Inorganic Syntheses, Volume 29

Copyright © 1992 Inorganic Syntheses, Inc.

Inorganic Syntheses, Volume 29

Editor(s): Russell N. Grimes

Published Online: 5 JAN 2007

Print ISBN: 9780471544708

Online ISBN: 9780470132609

DOI: 10.1002/9780470132609

About this Book

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The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested.

Table of contents

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      Frontmatter (pages i–xxi)

  2. Part 1: Chapter One MAIN–GROUP COMPOUNDS—GENERAL

    1. Xenon Difluoride (Modification) (pages 1–4)

      Andrej Šmalc, Karel Lutar and Scott A. Kinkead

    2. Xenon Tetrafluoride (pages 4–6)

      Karel Lutar, Andrej Šmalc, Boris Žemva and Scott A. Kinkead

    3. Chlorine Pentafluoride (pages 7–8)

      Karel Lutar, Andrej Šmalc, Boris Žemva and Scott A. Kinkead

    4. Dioxygenyl Hexafluoroarsenate (pages 8–9)

      Andrej Šmalc, Karel Lutar and Scott A. Kinkead

    5. Peroxydisulfuryl Difluoride (Modification) (pages 10–11)

      Andrej Šmalc, Steven G. Mayorga and Neil Bartlett

    6. Krypton Difluoride (pages 11–15)

      Andrej Šmalc, Karel Lutar, Boris Žemva and Scott A. Kinkead

    7. Simple Preparation of Benzenethiolato and Benzeneselenolato Derivatives of Indium and Tin (pages 15–19)

      Rajesh Kumar, Hassan E. Mabrouk, Dennis G. Tuck, Edward Ganja and Thomas B. Rauchfuss

    8. Tetrakis (2,4,6–Trimethylphenyl)Disilene (Tetramesityldisilene) (pages 19–24)

      Robin P. Tan, Gregory R. Gillette, Howard B. Yokelson, Robert West and Philip Boudjouk

    9. Monoorganotin Phosphinate Clusters: The Oxygen-Capped Cluster [(n-BuSn(OH)O2PPh2)3O] [Ph2PO2] (1) and its Conversion to the Cubic Cluster [n-BuSn(O)O2PPh2]4(2) (pages 24–26)

      K. C. Kumara Swamy, Robert R. Holmes, Kenneth C. Carter and Christopher W. Allen

    10. (Triphenylphosphoranylidene)Sulfamoyl Chloride (pages 27–29)

      Dale E. Arrington and Arlan D. Norman

    11. Hexamethyldisilathiane (pages 30–32)

      Jeung-Ho So, Philip Boudjouk, Harry H. Hong and William P. Weber

    12. Addition of Sulfur Trioxide to Pentafluorothio (SF5) (Pentafluoro-λ6-Sulfanyl) Containing Fluoroolefins (pages 33–38)

      Javid Mohtasham, Robin J. Terjeson, Gary L. Gard, Robert A. Scott, Krishnan V. Madappat and Joseph S. Thrasher

    13. Pentafluoro(Isocyanato)-λ6-Sulfane (SF5N=C=O) (pages 38–40)

      Joseph S. Thrasher, Matthew Clark, Jon B. Nielsen, Carlos Alvarado, Mark T. Anderson, Günther Steinke, Thomas Meier and Rüdiger Mews

    14. Ambient-Pressure Superconducting Synthetic Metals β-(Bedt–TTF)2X, X = I3-, IBr2-, and AuI2- (pages 41–50)

      H. Hau Wang and Jack M. Williams

  3. Part 2: Chapter Two BORON COMPOUNDS

    1. Trimethylamine-Tribromoborane (pages 51–54)

      Milap A. Mathur, Dennis A. Moore, Ronald E. Popham, Harry H. Sisler, Shawn Dolan and Sheldon G. Shore

    2. 1,4-DI-tert-Butyl-2,6-Diisopropyl-3,5-Bis(Trimethylsilyl)-3,5- Diaza-nido-Hexaborane(6) (pages 54–57)

      P. Paetzold, B. Redenz-Stormanns and N. S. Hosmane

    3. Polycyclic Borazines (pages 57–60)

      D. T. Haworth, G.-Y. Lin Kiel, Lee J. Todd and Mark W. Baize

    4. 1,5-Cyclooctanediylborylsulfides (pages 60–69)

      Roland Köster, Günter Seidel, Walter Siebert and Bernd Gangnus

    5. 1,5-Cyclooctanediylborylselenides (pages 70–77)

      Roland Köster, Günter Seidel, Mohamed Yalpani, Walter Siebert and Bernd Gangnus

    6. Trimethylamine-Diethyl-1-Propynylborane and Diethyl-1-Propynylborane (pages 77–82)

      Roland Köster, Heinz Josef Horstschäfer, Günter Seidel, Walter Siebert and Bernd Gangnus

    7. Pentaethyl-1,5-Dicarba-closo-Pentaborane(5) and Decaethyl-2,6,8,10-Tetracarba-nido-Decaborane(10) (pages 82–89)

      Roland Köster, Günter Seidel, Heinz Josef Horstschäfer, Walter Siebert and Bernd Gancnus

    8. Trimethylsilyl-Substituted Derivatives of 2,3-Dicarba-nido-Hexaborane(8) and Lithium, Sodium, and Dilithium Salts of the Carborane Dianion 2,3-Bis(Trimethylsilyl)-2,3-Dicarba-nido-Hexaborate(2–) (pages 89–101)

      Reynaldo D. Barreto, Narayan S. Hosmane, Mark A. Benvenuto and Russell N. Grimes

    9. 1,2-(1,2-Ethanyldiyl)-1,2-Dicarbadodecaborane(12) (1,2-Ethano-o-Carborane) (pages 101–103)

      Maitland Jones, Zhen-Hong Li, Robert P. L'Esperance and Kenneth Wade

    10. 7,9-Diselena-nido-Undecaborane(9) (pages 103–105)

      G. D. Friesen, T. P. Hanusa, L. J. Todd and L. G. Sneddon

    11. 6,9-Diselena-Arachno-Decaborane(10) (pages 105–107)

      G. D. Friesen, R. L. Kump, L J. Todd and L. G. Sneddon

  4. Part 3: Chapter Three TRANSITION METAL COORDINATION COMPOUNDS

    1. Solvated and Unsolvated Anhydrous Metal Chlorides from Metal Chloride Hydrates (pages 108–111)

      Philip Boudjouk, Jeung-Ho So, Marlin N. Ackermann, Susan E. Hawley and Benjamin E. Turk

    2. Solid Solvates: The Use of Weak Ligands in Coordination Chemistry (pages 111–118)

      Willem L. Driessen, Jan Reedijk, Kim R. Dunbar and Laura E. Pence

    3. Niobium(III) and (IV) Halide Complexes (pages 119–123)

      Steven F. Pedersen, Jack B. Hartung, Eric J. Roskamp, Peter S. Dragovich, Charles J. Ruffing and Bruce A. Klein

    4. Chromium(V) Fluoride and Chromium(VI) Tetrafluoride Oxide (pages 124–127)

      S. P. Mallela, Jean'ne M. Shreeve and Darryl D. DesMarteau

    5. Ammonium Hexachloromolybdate(III) (pages 127–129)

      Takashi Shibahara, Mikio Yamasaki, Abdul K. Mohammed and Andrew W. Maverick

    6. Dioxobis(2,4-Pentanedionato)Molybdenum(VI), MoO2(acac)2 and μ-Oxodioxotetrakis(2,4-Pentanedionato)Dimolybdenum)(V), Mo2O3 (acac)4 (pages 129–134)

      Mukul C. Chakravorti, Debasis Bandyopadhyay, Malcolm H. Chisholm and Charles E. Hammond

    7. Decakis(Acetonitrile)Dimolybdenum(II) Tetrafluoroborate(1—) (pages 134–137)

      F. Albert Cotton and Kenneth J. Wiesinger

    8. Hexakis(Dimethylamido)Ditungsten and Tungsten(IV) Chloride (pages 137–140)

      Malcolm H. Chisholm, James D. Martin, John E. Hill and Ian P. Rothwell

    9. Tetracarbonyl[1,2-Ethanediylbis-(Diphenylphosphine)]Tungsten(0), fac-(Acetone)Tricarbonyl[1,2-Ethanediylbis-(Diphenylphosphine)]Tungsten(0), and mer-Tricarbonyl[1,2-Ethanediylbis-(Diphenylphosphine)](Phenylvinylidene)Tungsten(0) (pages 141–146)

      Kurt R. Birdwhistell, Anne C. Dema, Xiahou Li, C. M. Lukehart and Margaret D. Owen

    10. Nitrido and Oxo Complexes of Rhenium(V) (pages 146–150)

      B. Patrick Sullivan, John C. Brewer, Harry B. Gray, Douglas Linebarrier and James M. Mayer

    11. trans-Tricarbonylbis(Phosphine)Iron(0) Complexes: One-Pot Syntheses from Pentacarbonyliron (pages 151–156)

      J.-J. Brunet, F. B. Kindela, D. Neibecker, S. A. Wander and M. Y. Darensbourg

    12. Dicarbonyl -cis-Dihydrido-trans-Bis(Phosphite)Iron(II) Complexes: One-Pot Syntheses from Pentacarbonyliron (pages 156–160)

      J.-J. Brunet, F. B. Kindela, D. Neibecker, S. A. Wander and M. Y. Darensbourg

    13. Thionitrosyl Complexes of Ruthenium(II) (pages 161–164)

      K. C. Jain, U. C. Agarwala, T. W. Dekleva, P. Legzdins and J. C. Oxley

    14. trans-Dichloro Tetramine Complexes of Ruthenium(III) (pages 164–167)

      Chi-Ming Che, Tai-Chu Lau, Chung-Kwong Poon, Jill Grantham and Thomas G. Richmond

    15. trans-Dichlorobis(1,2- Ethanediamine)Cobalt(III) Chloride (pages 167–168)

      W. Gregory Jackson, Stanley Kirschner, Thaddeus J. Gish and Steven Barber

    16. Resolution of the Dodecaamminehexa-μ-Hydroxo-Tetracobalt(III) Ion (pages 169–174)

      Takaji Yasui, Tomoharu Ama, George B. Kauffman, Dušan J. Radanović and Miloš I. Djuran

    17. Tricarbonyl Phosphine, Phosphite, and Arsine Derivatives of Cobalt(I) (pages 174–182)

      Christa Loubser, Simon Lotz and John E. Ellis

    18. Decakis(Acetonitrile)Dirhodium(II) Tetrafluoroborate (pages 182–185)

      Kim R. Dunbar, Laura E. Pence, Joanna Czuchajowska and F. Albert Cotton

    19. (2,2′-Bipyridine)Dichloropalladium(II) and [N′-(2-Diaminoethyl)-1,2-Ethanediamine]Chloropalladium(II) Chloride (pages 185–187)

      F. L. Wimmer, S. Wimmer, P. Castan and Richard J. Puddephatt

    20. trans-Dicarbonyl-Di-μ-Iodo-Diiododiplatinum(II) (pages 188–189)

      Bianca Patrizia Andreini, Daniela Belli Dell'Amico, Fausto Calderazzo, Nicola Pasqualetti, Allen L. Seligson and William C. Trogler

    21. Chlorohydridobis(Trialkylphosphine)-Platinum(II) Complexes (pages 189–192)

      Julia R. Phillips, William C. Trogler, Mick Brammer and Dianne L. Packett

  5. Part 4: Chapter Four TRANSITION METAL ORGANOMETALLICS AND LIGANDS

    1. Large-Scale Synthesis of 1,2,3,4,5-Penta-Methylcyclopentadiene (pages 193–198)

      Carol M. Fendrick, Larry D. Schertz, Eric A. Mintz, Tobin J. Marks, T. E. Bitterwolf, P. A. Horine, T. L. Hubler, J. A. Sheldon and D. D. Belin

    2. Dichlorobis(η5-Chlorocyclopentadienyl)-Titanium, (ClC5H4)2TiCl2 (pages 198–201)

      Eric A. Anslyn, Robert H. Grubbs, Christian Felten and Dieter Rehder

    3. η3-Allylhydridobis[Ethylenebis (Diphenylphosphine)]Molybdenum(II) (pages 201–203)

      Christopher J. Bischoff, John M. Hanckel, Maria M. Ludvig, Marcetta Y. Darensbourg, M. Maciejewski and M. Rakowski Dubois

    4. Bis(η5-Cyclopentadienyl)Molybdenum(IV) Complexes (pages 204–211)

      Ned D. Silavwe, Michael P. Castellani, David R. Tyler, Mark A. Beck, Joseph D. Lichtenhan and Nancy M. Doherty

    5. Cyclopentadienyl Rhenium Complexes (pages 211–225)

      Francine Agbossou, Edward J. O'Connor, Charles M. Garner, N. Quirós Méndez, Jesús M. Fernández, Alan T. Patton, James A. Ramsden, J. A. Gladysz, Joseph M. O'Connor, Tracy Tajima and Kevin P. Gable

    6. Di-μ-Chloro-Bis[(η5-Pentamethylcyclopentadienyl) Chlororuthenium(III)], [Cp*RuCl2]2 and Di-μ-methoxo-Bis(η5-Pentamethylcyclopentadienyl)diruthenium(II), [Cp*RuOMe]2 (pages 225–228)

      U. Koelle, J. Kossakowski, D. Grumbine and T. Don Tilley

    7. (η5-Pentamethylcyclopentadienyl)Rhodium and -Iridium Compounds (pages 228–234)

      C. White, A. Yates, P. M. Maitlis and D. M. Heinekey

    8. Bis(η5-Cyclopentadienyl)Bis(Diethylamido)Uranium(IV) and Tris(η5-Cyclopentadienyl) (Diethylamido)Uranium(IV) (pages 234–238)

      F. Ossola, G. Rossetto, P. Zanella, A. Arudini, J. D. Jamerson, J. Takats and A. Dormond

  6. Part 5: Chapter Five CLUSTER AND CAGE COMPOUNDS CONTAINING TRANSITION METALS

    1. Disodium Tris(Tetrabutylammonium) [β-Hexatricontaoxo (μ12-Tetraoxosilicato) (10,11,12-Triniobiumnonatungsten)Ato (7–)] (η5-Pentamethylcyclopentadienyl) Rhodate (5–), Na2(Bu4N)3[Rh[β-Nb3 SiW9O40]{η5-C5(CH3)5}] (pages 239–247)

      R. G. Finke, K. Nomiya, C. A. Green, M. W. Droege and A. R. Siedle

    2. η5-Cyclopentadienylchromium Complexes of Phosphorus, Tetracarbonyl-μ-Diphosphido-Bis(η5-Cyclopentadienylchromium), [CpCr(CO)2]2(μ-η2-P2) and Dicarbonyl-Cyclotriphosphido-(η5-Cyclopentadienylchromium), CpCr(CO)2(η3-P3) (pages 247–250)

      Lai Yoong Goh, Richard C. S. Wong, O. J. Scherer and A. Schneider

    3. η5-Cyclopentadienylchromium Complexes of Sulfur (pages 251–254)

      Lai Yoong Goh, Marcetta Y. Darensbourg and Yui-May Hsiao

    4. Sulfur-Bridged Dinuclear Molybdenum(V) Complexes with Mo2O3S and Mo2O2S2 Cores (pages 254–260)

      Takashi Shibahara, Haruo Akashi, Andreas Toupadakis and Dimitri Coucouvanis

    5. Sulfur-Bridged Cubane-Type (Mo4S4) and Incomplete Cubane-Type (Mo3O4 – nSn; n = 1–4) Molybdenum Aqua Ions (pages 260–269)

      Takashi Shibahara, Haruo Akashi, Andreas Toupadakis and Dimitri Coucouvanis

    6. Preparation of Dinuclear and Trinuclear Ferraboranes, Fe2 (CO)6B2H6 and Fe3H(CO)10BH2 (pages 269–273)

      Xiangsheng Meng, Thomas P. Fehlner and Kenton H. Whitmire

    7. Preparation of the Metal- and Hydrogen-Rich Ferraborane Fe3H(CO)9BH4 (pages 273–275)

      Xiangsheng Meng, Thomas P. Fehlner and Kenton H. Whitmire

    8. Tetrammonium Hexakis[Tetraethyl-2,3-Dioxobutane-1,1,4,4-Tetracarboxylato(2–)- O1′,O2:O3,O4′]Tetrametalate(4–) (pages 275–278)

      Rolf W. Saalfrank, Armin Stark, Roman Burak, Will E. Lynch and Richard L. Lintvedt

    9. Mixed-Metal-Gold Phosphine Cluster Compounds (pages 279–298)

      A. M. Mueting, B. D. Alexander, P. D. Boyle, A. L. Casalnuovo, L. N. Ito, B. J. Johnson, L. H. Pignolet, M. Leeaphon, K. E. Meyer, R. A. Walton, D. M. Heinekey and T. G. P. Harper

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      Index of Contributers (pages 299–308)

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      Subject Index (pages 309–340)

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      Formula Index (pages 341–427)

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