Inorganic Syntheses, Volume 27

Copyright © 1990 Inorganic Syntheses, Inc.

Inorganic Syntheses, Volume 27

Editor(s): Alvin P. Ginsberg

Published Online: 5 JAN 2007

Print ISBN: 9780471509769

Online ISBN: 9780470132586

DOI: 10.1002/9780470132586

About this Book

Product Information

About The Product

The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.

Table of contents

    1. You have free access to this content
      Frontmatter (pages i–xxv)

  2. Part 1: Chapter One Transition Metal Polyhydride Complexes

    1. Molecular Hydrogen Complexes of Mo and W (pages 1–8)

      Gregory J. Kubas and Carl Hoff

    2. Molybdenum and Tungsten Phosphine Polyhydrides (pages 8–14)

      Gregory G. Hlatky, Robert H. Crabtree, Kimberly A. Kubat-Martin and G. J. Kubas

    3. Heptahydridobis(Triphenylphosphine)-Rhenium(VII) and Octahydridotetrakis-(Triphenylphosphine)Dirhenium(IV) (pages 14–18)

      C. J. Cameron, G. A. Moehring, R. A. Walton, K. G. Caulton and R. L. Bansemer

    4. Tetrahydrido(η5-Pentamethylcyclopenta-Dienyl)Iridium (pages 19–22)

      Thomas M. Gilbert, Robert G. Bergman and Joseph S. Merola

    5. Tris[1,3-Bis(Diphenylphosphino)Propane]-Heptahydridotriiridium(2 +) Bis(Tetrafluoroborate) and Bis[1, 3-Bis-(Diphenylphosphino)Propane]-Pentahydridodiiridium(1+) Tetrafluoroborate (pages 22–26)

      H. H. Wang, A. M. Mueting, J. A. Casalnuovo, S. Yan, J. K.-H. Barthelmes, L. H. Pignolet, Martin P. Mcgrath and Robert H. Crabtree

    6. Heterobimetallic Hydride Complexes (pages 26–30)

      E. G. Lundquist, K. G. Caulton and J. L. Spencer

    7. μ-Hydrido-tetrakis(tertiary phosphine)diplatinum Cations (pages 30–38)

      Stanislav Chaloupka, Luigi M. Venanzi, Robert L. Cowan and William C. Trogler

  3. Part 2: Chapter Two Transition Metal Polyhydride Complexes

    1. Tetraphenylphosphonium Salts of [Mo2(S)N(s2)6-N]2- Thioanions and Derivatives (pages 39–47)

      A. I. Hadjikyriacou, D. Coucouvanis, J. H. Enemark and G. Backes-Dahmann

    2. Molybdenum-Sulfur Clusters (pages 47–51)

      Achim M¨ller, Erich Krickemeyer, Anastasios Hadjikyriacou and Dimitri Coucouvanis

    3. Bis(η5-Methylcyclopentadienyl)Titanium Pentasulfide, Bis(μ-Methylcyclopentadienyl)-Divanadium Pentasulfide, and Bis(μ5-Methylcyclopentadienyl)Divanadium Tetrasulfide (pages 51–58)

      James Darkwa, Dean M. Giolando, Catherine Jones Murphy, Thomas B. Rauchfuss and A. Müller

    4. Cyclometallapolysulfanes (and Selanes) of Bis(η5-Cyclopentadienyl) Titanium(IV), Zirconium(IV), Molybdenum(IV), and Tungsten(IV) (pages 59–65)

      Alan Shaver, James M. Mccall, Gabriela Marmolejo, F. Bottomley, E. C. Ferris and J. A. Gladysz

    5. Bis(Hydrogensulfido) Complexes of Bis(η5-Cyclopentadienyl) Titanium(IV) and Tungsten(IV) (pages 65–68)

      Alan Shaver, Gabriela Marmolejo, James M. Mccall, Thomas B. Rauchfuss, Lenore Koczon and Scott Simerly

    6. (μ-Disulfido-S)(η-Disulfido-η2:μ2)Bis-(η5-Pentamethylcyclopentadienyl)(μ-Thio)-Dichromium(Cr—Cr) (pages 69–70)

      Joachim Wachter, Henri Brunner, Walter Meier, Umar Riaz and M. David Curtis

  4. Part 3: Chapter Three Early Transition Metal Polyoxoanions

    1. Introduction to Early Transition Metal Polyoxoanions (pages 71–85)

      Walter G. Klemperer

    2. Tetrabutylammonium Isopolyoxometalates (pages 74–85)

      Walter G. Klemperer

    3. α-, β-, and γ-Dodecatungstosilicic Acids: Isomers and Related Lacunary Compounds (pages 85–96)

      Andréa Téazéa, Gilbert Hervéa, Richard G. Finke and David K. Lyon

    4. Vanadium(V) Substituted Dodecatungstophosphates (pages 96–104)

      Peter J. Domaille, Gilbert Hervéa and Andréa Téazéa

    5. Potassium Octadecatungstodiphosphates(V) and Related Lacunary Compounds (pages 104–111)

      Roland Contant, Walter G. Klemperer and Omar Yaghi

    6. The Aquatrihexacontaoxobis[Trioxoarsenato(III)]Henicosatungstate(6—) Anion Isolated as the Acid or as the Rubidium Salt (pages 111–115)

      Y. Jeannin, J. Martin-Frere, Jingfu Liu and M. T. Pope

    7. The Sodium Pentaphosphato(V)-Triacontatungstate Anion Isolated as the Ammonium Salt (pages 115–118)

      Y. Jeannin, J. Martin-Frere, Daniel J. Choi and Michael T. Pope

    8. Tetracontatungstotetraarsenate(III) and its Cobalt(II) Complex (pages 118–120)

      Gilbert Hervéa, Andréa Téazéa, Jingfu Liu and Michael T. Pope

    9. Ammonium Sodium Henicosatungstonona-Antimonate(III), (NH4)18[NaSb9W21O86]·24H2O (pages 120–122)

      Gilbert Hervéa, Andre Téazéa, Jingfu Liu and Michael T. Pope

    10. Bis(μ5-Organophosphonato-O, O′, O″)-Penta-μ-Oxo-Pentakis(Dioxomolybdates,-Tungstates)-(4—) (Pentametallobisphosphonates) (pages 123–128)

      Won Suk Kwak, Michael T. Pope, Purisai R. Sethuraman, Xiao Sun and Jon Zubieta

    11. Tetrakis(Tetrabutylammonium) μ3-[η5-Cyclopentadienyl)Trioxotitanate(IV)]-a-β-1,2,3-Trivanadononatungstosilicate(4—), [(c4H9)4n]4[A-β-(μ5-C5H5)Tisiw9V3O40] (pages 128–135)

      R. G. Finke, C. A. Green, B. Rapko, R. Contant, R. Thouvenot and N. Ammar

  5. Part 4: Chapter Four Lanthanide And Actinide Complexes

    1. Lanthanide Trichlorides by Reaction of Lanthanide Metals with Mercury(II) Chloride in Tetrahydrofuran (pages 136–141)

      Glen B. Deacon, Tran D. Tuong, Dallas L. Wilkinson and Tobin Marks

    2. Bis(Phenylethynyl)Ytterbium(II) from Ytterbium Metal and Bis(Phenylethynyl)Mercury (pages 142–146)

      Glen B. Deacon, Craig M. Forsyth, Dallas L. Wilkinson and Andrea L. Wayda

    3. Bis[Bis(Trimethylsilyl)Amido]Bis(Diethyl Ether)Ytterbium and (Diethyl Ether)Bis(η5-Pentamethylcyclopentadienyl)Ytterbium (pages 146–150)

      T. D. Tilley, J. M. Boncella, D. J. Berg, C. J. Burns, R. A. Andersen, G. A. Lawless, M. A. Edelman and M. F. Lappert

    4. Cyclooctatetraene Lanthanide Complexes. Lu(C8H8)Cl(thf) and Lu(C8H8)[o-C6H4CH2N(CH3)2](thf) (pages 150–154)

      Andrea L Wayda, John T. Rigsbee and Andrew Streitwieser,

    5. Bis(η5-Pentamethylcyclopentadienyl)-Bis(Tetrahydrofuran)Samarium (II) (pages 155–157)

      William J. Evans, Tamara A. Ulibarri, Herbert Schumann and Siegbert Nickel

    6. Tert-Butylbis(η5-Cyclopentadienyl)-(Tetrahydrofuran)Neodymium (pages 158–160)

      H. Schumann, G. Jeske, G. B. Deacon and P. I Mackinnon

    7. Bis(η5-Cyclopentadienyl)(Tetrahydrofuran)-[(Trimethylsilyl) Methyl] Lutetium and Bis (η5-Cyclopentadienyl)(Tetrahydrofuran)-p-Tolyllutetium (pages 160–163)

      Herbert Schumann, Wolfgang Genthe, Eftimios Palamidis, G. B. Deacon and S. Nickel

    8. Hydrocarbon-Soluble Homoleptic Bulky Aryl Oxides of the Lanthanide Metals: [Ln(OArR)3)] (pages 164–168)

      Michael F. Lappert, Anirudh Singh, Richard G. Smith, Hilmar A. Stecher and Ayusman Sen

    9. Bis[η5-1, 3-Bis(Trimethylsilyl)Cyclopenta-Dienyl]Chlorolanthanide(III) Complexes, [{LnCp″2(μ-Cl)}2] and [LnCp″2Gi-Cl)2Li(thf)2] (pages 168–172)

      Michael F. Lappert, Anirudh Singh and Josef Takats

    10. Bis[η5-1, 3-Bis(Trimethylsilyl)Cyclopenta-Dienyl]Halouranium(IV) and-Thorium(IV), [MCp″2 Cl2] and [UCp″2X2] (pages 172–177)

      Paul C. Blake, Michael F. Lappert, Richard C. Taylor, Paulette N. Hazin and Joseph W. Bruno

    11. Tris(η5-Cyclopentadienyl) [(Dimethylphenyl-Phosphoranylidene)Methyl]Uranium(IV) (pages 177–181)

      Roger E. Cramer, Jong Hwa Jeong, Richard B. Maynard, John W. Gilje, Dwight D. Heinrich and John P. Fackler

  6. Part 5: Chapter Five Transition Metal Cluster Complexes

    1. Tetrairon Carbido Carbonyl Clusters (pages 182–188)

      Ernestine W. Hill, John S. Bradley, Juanita Cassidy and Kenton H. Whitmire

    2. Tetraethylammonium Dodecarbonyl-Tricobaltferrate (1 -) and (Triphenylphosphine)-Gold(1 +) Dodecarbonyltricobaltferrate(1–) (pages 188–191)

      Arthur A. Low, Joseph W. Lauher, Pierre Braunstein, Anne Degremont and J Acky Roéa

    3. Chiral Trinuclear NiCoMo and MoRuCo Clusters (pages 191–196)

      H. Vahrenkamp, Da Quiang Xu, H. D. Kaesz, M. L. Williams and F. G. A. Stone

    4. Nonacarbonyl-Tri-μ-Hydrido-μ3-Methylidyne-Triruthenium and -Triosmium (pages 196–208)

      Jerome B. Keister, John R. Shapley, Debra A. Strickland, Ling-Shwu Hwang and Yun Chi

    5. Anionic and Heteronuclear Triosmium Clusters (pages 209–214)

      Kevin Burgess, Ross P. White, Richard D. Adams and James E. Babin

    6. Hexachlorododecakis(Triphenyl-Phosphine)Pentapentacontagold, Au55[P(C6H5)3]12CL6 (pages 214–218)

      Günter Schmid, Bruce D. Alexander, Jurgen Barthelmes, Ann M. Mueting and Louis H. Pignolet

    7. A Platinum-Gold Cluster: Chloro-1κCl-Bis(Triethylphosphine-1κP)Bis(Triphenyl- Phosphine)-2κP, 3κP-Triangulo- Digold-Platinum(1 +) Trifluoromethanesulfonate (pages 218–221)

      Pierre Braunstein, Hans Lehner, Dominique Matt, Kevin Burgess and Michael J. Ohlmeyer

  7. Part 6: Chapter Six Phosphorus Complexes And Compounds

    1. Chloro(η2-Tetrahedro-Tetraphosphorus)- Bis(Triphenylphosphine)Rhodium(I) (pages 222–224)

      W. E. Lindsell, A. P. Ginsberg, A. L. Balch, S. Rowley and S. Reimer

    2. Tetracarbonylbis(η5-Cyclopentadienyl)- (μ-η2-Diphosphorus)Dimolybdenum(I) and Dicarbonyl (η5- Cyclopentadienyl)-(η3-Cyclo-Triphosphorus)Molybdenum(I) (pages 224–227)

      O. J. Scherer, J. Schwalb, H. Sitzmann and W. E. Lindsell

    3. Trilithium Heptaphosphide, Dilithium Hexadecaphosphide, and Trisodium Henicosaphosphide (pages 227–235)

      M. Baudler, K. Glinka and Richard A. Jones

    4. Phosphorus Compounds Containing Sterically Demanding Groups (pages 235–240)

      Alan H. Cowley, Nicholas C. Norman, Marek Pakulski, G. Becker, M. Layh, E. Kirchner and M. Schmidt

    5. Compounds with Unsupported P=P Bonds (pages 240–243)

      Alan H. Cowley, Nicholas C. Norman, Marek Pakulski, G. Becker, M. Layh, E. Kirchner and M. Schmidt

    6. Tris(Trimethylsilyl)Phosphine and Lithium Bis(Trimethylsilyl)Phosphide.Bis-(Tetrahydrofuran) (pages 243–249)

      Gerd Becker, Helmut Schmidt, Gudrun Uhl, Werner Uhl, Manfred Regitz, Wolfgang Rösch and Uwe-Josef Vogelbacher

    7. (2,2-Dimethylpropylidyne)Phosphine (pages 249–253)

      Gerd Becker, Helmut Schmidt, Gudrun Uhl, Werner Uhl, Manfred Regitz, Wolfgang Rösch and Uwe-Josef Vogelbacher

    8. Triphosphenium Salts (pages 253–258)

      Alfred Schmidpeter, Siegfried Lochschmidt, Alan H. Cowley and Marek Pakulski

    9. cis-1,3-Di-Tert-Butyl-2,4-Dichloro-1,3,2,4-Diazadiphosphetidine (pages 258–260)

      Wan Ahmad Kamil, Ne M. JEAN′NE Shreeve, Robert R. Holmes and Kumara Swamy

  8. Part 7: Chapter Seven Transition Metal Complexes Of Biological Interest

    1. Reversible Cobalt(II) and Iron(II) Dioxygen Carriers of Totally Synthetic Lacunar Cyclidene Complexes (pages 261–282)

      Colin J. Cairns, Daryle H. Busch, Carol A. Bessel and Kenneth J. Takeuchi

    2. [Pt(1, 2-Cyclohexanediamine)(Ascorbato-C2, O5)] (pages 283–286)

      L. Steven Hollisxs, Sheryl L. Doran, Alan R. Amundsen, Eric W. Stern, Kazi J. Ahmed and Stephen J. Lippard

  9. Part 8: Chapter Eight Miscellaneous Transition Metal Complexes

    1. (Dithiocarbonato) [1,1,1-Tris(Diphenylphosphinomethyl)Ethane]Rhodium (III) Tetraphenylborate Solvate (pages 287–290)

      C. Bianchini, A. Meli and Y. Ohgomori

    2. The Vaska-Type Rhodium Complexes, trans-RhX(CO)L2 (pages 290–293)

      Yuji Ohgomori, Yoshihisa Watanabe, Martin A. Cushing and Steven D. Ittel

    3. Potassium Hexaiodorhenate(IV) (pages 294–295)

      M. C. Chakravorti, T. Gangopadhyay, R. J. Angelici and M. G. Choi

    4. Group 6 Pentacarbonyl Acetates as their μ-Nitrido-Bis(Triphenylphosphorus)(1+) Salts (pages 295–300)

      Donald J. Darensbourg, Susan A. Morse, Cesar Ovalles, Holly C. Pickner, Wayne L. Gladfelter and Daniel R. Mantell

    5. Bis(Organoimido) Complexes of Tungsten(VI) (pages 300–306)

      A. J. Nielson and B. L. Haymore

    6. Relatively Air-Stable M(II) saccharinates, M = V, or Cr (pages 306–310)

      F. Albert Cotton, Eduardo Libby, Carlos A. Murillo, Grettel Valle, M. Bakir, D. R. Derringer and R. A. Walton

    7. Pyridinium Fluorotrioxochromate(VI), (C5H5NH)[CrO3F] (pages 310–312)

      Manabendra N. Bhattacharjee, Mihir K. Chaudhuri, Jay H. Worrell and Thomas Li

    8. Dipotassium Trifluorosulfato-Manganate(III) (pages 312–314)

      Manabendra N. Bhattacharjee, Mihir K. Chaudhuri, Thomas Li and Jay H. Worrell

    9. cis-Dichlorobis(1, 2-Ethanediamine)-Platinum(IV) Chloride (pages 314–317)

      Robert M. Kuksuk, Wade A. Freeman, Pierre R. Lebreton, George B. Kauffman and Matthew L. Adams

    10. Bis(1,1,1,5,5,5-Hexafluro-2,4-Pentane-Dionato)Palladium and its Complexes with 2,2′-Bipyridine and Bis[2-(Diphenylphosphino)-Ethyl]Phenylphosphine (pages 317–321)

      A. R. Siedle, X. L. Luo and R. H. Crabtree

  10. Part 9: Chapter Nine Ligands And Other Main Group Compounds

    1. Hybrid Tertiary Phosphine Amine and Amide Chelate Ligands: N-[2-(Diphenylphosphino)-Phenyl]Benzamide and 2-(Diphenylphosphino)-N-Phenylbenzamide (pages 322–326)

      David Hedden, D. Max Roundhill, Bruce N. Storhoff and M. Brian Arnold

    2. 1,1-Dimethyl-N-(Trimethylsilyl)Ethanamine (pages 327–329)

      A. J. Nielson and B. L. Haymore

    3. Ethynylpentafluoro-λ6-Sulfane (SF5C≡CH) (pages 329–332)

      Robin J. Terjeson, Jo Ann Canich, Gary L. Gard, Mark R. Colsman, Mark A. Uremovich and Steven H. Strauss

    4. Iodine and Bromine Polysulfur Hexafluoroarsenate(V) and Hexafluoroantimonate(V) (pages 332–339)

      M. P. Murchie, J. Passmore, C.-M. Wong, T. Grelbig, K. Seppelt, M. Witt and H. W. Roesky

    5. Trimethylborane (pages 339–342)

      William S. Rees, Michael D. Hampton, Stephen W. Hall, Jerry L. Mills, Phillip Niedenzu and Sheldon G. Shore

    1. You have free access to this content
      Sources of Chemicals and Equipment (pages 343–344)

    1. You have free access to this content
      Index of Contributers (pages 345–349)

    1. You have free access to this content
      Subject Index (pages 351–372)

    1. You have free access to this content
      Formula Index (pages 373–433)

SEARCH