)

      George B. Kauffman, Günter Bergerhoff, Jane V. Zeile Krevor and Sandra I. Barbour

    15. Carbonylchlorogold(I) (pages 236–238)

      D. Belli Dell'amico, F. Calderazzo, H. H. Murray and J. P. Fackler

    16. Platinum Microcrystals (pages 238–242)

      P. Van Rheenen, M. Mckelvy, R. Marzke, W. S. Glaunsinger and R. Kent Murmann

  7. Part 5: Chapter Five TRIFLUOROMETHANESULFONATES AND TRIFLUOROMETHANESULFONATO-O COMPLEXES

    1. Introduction to Trifluoromethanesulfonates and Trifluoromethanesulfonato-O Complexes (pages 243–250)

      Nicholas E. Dixon, Geoffrey A. Lawrance, Peter A. Lay, Alan M. Sargeson and Henry Taube

    2. Pentaammine(Trifluoromethanesulfonato-O)-Chromium(III) Trifluoromethanesulfonate and Bis(1,2-Ethanediamine)-Bis(Trifluoromethanesulfonato-O) Chromium(III) Trifluoromethanesulfonate (pages 250–252)

      Geoffrey A. Lawrance, Alan M. Sargeson, Andreja Bakac and James H. Espenson

    3. Pentaammine(Trifluoromethanesulfonato-O)Rhodium(III) Trifluoromethanesulfonate, Pentaammineaquarhodium(III) Perchlorate, and Hexaamminerhodium(III) Trifluoromethanesulfonate or Perchlorate (pages 253–256)

      N. E. Dixon, A. M. Sargeson, H. Englehardt and M. Herberhold

    4. Pentaammineruthenium(III), Pentaammineruthenium(II), and Binuclear Decaamminediruthenium(III)/(II) Complexes (pages 257–263)

      Geoffrey A. Lawrance, Peter A. Lay, Alan M. Sargeson, Henry Taube, H. Englehardt and M. Herberhold

    5. Pentaammineiridium(III) and Hexaammineiridium(III) Complexes (pages 263–269)

      Peter A. Lay, Alan M. Sargeson, Frode Galsbøl, Solveig Kallesøe Hansen and Andrew W. Zanella

    6. Pentaammineosmium(III) and Hexaammineosmium(III) Complexes (pages 269–277)

      Peter A. Lay, Roy H. Magnuson, Henry Taube and Asbed Vassilian

    7. Pentaammineplatinum(IV) Complexes (pages 277–279)

      Neville J. Curtis, Geoffrey A. Lawrance, Alan M. Sargeson and Ronald C. Johnson

    8. Pentakis(Methnamine)-(Trifluoromethanesulfonato-O) Complexes of Chromium(III), Cobalt(III), and Rhodium(III) (pages 279–282)

      Geoffrey A. Lawrance, Alan M. Sargeson, George R. Brubaker, David W. Johnson and Richard A. Peterson

    9. Cis- and Trans-Bis(1,2-Ethanediamine)-Iridium(III) Complexes (pages 287–291)

      Peter A. Lay, Alan M. Sargeson, Henry Taube, Liangshiu Lee and John D. Petersen

    10. Cis-Bis(2,2′-Bipyridine-N,N′) Complexes of Ruthenium(III)/(II) and Osmium(III)/(II) (pages 291–299)

      Peter A. Lay, Alan M. Sargeson, Henry Taube, Mei H. Chou and Carol Creutz

    11. (2,2′-Bipyridine-N,N′)(2,2′:6′,2″-Terpyridine-N,N′,N″) Complexes of Ruthenium(III)/(II) and Osmium(III)/(II) (pages 299–306)

      David C. Ware, Peter A. Lay, Henry Taube, Mei H. Chou and Carol Creutz

  8. Part 5: TRIFLUOROMETHANESULFONATES AND TRIFLUOROMETHANESULFONATO-O COMPLEXES

    1. Cis- and Trans-Bis(1,2-Ethanediamine)-Rhodium(III) Complexes (pages 283–287)

      Peter A. Lay, Alan M. Sargeson, Liangshiu Lee and John D. Petersen

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      Sources of Chemicals and Equipment (pages 307–308)

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      Index of Contributers (pages 309–316)

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      Subject Index (pages 317–344)

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      Formula Index (pages 345–391)

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