Inorganic Syntheses, Volume 26

Copyright © 1989 Inorganic Syntheses, Inc.

Inorganic Syntheses, Volume 26

Editor(s): Herbert D. Kaesz

Published Online: 5 JAN 2007

Print ISBN: 9780471504856

Online ISBN: 9780470132579

DOI: 10.1002/9780470132579

About this Book

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The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.

Table of contents

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      Frontmatter (pages i–xxvii)

  2. Part 1: Chapter one COMPOUNDS OF THE MAIN GROUP ELEMENTS AND THE LANTHANIDES

    1. Potassium tetradecahydrononaborate(1-) (pages 1–3)

      Patrick J. Dolan, Donald F. Gaines, David C. Moody, Caterina K. Nelson, Riley Schaeffer, Sheldon G. Shore and Steven H. Lawrence

    2. Bromotrimethylsilane (pages 4–6)

      Claudio Palomo, Jesus M. Aizpurua, Joyce Y. Corey and Janet Braddock

    3. Trimethylphosphine (pages 7–12)

      M. L. Luetkens, A. P. Sattelberger, H. H. Murray, J. D. Basil, J. P. Fackler, R. A. Jones and D. E. Heaton

    4. Phosphorus Trifluoride (pages 12–17)

      Ronald J. Clark, Helen Belefant and Stanley M. Williamson

    5. (η5-Cyclopentadienyl)Lanthanide complexes from the metallic elements (pages 17–23)

      Glen B. Deacon, Geoff N. Pain, Tran D. Tuong, William J. Evans, Keith R. Levan and Raul Dominguez

  3. Part 2: Chapter two MONONUCLEAR TRANSITION METAL COMPLEXES PART I

    1. Ammonium [(1R)-(Endo, Anti)]-3-Bromo-1, 7-Dimethyl-2-Oxobicyclo[2.2.1]Heptane-7-Methanesulfonate, and Synthesis and Resolution of cis-Dichlorobis(1, 2-Ethanediamine)Chromium(III) Chloride (pages 24–30)

      A. Hammershøi, E. Hansson, J. Springborg and C. J. Hawkins

    2. Organometallic Complexes of Isomeric Acyl Isocyanides: Chromium Carbonyl (Acyl Isocyanide) and (Acyl Cyanide) Complexes (pages 31–36)

      Ashraf A. Ismail, Ian S. Butler, Gerard Jaouen, Robert J. Angelici and George N. Glavee

    3. Diammonium Pentachlorooxomolybdate(V) (pages 36–39)

      A. Syamal, M. R. Maurya, K. Dehnicke and F. Schmock

    4. Carbyne Complexes of Tungsten (pages 40–43)

      E. O. Fischer, D. Wittmann, A. Mayr and A. Mcdermott

    5. 2, 2-Dimethylpropylidyne Tungsten(VI) Complexes and Precursors for their Syntheses (pages 44–51)

      Richard R. Schrock, Jose Sancho, Steven F. Pederson, Scott C. Virgil and Robert H. Grubbs

    6. Zerovalent Iron Isocyanide Complexes (pages 52–59)

      Michel O. Albers, Eric Singleton, Neil J. Coville, Arthur Y-J. Chen, Rusty Blanski and Herbert D. Kaesz

    7. Tetracarbonyliron(0) Complexes Containing Group V Donor Ligands (pages 59–64)

      Michel O. Albers, Eric Singleton, Neil J. Coville, Carlton E. Ash, Christine C. Kim and Marcetta Y. Darensbourg

    8. cis-Tetraamminedihaloruthenium(III) Halide Complexes (pages 65–68)

      S. D. Pell, M. M. Sherban, V. Tramontano, M. J. Clarke, K. Hansongnern and R. A. Krause

    9. (η4-1, 5-Cyclooctadiene)Ruthenium(II) Complexes (pages 68–77)

      Michel O. Albers, Terence V. Ashworth, Hester E. Oosthuizen, Eric Singleton, Joseph S. Merola and Raymond T. Kacmarcik

    10. Pentacarbonylhydridorhenium (pages 77–80)

      Michael A. Urbancic, John R. Shapley, Nancy N. Sauer and Robert J. Angelici

    11. Organometallic Fluoro Complexes (pages 81–85)

      E. Horn, F. L. Wimmer, M. R. Snow, Penny Pangagiotidou and R. Cotton

    12. (Tetrahydrothiophene)Gold(I) or Gold(III) Complexes (pages 85–91)

      Rafael Uson, Antonio Laguna, Mariano Laguna, D. A. Briggs, H. H. Murray and J. P. Fackler

  4. Part 3: MONONUCLEAR TRANSITION METAL COMPLEXES PART II: COMPLEXES WITH WEAKLY BONDED ANIONS

    1. Carbonyl(η5-Cyclopentadienyl)-(Tetrafluoroborato)Molybdenum and Tungsten Complexes (pages 92–106)

      W. Beck, Wolfgang Beck, Klaus Schloter, Karlheinz Sünkel, Günter Urban, Thomas Forschner, Alicia Todaro and Alan Cutler

  5. Part 3: Chapter three MONONUCLEAR TRANSITION METAL COMPLEXES PART II

    1. Pentacarbonyl(Tetrafluoroborato)Rhenium and -Manganese and Reactions Thereof (pages 106–113)

      Wolfgang Beck, Klaus Raab, J. R. Shapley and B. R. Whittlesey

    2. Manganese(I) and Rhenium(I) Pentacarbonyl(Trifluoromethanesulfonato) Complexes (pages 113–117)

      Steven P. Schmidt, Jay Nitschke, William C. Trogler, Sarah Inman Huckett and Robert J. Angelici

    3. Iridium(III) Complexes with the Weakly Bonded Anions [Bf4]- and [Oso2Cf3]- (pages 117–121)

      Wolfgang Beck, Herbert Bauer, Bernhard Olgemöller, Devereaux A. Clifford and Robert H. Crabtree

    4. Dihydridobis(Solvent)Bis(Triphenylphosphine)Iridium(III) Tetrafluoroborates (pages 122–126)

      Robert H. Crabtree, Michelle F. Mellea, Jean M. Mihelcic, Ayusman Sen and Venkatasuryanaryana Chebolu

  6. Part 3: Chapter three MONONUCLEAR TRANSITION METAL COMPLEXES PART II: COMPLEXES WITH WEAKLY BONDED ANIONS

    1. cis-Chlorobis(Triethylphosphine)(Trifluoromethanesulfonato)Platinum(II) (pages 126–128)

      Wolfgang Beck, Bernhard Olgemöller, Luitgard Olgemöller, S. Chaloupka and L. M. Venanzi

    2. Acetonitrile Complexes of Selected Transition Metal Cations (pages 128–134)

      Richard R. Thomas, Ayusman Sen, Wolfgang Beck and Reich Leidl

    3. The Formation of the Hydrido(Methanol)Bis(Triethylphosphine)Platinum(II) Cation and its Reactions with Unsaturated Hydrocarbons (pages 134–141)

      Carla Sorato, Luigi M. Venanzi, Henry E. Bryndza and Sonbinh Nguyen

  7. Part 4: Chapter four MONONUCLEAR TRANSITION METAL COMPLEXES PART III: METALLACYCLIC COMPLEXES

    1. Main Group Metal (Li or Mg) O-Phenylenedimethyl [O-C6H4(C¯H2), or O-C6H4{ Ch(Sime3)}2] Transfer Reagents (pages 142–150)

      Ekkehard Lindner, M. F. Lappert, T. R. Martin, C. L. Raston and R. A. Andersen

    2. Metallation of Aromatic Ketones with Pentacarbonylmethylmanganese(I) (pages 155–161)

      R. J. Mckinney, S. S. Crawford, K. Oberdorf and J. L. Spencer

    3. Cyclo-Cotrimerization of Phosphinothioyls with Alkynes. Phosphinothioyl-Containing Manganese Analogs of Cyclopentadienes and Bicycloheptadienes (pages 161–169)

      E. Lindner, A. Rau, V. Käss, Martin A. Bennett and Horst Neumann

    4. Tetracarbonyl{[2-(Diphenylphosphino)Phenyl]Hydroxymethyl-C, P}Manganese (pages 169–171)

      G. D. Vaughn, J. A. Gladysz, K. Youngdahl, Y. K. Park and M. Y. Darensbourg

    5. Cyclometallation Reactions (pages 171–180)

      Michael I. Bruce, Michael J. Liddell, Geoff N. Pain, Martin A. Bennett and Horst Neumann

    6. (η6-Hexamethylbenzene)Ruthenium Complexes Containing Hydride and Orthometallated Triphenylphosphine (pages 180–183)

      M. A. Bennett, J. L. Latten and W. D. Jones

    7. An Osmium Containing Benzene Analog, Os(CSCHCHCHCH)(CO)(Pph3)2, Carbonyl(5-Thioxo-1, 3-Pentadiene-1, 5-Diyl-C1, C5, S)-Bis(Triphenylphosphine)Osmium, and its Precursors (pages 184–189)

      Gregory P. Elliott, Nicola M. Mcauley, Warren R. Roper and Patricia A. Shapley

    8. (1, 3-Butadiene-1, 4-Diyl)(η5-Cyclopentadienyl)-(Triphenylphosphine)Cobalt with Various Substituents (pages 189–200)

      Y. Wakatsuki, H. Yamazaki, E. Lindner and A. Bosamle

    9. An Iridium(III) Complex Containing Cyclometallated Triphenylphosphine Formed by Isomerization of an Iridium(I) Triphenylphosphine Complex (pages 200–203)

      M. A. Bennett, J. L. Latten, L. J. Ayers and D. L. Thorn

    10. Nickel-Containing Cyclic Amide Complexes (pages 204–207)

      T. Yamamoto, H. M. Büch and P. Binger

    11. Six-Membered Cyclopalladated Complexes of 2-Benzylpyridine (pages 208–211)

      K. Hiraki, Y. Fuchita and M. Pfeffer

  8. Part 4: Chapter four MONONUCLEAR TRANSITION METAL COMPLEXES PART III

    1. Cyclometallated Organolithium Compounds (pages 150–155)

      Johann T. B. H. Jastrzebski, Gerard Van Koten, M. F. Lappert, P. C. Blake and D. R. Hankey

    2. Cyclopalladated Compounds (pages 211–214)

      Michel Pfeffer and Anil B. Goel

  9. Part 5: Chapter five POLYNUCLEAR TRANSITION METAL COMPLEXES

    1. Ditungsten Tetracarboxylates (pages 215–225)

      J. R. Shapley, D. J. Santure, A. P. Sattelberger, F. A. Cotton and W. Wang

    2. Diphenylphosphino-Bridged Dimanganese Complexes (pages 225–231)

      J. A. Iggo, M. J. Mays, A. Wojcicki and Shin-Guang Shyu

    3. Preparation of Some Bimetallic μ-(η1-C, O) Acetyl Complexes (pages 231–243)

      T. C. Forschner, A. R. Cutler, P. A. Goodson, C. P. Casey, W. Beck and K. H. Sünkel

    4. Trinuclear Metal Complexes (pages 243–246)

      L. Markó, J. Takács, Kenton H. Whitmire, B. A. Matrana and H. D. Kaesz

    5. Bis[μ-Nitrido-Bis(Triphenylphosphorus) (1 +)] μ4-Carbido-Dodecacarbonyl-Tetraferrate(2 -), [Ppn]2[Fe4C(Co)12] (pages 246–249)

      J. W. Kolis, M. A. Drezdzon, D. F. Shriver, F. R. Furuya and W. L. Gladfelter

    6. Dinuclear Ruthenium(II) Carboxylate Complexes (pages 249–258)

      Michel O. Albers, Eric Singleton, Janet E. Yates and Fred B. Mccormick

    7. Polynuclear Ruthenium Complexes (pages 259–263)

      M. I. Bruce, C. M. Jensen, N. L. Jones, Georg Süss-Fink, Gerhard Herrmann and Vera Dase

    8. A Phosphino Bridged Ruthenium Cluster: Nonacarbonyl-μ-Hydrido-(μ-Diphenylphosphino)Triruthenium(0) (pages 264–268)

      D. Nucciarone, S. A. Maclaughlin, A. J. Carty and Stephen B. Colbran

    9. [μ-Nitrido-Bis(Triphenylphosphorus)(1 +)]-[Decacarbonyl-1K3C, 2K3C, 3K4C-μ-Hydrido-1: 2K2H-Bis(Triethylsilyl-1KSi) 2KSi)-Triangulo-Triruthenate(1—)] (pages 269–271)

      Georg Süss-Fink, Herbert D. Kaesz and Yea-Jer Chen

    10. Tri- and Tetranuclear Carbonyl-Ruthenium Cluster Complexes Containing Isocyanide, Tertiary Phosphine, and Phosphite Ligands. Radical Ion-Initiated Substitution of Metal Cluster Carbonyl Complexes Under Mild Conditions (pages 271–280)

      Michael I. Bruce, Brian K. Nicholson, Michael L. Williams, Thérèse Arliguie and Guy Lavigne

    11. Carbido-Carbonyl Ruthenium Cluster Complexes (pages 280–285)

      J. N. Nicholls, M. D. Vargas, J. Hriljac and Michael Sailor

    12. Nitrido-Ruthenium Cluster Complexes (pages 286–289)

      Margaret L. Blohm, Wayne L. Gladfelter and A. G. Cowie

    13. Some Useful Derivatives of Dodecacarbonyltriosmium (pages 289–293)

      J. N. Nicholls, M. D. Vargas, A. J. Deeming and S. E. Kabir

    14. Dodecacarbonyltetra-μ-Hydrido-Tetrahedro-Tetraosmium (pages 293–295)

      Camilo Zuccaro, G. Pamploni and F. Calderazzo

    15. High Nuclearity Carbonyl Cluster Compounds of Osmium (pages 295–302)

      J. N. Nicholls, M. D. Vargas, R. D. Adams and K. Natarajan

    16. Thioosmium Clusters (pages 303–309)

      Richard D. Adams, Istvan T. Horvath, Jean-Jacques Bonnet, Christian Bergounhou and Julian P. Attard

    17. Tris(η5-Cyclopentadienyl)Bis-(μ3-Phenylmethylidyne)-Tricobalt (pages 309–311)

      S. B. Colbran, B. H. Robinson, J. Simpson, J. R. Shapley and Wenn-Yann Yeh

    18. Bis(Tetramethylammonium) Hexa-μ-Carbonyl-Hexacarbonylhexanickelate(2-), [N(Ch3)4]2[Ni6(Co)6(μ-Co)6] (pages 312–315)

      A. Ceriotti, G. Longoni, G. Piva, Jacky Rosé and Pierre Braunstein

    19. Bis(Tetrabutylammonium) Hexa-μ-Carbonyl-Hexacarbonylhexaplatinate(2 -), [N(C4H9)4]2[Pt6(Co)6(μ-Co)6] (pages 316–319)

      A. Ceriotti, G. Longoni, M. Marchionna, Anne Degremont, Jacky Rose and Pierre Braunstein

    20. Preparation of the Carbonyl Platinum Anions, [Pt3(Co)6]N2-, (N = 3–5) (pages 319–323)

      Michael J. D′Aniello, Constance J. Carr, Michael G. Zammit, Anne Degremont, Jacky Rosé and Pierre Braunstein

    21. Synthesis of Gold-Containing Mixed-Metal Cluster Complexes (pages 324–328)

      M. I. Bruce, B. K. Nicholson, O. Bin Shawkataly, J. R. Shapley and T. Henly

    22. Mercury-Bridged Transition Metal Cluster Derivatives and their Precursor (pages 328–335)

      Edward Rosenberg, Bruce Novak and W. Edward Lindsell

    23. Heterobinuclear Nonacarbonyl Complexes and Hydride Complexes of Iron—Chromium, Iron—Molybdenum, and Iron—Tungsten (pages 335–341)

      Larry W. Arndt, Christopher J. Bischoff, Marcetta Y. Darensbourg and John E. Ellis

    24. Cyclopentadienylsodium and some mono-, tri-, and tetranuclear metal carbonyl derivatives and cluster complexes (pages 341–350)

      Pierre Braunstein, Robert Bender, Jeanmarc Jud, H. Vahrenkamp, Glen C. Vogel and Gregory L. Geoffroy

    25. Mixed Trinuclear Dicobaltiron and Dicobaltruthenium Cluster Complexes (pages 351–356)

      H. Vahrenkamp, Daqiang Xu, Herbert D. Kaesz, Edward Rosenberg and Bruce Novak

    26. Stepwise Syntheses of Ruthenium Mixed-Metal Cluster Complexes (pages 356–360)

      Pierre Braunstein, Jacky Rose and David C. Busby

    27. Mixed-Metal Cluster Complexes of Nickel with Ruthenium or with Osmium (pages 360–365)

      C. Bergounhou, J.-J. Bonnet, G. Lavigne, F. Papageorgiou, S. G. Shore and U. Siriwardane

    28. Triosmium and Trinickeltriosmium Cluster Complexes (pages 365–369)

      Enrico Sappa, Mario Valle, Sheldon G. Shore and Upali Siriwardane

    29. A Dicobaltplatinum Complex and its Platinum Precursor (pages 369–372)

      K. Yasufuku, H. Noda, H. Yamazaki and S. Martinengo

    30. Salts of Mixed Platinum-Tetrarhodium Cluster Complexes (pages 372–376)

      Alessandro Fumagalli, Secondo Martinengo, Pierre Braunstein and Dominique Watt

  10. Part 6: Chapter six SOLID STATE

    1. Synthesis and Crystal Growth of A3M2X9 (A = Cs, Rb; M = Ti, V, Cr; X = Cl, Br) (pages 377–385)

      Anton Stebler, Bruno Leuenberger, Hans U. Gödel and Bernard Briat

    2. Highly Conducting and Superconducting Synthetic Metals (pages 386–394)

      Jack M. Williams and Coworkers

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      Index of Contributers (pages 395–397)

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      Subject Index (pages 399–409)

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      Formula Index (pages 411–443)

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