Inorganic Syntheses: Reagents for Transition Metal Complex and Organometallic Syntheses, Volume 28

Copyright © 1990 Inorganic Syntheses, Inc.

Inorganic Syntheses: Reagents for Transition Metal Complex and Organometallic Syntheses, Volume 28

Editor(s): Robert J. Angelici

Published Online: 5 JAN 2007

Print ISBN: 9780471526193

Online ISBN: 9780470132593

DOI: 10.1002/9780470132593

About this Book

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The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.

Table of contents

    1. You have free access to this content
      Frontmatter (pages i–xxiii)

  2. Part 1: Chapter One COMPLEXES WITH WEAKLY COORDINATED LIGANDS

    1. Metal Complexes with Weakly Bonded Anions: General Considerations (pages 1–4)

      Preface W. Beck

    2. Carbonyl(η5-Cyclopentadienyl)-(Tetrafluoroborato)Molybdenum and - Tungsten Complexes (pages 5–15)

      Wolfgang Beck, Klaus Schloter, Karlheinz Sünkel, Günter Urban, Thomas Forschner, Alicia Todaro and Alan Cutler

    3. Pentacarbonyl(Tetrafluoroborato)Rhenium and -Manganese and Reactions Thereof (pages 15–22)

      Wolfgang Beck, Klaus Raab, J. R. Shapley and B. R. Whittlesey

    4. Iridium(III) Complexes with the Weakly Bonded Anions [BF4]- and [Oso2CF3]- (pages 22–27)

      Wolfgang Beck, Herbert Bauer, Bernhard Olgemöller, Devereaux A. Clifford and Robert H. Crabtree

    5. cis-Chlorobis(Triethylphosphine)(Trifluoro- Methanesulfonato)Platinum (II) (pages 27–29)

      Wolfgang Beck, Bernhard Olgemöller, Luttgard Olgemöller, S. Chaloupka and L. M. Venanzi

    6. Tricarbonyltris(Nitrile) Complexes of Cr, Mo, and W (pages 29–33)

      Gregory J. Kubas, Lori Stepan Van Der Sluys, Ruth Ann Doyle and Robert J. Angelici

    7. The Synthesis of Molybdenum and Tungsten Dinitrogen Complexes (pages 33–43)

      Jonathan R. Dilworth, Raymond L. Richards, Grace J.-J. Chen and John W. Mcdonald

    8. trans-Bis[1,2-Ethanediylbis(Diphenyl- Phosphine)]Bis(Isocyanomethane)Tungsten(0) (pages 43–45)

      A. J. L. Pombeiro, R. L. Richards and B. I. Haymore

    9. Tricarbonyl(Cycloheptatriene)-Molybdenum(0) (pages 45–47)

      F. A. Cotton, J. A. Mccleverty, J. E. White, R. B. King, A. F. Fronzaglia and M. B. Bisnette

    10. Tetracarbonyl(η2-Methyl Acrylate)Ruthenium (pages 47–51)

      F.-W. Grevels, J. G. A. Reuvers, J. Takats and B. F. G. Johnson

    11. Reagents for the Synthesis of η-Diene Complexes of Tricarbonnyliron and Tricarbonylruthenium (pages 52–55)

      A. J. P. Domingos, J. A. S. Howell, B. F. G. Johnson, J. Lewis, N. Grice and R. Pettit

    12. Dihydridobis(Solvent)Bis(Triphenyl-Phosphine)Iridium(III) Tetrafluoroborates (pages 56–60)

      Robert H. Crabtree, Michelle F. Mellea, Jean M. Mihelcic, Ayusman Sen and Venkatasuryanaryana Chebolu

    13. Bis(Benzonitrile)Dichloro Complexes of Palladium and Platinum (pages 60–63)

      Gordon K. Anderson, Minren Lin, Ayusman Sen and Efi Gretz

    14. Acetonitrile Complexes of Selected Transition Metal Cations (pages 63–67)

      Richard R. Thomas, Ayusman Sen, Wolfgang Beck and Reich Leidl

    15. Tetrakis(Acetonitrile)Copper(1+) Hexafluorophosphate(1-) (pages 68–70)

      G. J. Kubas, B. Monzyk and A. L. Crumblis

    16. Trifluoromethanesulfonates and Trifluoromethanesulfonato-O Complexes (pages 70–76)

      Nicholas E. Dixon, Geoffrey A. Lawrance, Peter A. Lay, Alan M. Sargeson and Henry Taube

  3. Part 2: Chapter Two LOW-VALENT COMPLEXES OF RH, IR, NI, PD, AND PT

    1. Chlorotris(Triphenylphosphine)Rhodium(I)(Wilkinson'S Catalyst) (pages 77–79)

      J. A. Osborn, G. Wilkinson and J. J. Mrowca

    2. trans-Carbonylchlorobis(Triphenyl-Phosphine)Rhodium and Related Complexes (pages 79–80)

      D. Evans, J. A. Osborn, G. Wilkinson, Robert Paine, Jr. and R. W. Parry

    3. Hydrido Phosphine Complexes of Rhodium(I) (pages 81–83)

      N. Ahmad, J. J. Levison, S. D. Robinson, M. F. Uttley, E. R. Wonchoba and G. W. Parshall

    4. Tetracarbonyldichlorodirhodium (pages 84–86)

      J. A. Mccleverty, G. Wilkinson, Loren G. Lipson, Michael L. Maddox and Herbert D. Kaesz

    5. Di-μ-Chloro-Tetrakis(Ethene)Dirhodium(I): [Rh(Cl)(C2H4)2]2 (pages 86–88)

      Richard Cramer, J. A. Mccleverty and J. Bray

    6. Di-μ-Chloro-Bis(η4-1,5-Cyclooctadiene)-Dirhodium(I) (pages 88–90)

      G. Giordano, R. H. Crabtree, R. M. Heintz, D. Forster and D. E. Morris

    7. Chlorobis(Cyclooctene)Rhodium(I) and–Iridium(I) Complexes (pages 90–92)

      A. Van Der Ent, A. L. Onderdelinden and Robert A. Schunn

    8. trans-Carbonylchlorobis-(Triphenylphosphine)Iridium (pages 92–94)

      J. P. Collman, C. T. Sears, M. Kubota, Alan Davison, E. T. Shawl, John R. Sowa and Robert J. Angelici

    9. Bis(1,5-Cyclooctadiene)Nickel(0) (pages 94–98)

      R. A. Schunn, S. D. Ittel, M. A. Cushing, R. Baker, R. J. Gilbert and D. P. Madden

    10. Complexes of Nickel(0) (pages 98–104)

      Steven D. Ittel, H. Berke, H. Dietrich, J. Lambrecht, P. Härter, J. Opitz and W. Springer

    11. Tetrakis(Triethyl Phosphite)Nickel(0), Palladium(0), and Platinum(0) Complexes (pages 104–107)

      Max Meier, Fred Basolo, W. R. Kroll, D. Moy and M. G. Romanelli

    12. Tetrakis(Triphenylphosphine)Palladium(0) (pages 107–109)

      D. R. Coulson, L. C. Satek and S. O. Grim

    13. Tetrakis(tert-Butyl Isocyanide)Di-μ-Chlorodipalladium(I) (pages 110–113)

      M. F. Rettig, P. M. Maitlis, F. A. Cotton and T. R. Webb

    14. Two-Coordinate Phosphine Complexes of Palladium(0) and Platinum(0) (pages 113–119)

      T. Yoshida, S. Otsuka, D. G. Jones, J. L. Spencer, P. Binger, A. Brinkmann and P. Wedemann

    15. Three-Coordinate Phosphine Complexes of Platinum(0) (pages 119–121)

      T. Yoshida, T. Matsuda, S. Otsuka, G. W. Parshall, W. G. Peet, P. Binger, A. Brinkmann and P. Wedemann

    16. Tetrakis(Triethylphosphine)Platinum(0) (pages 122–123)

      T. Yoshida, T. Matsuda, S. Otsuka, G. W. Parshall and W. G. Peet

    17. Tris- and Tetrakis(Triphenylphosphine)-Platinum(0) (pages 123–126)

      R. Ugo, F. Cariati, G. La Monica and Joseph J. Mrowca

    18. Olefin Complexes of Platinum (pages 126–132)

      Louise E. Crascall, John L. Spencer, Ruth Ann Doyle and Robert J. Angelici

    19. Ethene Complexes of Bis(Trialkylphosphine)Platinum(0) (pages 132–135)

      R. A. Head, D. M. Roundhill and D. Hedden

  4. Part 3: Chapter Three SUBSTITUTED METAL CARBONYL COMPLEXES

    1. (η6-Arene)Tricarbonylchromium Complexes (pages 136–140)

      C. A. L. Mahaffy, P. L. Pauson, M. D. Rausch and W. Lee

    2. Zero-Valent Isocyanide Complexes of Chromium, Molybdenum, and Tungsten (pages 140–145)

      Michel O. Albers, Neil J. Coville, Haewon L. Uhm and Ian S. Butler

    3. cis-Bis(Diethyldithiocarbamato)Dinitrosyl-Molybdenum, Dibromotetracarbonyl-Molybdenum(II), and Di- and Tricarbonyl-Bis(Diethyldithiocarbamato)Molybdenum(II) (pages 145–147)

      J. A. Broomhead, J. Budge, W. Grumley and J. W. Mcdonald

    4. Hexacarbonylbis(η5-Cyclopentadienyl)Dichromium, Molybdenum, and Tungsten and their Analogs, M2(η5-C5H4r)2 (Co)6 (M = Cr, Mo, and W; R = H, Me Or PhCH2) (pages 148–150)

      A. R. Manning, Paul Hacket, Ralph Birdwhistell, Paul Soye, David C. Miller and Robert J. Angelici

    5. Pentacarbonylmanganese Halides (pages 154–159)

      Kenneth J. Reimer, Alan Shaver, Michael H. Quick and Robert J. Angelici

    6. Pentacarbonylrhenium Halides (pages 160–165)

      Steven P. Schmidt, William C. Trogler, Fred Basolo, Michael A. Urbancic and John R. Shapley

    7. Pentacarbonylhydridorhenium (pages 165–168)

      Michael A. Urbancic, John R. Shapley, Nancy N. Sauer and Robert J. Angelici

    8. Tetracarbonyliron(O) Complexes Containing Group V Donor Ligands (pages 168–173)

      Michel O. Albers, Eric Singleton, Neil J. Coville, Carlton E. Ash, Christine C. Kim and Marcetta Y. Darensbourg

    9. Bis(Phosphine) Derivatives of Iron Pentacarbonyl and Tetracarbonyl (Tri-tert-Butylphosphine)Iron(O) (pages 173–179)

      Michael J. Therien, William C. Trogler, Rosalice Silva and Marcetta Y. Darensbourg

    10. Zero-Valent Iron Isocyanide Complexes (pages 179–186)

      Michel O. Albers, Eric Singleton, Neil J. Coville, Arthur Y-J. Chen, Rusty Blanski and Herbert D. Kaesz

    11. Dicarbonyl(η5-Cyclopentadienyl)-(Thiocarbonyl)Iron(1+) Trifluoromethane-Sulfonate(1–) and Dicarbonyl(η5-Cyclo-Pentadienyl)[(Methylthio)Thiocarbonyl]Iron (pages 186–189)

      B. Duane Dombek, Moon-Gun Choi, Robert J. Angelici, Ian S. Butler and Daniel Cozak

    12. Tetracarbonylbis(η5-Cyclopentadienyl)-Diruthenium (pages 189–191)

      N. M. Doherty, S. A. R. Knox, M. J. Morris, C. P. Casey and G. T. Whiteker

  5. Part 3: Chapter Three Chapter Three SUBSTITUTED METAL CARBONYL COMPLEXES

    1. Cyclopentadienyl Metal Carbonyl Dimers of Molybdenum and Tungsten (pages 150–154)

      M. David Curtis, Michael S. Hay, Moon Gun Choi and Robert J. Angelici

  6. Part 4: Chapter Four METAL CARBONYL ANION COMPLEXES

    1. Sodium Hexacarbonylniobate(1-) (pages 192–195)

      Fausto Calderazzo, Guido Pampaloni and J. E. Ellis

    2. Dicarbonyl(η5-Cyclopentadienyl)Nitrosyl Complexes of Chromium, Molybdenum, and Tungsten (pages 196–198)

      Teen T. Chin, James K. Hoyano, Peter Legzdins, John T. Malito, Thomas Arnold and Basil I. Swanson

    3. Acetylpentacarbonylmanganese and Acetylpentacarbonylrhenium (pages 199–202)

      C. M. Lukehart, G. Paull Torrence, Jane V. Zeile, K. P. Darst, L. T. Warfield, B. Duane Dombek, Robert J. Angelici, J. A. Gladysz and J. C. Selover

    4. Sodium Carbonyl Ferrates, Na2[Fe(Co)4], Na2[Fe2(Co)8], and Na2[Fe3(Co)11]. Bis[μ-Nitrido-Bis(Triphenylphosphorus)(1 +)] Undeca-Carbonyltriferrate(2-), [(Ph3P)2N]2[Fe3(Co)11] (pages 203–207)

      Henry Strong, Paul J. Krusic, Joseph San Filippo, Scott Keenan and Richard G. Finke

    5. Dicarbonyl(η5-Cyclopentadienyl) (2-Methyl-1-Propenyl-kC1)Iron and Dicarbonyl(η5- Cyclopentadienyl)(η2-2-Methyl-1-Propene)Iron(1+) Tetrafluoroborate(1-) (pages 207–211)

      Myron Rosenblum, Warren P. Giering, Sari-Beth Samuels and Paul J. Fagan

    6. μ-Nitrido-Bis(Triphenylphosphorus) (1 +) Tetracarbonylrhodate(1 -) and μ-Nitrido-Bis(Triphenylphosphorus)(1 +) Tetra-Carbonyliridate(1 -), [(PPh3)2N][M(Co)4] (M = Rh, Ir) (pages 211–215)

      L. Garlaschelli, R. Della Pergola, S. Martinengo and J. E. Ellis

  7. Part 5: Chapter Five METAL CLUSTER COMPLEXES

    1. Polynuclear Ruthenium Complexes (pages 216–220)

      M. I. Bruce, C. M. Jensen, N. L. Jones, Georg Süss-Fink, Gerhard Herrmann and Vera Dase

    2. Tri- and Tetranuclear Carbonyl-Ruthenium Cluster Complexes Containing Isocyanide, Tertiary Phosphine, and Phosphite Ligands. Radical Ion-Initiated Substitution of Metal Cluster Carbonyl Complexes Under Mild Conditions (pages 221–230)

      Michael I. Bruce, Brian K. Nicholson, Michael L. Williams, Thérèse Arliguie and Guy Lavigne

    3. Dodecacarbonyltriosmium (pages 230–231)

      Simon R. Drake, Paul A. Loveday, Ruth Ann Doyle and Robert J. Angelici

    4. Some Useful Derivatives of Dodecacarbonyltriosmium (pages 232–235)

      J. N. Nicholls, M. D. Vargas, A. J. Deeming and S. E. Kabir

    5. μ-Nitrido-Bis(Triphenylphosphorus) (1+) μ-Carbonyl-Decacarbonyl-μ-Hydridotriosmate(1-) (pages 236–237)

      K. Burgess, R. P. White, S. Bassner, G. L. Geoffroy, R. L. Gray and D. J. Darensbourg

    6. Decacarbonyldi-μ-Hydridotriosmium: Os3(μ-H)2(Co)10 (pages 238–239)

      H. D. Kaesz, G. N. Glavee and R. J. Angelici

    7. Dodecacarbonyltetra-μ-Hydrido-Tetrahedro-Tetraosmium (pages 240–241)

      Camilo Zuccaro, G. Pamploni and F. Calderazzo

    8. Tri-μ-Carbonyl-Nonacarbonyltetra-Rhodium, Rh4(Co)9(μ-Co)3 (pages 242–245)

      S. Martinengo, G. Gxordano, P. Chini, G. W. Parshall and E. R Wonchoba

    9. Dodecacarbonyltetraidium: Ir4(Co)12 (pages 245–247)

      Roberto Della Pergola, Luigi Garlaschelli, Secondo Martinengo, Stephen Sherlock and Wayne Gladfelter

  8. Part 6: Chapter Six CYCLOPENTADIENYL COMPLEXES

    1. Dicarbonylbis(η5-Cyclopentadienyl) Complexes of Titanium, Zirconium, and Hafnium (pages 248–257)

      David J. Sikora, Kevin J. Moriarty, Marvin D. Rausch, A. Ray Bulls, John E. Bercaw, Vikram D. Patel and Arthur J. Carty

    2. (η5-Cyclopentadienyl)Hydridozirconium Complexes (pages 257–260)

      P. C. Wailes, H. Weigold, Jeffrey Schwartz and Chu Jung

    3. Cyclopentadienyl Complexes of Titanium(III) and Vanadium(III) (pages 260–263)

      L. E. Manzer, E. A. Mintz and T. J. Marks

    4. Vanadocene, Bis(η5-Cyclopentadienyl) Vanadium (pages 263–267)

      Carlo Floriani, Vladimir Mange, E. Kent Barefield and Michael W. Carris

    5. Dichlorobis(η5-Cyclopentadienyl) Niobium(IV) (pages 267–270)

      C. R. Lucas, J. A. Labinger and J. Schwartz

    6. Chloro(η5-Cyclopentadienyl)Bis(Triphenyl-Phosphine) Ruthenium(II): Rucl(PPh3)2(η5-C5H5) (pages 270–272)

      M. I. Bruce, C. Hameister, A. G. Swincer, R. C. Wallis and S. D. Ittel

    7. (η5-Pentamethylcyclopentadienyl)Cobalt complexes (pages 273–280)

      Steven A. Frith, John L. Spencer, W. E. Geiger and J. Edwin

    8. Cyclopentadienylbis(Trimethylphosphine) and Cyclopentadienylbis(Trimethylphosphite) Complexes of Co and Rh (pages 280–285)

      H. Werner, R. Feser, V. Harder, W. Hofmann, H. Neukomm and W. D. Jones

  9. Part 7: Chapter Seven LANTHANIDE AND ACTINIDE COMPLEXES

    1. Lanthanide Trichlorides by Reaction of Lanthanide Metals with Mercury(II) Chloride in Tetrahydrofuran (pages 286–291)

      Glen B. Deacon, Tran D. Tuong, Dallas L. Wilkinson and Tobin Marks

    2. (η5-Cyclopentadienyl)Lanthanide Complexes from the Metallic Elements (pages 291–297)

      Glen B. Deacon, Geoff N. Pain, Tran D. Tuong, William J. Evans, Keith R. Levan and Raul Dominguez

    3. Bis(η5-Pentamethylcyclopentadienyl)- Bis(Tetrahydrofuran)Samarium(II) (pages 297–300)

      William J. Evans, Tamara A. Ulibarri, Herbert Schumann and Siegbert Nickel

    4. Chlorotris (η5-Cyclopentadienyl) Complexes of Uranium(IV) and Thorium(IV) (pages 300–304)

      T. J. Marks, A. M. Seyam, W. A. Wachter, G. W. Halstead and K. N. Raymond

  10. Part 8: Chapter Eight LIGANDS AND OTHER TRANSITION METAL COMPLEXES

    1. Trimethylphosphine (pages 305–310)

      M. L. Luetkens, A. P. Sattelberger, H. H. Murray, J. D. Basil, J. P. Fackler, R. A. Jones and D. E. Heaton

    2. Phosphorus Trifluoride (pages 310–315)

      Ronald J. Clark, Helen Belefant and Stanley M. Williamson

    3. Cyclopentadienylthallium (pages 315–317)

      A. J. Nielson, C. E. F. Rickard, J. M. Smith and Bruce N. Diel

    4. 1,2,3,4,5-Pentamethylcyclopentadiene (pages 317–320)

      Juan M. Manriquez, Paul J. Fagan, Larry D. Schertz, Tobin J. Marks, John Bercaw and Nancy Mcgrady

    5. Anhydrous Metal Chlorides (pages 321–323)

      Alfred R. Pray, Richard F. Heitmiller, Stanley Strycker, Victor D. Aftandilian, T. Muniyappan, D. Choudhury and Milton Tamres

    6. Tungsten and Molybdenum Tetrachloride Oxides (pages 323–326)

      A. J. Nielson and R. A. Andersen

    7. Tungsten Chloro Phosphine Complexes (pages 326–332)

      Paul R. Sharp, Jeffrey C. Bryan, James M. Mayer, Joseph L. Templeton and Shaoguang Feng

    8. Tetrabutylammonium Octachlorodirhenate(III) (pages 332–334)

      T. J. Barder, R. A. Walton, F. A. Cotton and G. L. Powell

    9. Di-μ-Chloro-Bis[Tricarbonylchloro-Ruthenium(II)] (pages 334–336)

      A. Mantovani, S. Cenini, R. M. Heintz and D. E. Morris

    10. Dihydridotetrakis(Triphenylphosphine)-Ruthenium(II) (pages 337–338)

      R. Young, G. Wilkinson, S. Komiya and A. Yamamoto

    11. Tris(2,2″-Bipyridine)Ruthenium(II) Dichloride Hexahydrate (pages 338–340)

      John A. Broomhead, Charles G. Young and Pam Hood

    12. Dichlorobis[μ-Methylenebis (Diphenyl-Phosphine)]Dipalladium(I) (Pd–Pd) (pages 340–342)

      Alan L. Balch, Linda S. Benner and John D. Basil

    13. (η3-Allyl)Palladium(II) Complexes (pages 342–345)

      Yoshitaka Tatsuno, Toshikatsu Yoshida, Sei Otsuka, Najeeb Al-Salem and Bernard L. Shaw

    14. Cyclic Diolefin Complexes of Platinum and Palladium (pages 346–349)

      D. Drew, J. R. Doyle and Alan G. Shaver

    15. Potassium Trichloro(Ethene)Platinate(II) (Zeise's Salt) (pages 349–351)

      P. B. Chock, J. Halpern, F. E. Paulik, Saul I. Shupack and Thomas P. Deangelis

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      Index of Contributers (pages 353–360)

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      Subject Index (pages 361–386)

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      Formula Index (pages 387–463)

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