Inorganic Syntheses, Volume 25

Copyright © 1989 Inorganic Syntheses, Inc.

Inorganic Syntheses, Volume 25

Editor(s): Harry R. Allcock

Published Online: 5 JAN 2007

Print ISBN: 9780471618744

Online ISBN: 9780470132562

DOI: 10.1002/9780470132562

About this Book

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About The Product

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.

Table of contents

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      Frontmatter (pages i–xxi)

  2. Part 1: Chapter One MAIN GROUP RING SYSTEMS AND RELATED COMPOUNDS

    1. Organocyclophosphanes (pages 1–5)

      M. Baudler, K. Glinka, A. H. Cowley and M. Pakulski

    2. Diethylammonium Cyclo- Octathiotetraphosphate(III) (pages 5–7)

      Hans H. Falius, Andreas B. Schliephake, A. H. Cowley and M. Pakulski

    3. Tervalent Phosphorus–Nitrogen Ring Compounds (pages 7–12)

      O. J. Scherer, R. Anselmann, R. T. Paine and S. Karthikeyan

    4. 2,4,6-Trichloro-1,3,5-Triethylcyclophosph(III)Azanes (1,3,5,2,4,6-Triazatriphosphorinanes) (pages 13–15)

      James Gemmill, Rodney Keat, Rahim Hani and Robert H. Neilson

    5. Aminocyclotetraphosphazenes and Transannular Bridged Bicyclic Phosphazenes (pages 15–24)

      A. C. Sau, K. S. Dhathathreyan, P. Y. Narayanaswamy, S. S. Krishnamurthy, J. C. Van De Grampel, A. A. Van Der Huizen and A. P. Jekel

    6. Chlorofunctional 1,3,5,2λ5,4λ5-Triazadiphosphinines (pages 24–30)

      Alfred Schmidpeter, Philip P. Power and Raskika Das

    7. Binary Cyclic Nitrogen-Sulfur Anions (pages 30–35)

      J. Bojes, T. Chivers, R. T. Oakley, G. Womershäuser and M. Schnauber

    8. Binary Catena-Nitrogen-Sulfur Anions (pages 35–38)

      J. Bojes, T. Chivers, R. T. Oakley, T. B. Rauchfuss and S. Gammon

    9. Pentanitrogen Tetrasulfide Chloride, [N5S4]Cl [1λ4,3λ4,7-Tetrathia-2,4,6,8,9-Pentaazabicyclo[3.3.1]Nona-1(8),2,3,5-Tetraenylium Chloride] (pages 38–40)

      T. Chivers, L. Fielding, R. Mews and R. Maggiulli

    10. (N3P2S)Clph4, 1-Chloro-3,3,5,5-Tetraphenyl-1λ4,2,4,6,3λ5,5λ5-thiatriazadiphosphorine (pages 40–43)

      T. Chivers, M. N. S. Rao and R. T. Oakley

    11. Silicon and Tin Sulfur-Nitrogen Compounds, (Me3Si)2N2S, (Me3Sn)2N2S, and (Me2Sn)S2N2 (pages 43–47)

      Christopher P. Warrens, J. Derek Woollins, M. Witt and H. W. Roesky

    12. 1,1,1-Trimethyl-N-Sulfinylsilanamine, Me3Sinso (pages 48–49)

      Erica Parkes, J. Derek Woollins, Howard B. Yokelson and Robert West

    13. Sulfur-Nitrogen Rings Containing Exocyclic Oxygen (pages 49–55)

      Herbert W. Roesky, Michael Witt, John Burgess, Paul F. Kelly, Thomas G. Purcell and J. Derek Woollins

  3. Part 2: Chapter Two INORGANIC POLYMER SYSTEMS

    1. Organosilane High Polymers: Poly(Methylphenylsilylene) (pages 56–60)

      R. West, P. Trefonas, W. P. Weber and Y.-X. Ding

    2. Organosilicon Derivatives of Cyclic and High Polymeric Phosphazenes (pages 60–68)

      David J. Brennan, James M. Graaskamp, Beverly S. Dunn, Harry R. Allcock and Michael Sennett

    3. Poly (Dimethylphosphazene) and Poly (Methylphenylphosphazene): {Poly[nitrilo (dimethylphosphoranylidyne)] and Poly[nitrilo (methylphenylphosphoranylidyne)]} (pages 69–74)

      P. Wisian-Neilson, R. H. Neilson, James M. Graaskamp and Beverly S. Dunn

    4. Pentachloro(Vinyloxy) Cyclotriphosphazenes and their Polymers: [2,2,4,4,6-Pentachloro-6-(Ethenyloxy)-1,3,5,2λ5,4λ5,6λ5-Triazatriphosphorine] (pages 74–78)

      Christopher W. Allen, Kolikkara Ramachandran, Douglas E. Brown, W. J. Birdsall and J. E. Scheirer

  4. Part 3: Chapter Three COMPOUNDS OF PHARMACOLOGICAL INTEREST

    1. Boron Analogs of Amino Acids (pages 79–85)

      Bernard F. Spielvogel, Fahim U. Ahmed, Andrew T. Mcphail, Karen W. Morse and Terry J. Lofthouse

    2. 1-Aziridinyl-Amino Substituted Cyclophosphazenes (pages 86–94)

      J. C. Van De Grampel, A. A. Van Der Huizen, N. H. Mulder, J. W. Rusch, T. Wilting, M. A. Baxter and D. P. Mack

    3. cis-Diammineplatinum α-Pyridone Blue (pages 94–97)

      Pradip K. Mascharak, Stephen J. Lippard, F. Albert Cotton and Daniel P. Bancroft

  5. Part 4: Chapter Four METAL COMPOUNDS, COMPLEXES, AND LIGANDS

    1. Dipotassium Tetraiodoplatinate(II) Dihydrate (pages 98–100)

      Lars-Fride Olsson, C. King and D. Max Roundhill

    2. Alkyl or Aryl Bis(Tertiary Phosphine) Hydroxo Complexes of Platinum(II) (pages 100–106)

      M. A. Bennett, A. Rokicki and R. J. Puddephatt

    3. Tris(Bidentate)Ruthenium(II) Bis[Hexafluorophosphate] Complexes (pages 107–110)

      Nicholas C. Thomas, Glen B. Deacon, Antonio Llobet and Thomas J. Meyer

    4. Potassium Trialkyl- and Triarylstannates: Preparation by the Deprotonation of Stannanes with Potassium Hydride (pages 110–114)

      R. Corriu, C. Guerin, B. Kolani, M. Newcomb and M. T. Blanda

    5. (Benzenethiolato) Tributyltin (pages 114–115)

      Paul M. Treichel, Marvin H. Tegen and Stephen A. Koch

    6. Use of (Benzenethiolato)Tributyltin to Prepare Complexes of Manganese Carbonyl Having Bridging Thiolate Ligands (pages 115–119)

      Paul M. Treichel, Marvin H. Tegen and Stephen A. Koch

    7. Methylenebis[Dichlorophosphine], Chlorobis[(Dichlorophosphino)Methyl]-Phosphine, and Methylenebis[Dimethyl Phosphine] (pages 120–122)

      S. Hietkamp, H. Sommer, O. Stelzer, A. L. Balch, J. C. Linehan and D. E. Oram

    8. 1,4,7,10,13,16-Hexathiacyclooctadecane (Hexathia-18-Crown-6) and Related Crown Thioethers (pages 122–126)

      Robert E. Wolf, Judith Ann R. Hartman, Leo A. Ochrymowycz, Stephen R. Cooper, Mahmood Sabahi and Richard S. Glass

    9. ([18]Crown-6)Potassium Dicyanophosphide(1-) (pages 126–129)

      Alfred Schmidpeter, Günther Burget, Don J. Chandler and Richard A. Jones

    10. (2-Diphenylphosphino)Benzenamine (pages 129–133)

      Mervyn K. Cooper, J. Michael Downes, Paul A. Duckworth, Michael C. Kerby, Ronald J. Powell and Mark D. Soucek

    11. Sodium Salt of (1R)-3-Nitrobornan-2-One (Sodium d-α-Camphornitronate) (pages 133–135)

      Jonathan W. Stocker, John C. Bailar, George B. Kauffman, Philip Chu and Ronald L. Marhenke

    12. Tris(Glycinato)Cobalt(III) (pages 135–139)

      George B. Kauffman, Mohammad Karbassi, Eishin Kyuno, W. J. Birdsall and P. E. A. Kylanpaa

    13. Resolution of the Tris(Oxalato)Chromate(III) Ion by a Second-Order Asymmetric Synthesis (pages 139–144)

      George B. Kauffman, Nobuyuki Sugisaka, Ian K. Reid and R. Kent Murmann

    14. Difluorodioxouranium(VI) (pages 144–146)

      M. C. Chakravorti, Manju Chowdhury, P. G. Eller and R. J. Kissane

    15. The Ammonium Chloride Route to Anhydrous Rare Earth Chlorides—The Example of Ycl3 (pages 146–150)

      Gerd Meyer, Eduardo Garcia and John D. Corbett

  6. Part 5: Chapter Five TRANSITION METAL ORGANOMETALLIC COMPOUNDS

    1. Bis (Phosphine) Derivatives of Iron Pentacarbonyl and Tetracarbonyl (Tri-tert-Butylphosphine) Iron (0) (pages 151–156)

      Michael J. Therien, William C. Trogler, Rosalice Silva and Marcetta Y. Darensbourg

    2. Tricarbonyl Bis (N, N-Dialkylcarbamodithioate) Tungsten (II) (pages 157–158)

      J. A. Broomhead, J. Budge, W. Pienkowski, C. G. Young, T. L. Tonker and J. L. Templeton

    3. Cyclopentadienylbis (Trimethylphosphine) and Cyclopentadienylbis (Trimethylphosphite) Complexes of Co and Rh (pages 158–164)

      H. Werner, R. Feser, V. Harder, W. Hofmann, H. Neukomm and W. D. Jones

    4. Mixed Cobalt–Ruthenium Dodecacarbonyl Clusters: Dodecacarbonyl Clusters: Dodecacarnbonylhydridotri-Cobaltruthenium, Co3Ruh (Co)12 (pages 164–167)

      F. Oldani, G. Bor, T. J. Coffy and S. G. Shore

    5. Dinuclear Phosphido and Arsenido Derivatives of Molybdenum (pages 167–170)

      R. A. Jones, S. T. Schwab, A. L. Stuart and J. L. Petersen

    6. Dicarbonylbis(Di-tert-Butylphosphine)-(μ-Di-tert-Butylphosphido)-μ-Hydrido-Dirhodium(1+)(Rh2(μ-T-Bu2P)(μ-H)(Co)2(T-Bu2Ph)2 and μ-Chloro-Bis(η4-1,5-Cyclooctadiene)(μ-Di-tert-Butylphosphido)Dirhodium(1+) (Rh2(μ-T-Bu2P)-μ-Cl(Cod)2),(Cod = 1,5-Cyclooctadiene) (pages 170–173)

      R. A. Jones, D. E. Heaton, T. C. Wright, D. W. Meek and C. Supplee

    7. BisTert-Butylphosphido (T-Bup(H)-) Bridged Dimers of Rhodium(+1) and Nickel(+1) Containing Rh=Rh Double and Ni—Ni Single Bonds (pages 173–177)

      R. A. Jones, M. H. Seeberger, A. A. Cherkas, F. Van Gastel and A. J. Carty

    8. Tetracarbonylbis(μ-Di-Tert-Butylphosphido)Dicobalt(+1) [Co(μ-T-Bu2P)(Co)2]2 (pages 177–179)

      D. J. Chandler, R. A. Jones, K. S. Ratliff, A. L. Stuart, N. Viswanathan and G. L. Geoffroy

    9. (η5-Cyclopentadienyl)Diruthenium Complexes (pages 179–187)

      N. M. Doherty, S. A. R. Knox, C. P. Casey and G. T. Whiteker

    10. Di-μ-Iodo-Bis(Tricarbonylosmium), Bis(Tetracarbonyliodoosmium), and Dicarbonyliodo(η5-Cyclopentadienyl)Osmium (pages 187–192)

      Steven Rosenberg, Albert W. Herlinger, Wayne S. Mahoney, Gregory L. Geoffroy, Robert T. Hembre, K. R. Birdwhistell and J. Norton

    11. μ-Nitrido-Bis(Triphenylphosphorus)(1 +)-μ-Carbonyl-Decacarbonyl-μ-Hydridotriosmate(1 –) (pages 193–194)

      K. Burgess, R. P. White, S. Bassner, G. L. Geoffroy, R. L. Gray and D. J. Darensbourg

    12. Decacarbonyl-(η5-Cyclopentadienyl)Dihydridocobalttriosmium, CoOs3(μ-H)2(η5-C5H5)(μ-CO)(CO)9; Nonacarbonyl-(η5Cyclopentadienyl)Trihydrido- and (η5-Cyclopentadienyl)Tetrahydridocobalt-Triosmium, CoOs3(μ-H)3(η5-C5H5)(CO)9 and CoOs3(μ-H)4-(η5-C5H5)(CO)9 (pages 195–199)

      Deng-Yang Jan, Tim J. Coffy, Wen-Liang Hsu, Sheldon G. Shore, B. Handwerker and Gregory L. Geoffroy

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      Index of Contributers (pages 201–209)

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      Subject Index (pages 211–241)

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      Formula Index (pages 243–300)

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