Inorganic Syntheses, Volume 32

Copyright © 1998 by John Wiley & Sons, Inc.

Inorganic Syntheses, Volume 32

Editor(s): Marcetta. Y. Darensbourg

Published Online: 5 JAN 2007

Print ISBN: 9780471249214

Online ISBN: 9780470132630

DOI: 10.1002/9780470132630

About this Book

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The Inorganic Synthesis Series provides all users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely compounds. This new volume includes information on water-solubilizing ligands for organometallics, labile ligand complexes, and the syntheses of cluster compounds and hydrides.

Table of contents

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      Frontmatter (pages i–xxiii)

  2. Part 1: Chapter one LIGANDS FOR WATER-SOLUBILIZING ORGANOMETALLIC COMPOUNDS

    1. (Meta- Sulfonatophenyl) Diphenylphosphine, Sodium Salt and its Complexes with Rhodium(I), Ruthenium(II), Iridium(I) (pages 1–8)

      Ferenc Joó, József Kovács, Ágnes Kathó, Attila C. Bényei, Tara Decuir, Donald J. Darensbourg, Alex Miedaner and Daniel L. Dubois

    2. Syntheses of Water-Soluble Phosphines and their Transition Metal Complexes (pages 8–25)

      Wolfgang A. Herrmann, Christian W. Kohlpaintner, Brian E. Hanson and Xianxing Kang

    3. Tris[tris(Sodium m-sulfonatophenyl)-Phosphino]Palladium(0) Enneahydrate (pages 25–29)

      G. Papadogianakis, L. Maat, R. A. Sheldon, C. J. Bishoff and B. D. Doggett

    4. Sulfonated Phosphines (pages 29–36)

      Hao Ding, Barbara B. Bunn, Brian E. Hanson, Robert W. Eckl, Christian W. Kohlpaintner and Wolfgang A. Herrmann

    5. (S,S)-2,3-Bis[Di(m-Sodiumsulfonatophenyl)-Phosphino]Butane (Chiraphosts) and (S,S)-2,4-Bis[Di(m-Sodiumsulfonatophenyl)- Phosphino]Pentane (BDPPts) (pages 36–40)

      D. Sinou, J. Bakos, D. J. Darensbourg and F. Beckford

    6. 1,3,5-Triaz-7-Phosphatricyclo[3.3.1.13,7]Decane and Derivatives (pages 40–45)

      Donald J. Daigle, Tara J. Decuir, Jeffrey B. Robertson and Donald J. Darensbourg

  3. Part 2: Chapter two BIOMIMETIC AND SPECIAL PROPERTY LIGANDS

    1. 2,2′:6′,2″-Terpyridine (pages 46–50)

      Donald L. Jameson, Lisa E. Guise, Carol A. Bessel and Kenneth Takeuchi

    2. Poly(1-Pyrazolyl)Alkane Ligands (pages 51–63)

      Donald L. Jameson, Ronald K. Castellano, Daniel L. Reger, James E. Collins, William B. Tolman and Christopher J. Tokar

    3. Tris [N-(3-tert-Butyl) Pyrazolyl] methane (pages 63–65)

      Daniel L. Reger, James E. Collins, Donald L. Jameson, Ronald K. Castellano, Allan J. Canty and Hong Jin

    4. Tris[2-(1,4-Diisopropylimidazolyl]Phosphine. (pages 66–70)

      Thomos N. Scrrell, William E. Allen, Gerard Parkin and Clare Kimblin

    5. Tris[(2-Pyridyl)Methyl] Amine (TPA) and (+)-Bis[(2-Pyridyl)methyl]-1-(2-Pyridyl)-Ethylamine (α-Metpa) (pages 70–75)

      James W. Canary, Yihan Wang, Richard Roy, Lawrence Que, and Hiroyuki Miyake

    6. C2-Symmetric 1,4-Diisopropyl-7-R-1,4,7-Triazacyclononanes (pages 75–81)

      Jason A. Halfen, William B. Tolman and Karl Weighardt

    7. N-(2-Hydroxyethyl)-3,5-Dimethylpyrazole, a Dinuclear Copper Complex, and N-(2-P-Toluenesulfonylethyl)-3,5-Dimethylpyrazole (pages 82–87)

      Elisabeth Bouwman, Willem L. Driessen, Jeehee Kang and Marcetta Y. Darensbourg

    8. N-(2-Mercaptoethyl)-3,5-Dimethylpyrazole (pages 87–89)

      Elisabeth Bouwman, Jan Reedijk, Jeehee Kang and Marcetta Y. Darensbourg

    9. 1,5-Diazacyclooctane, Pendant Arm Thiolato Derivatives and [N,N′ -Bis(2-Mercaptoethyl)-1,5-Diazacyclooctanato]Nickel(II) (pages 89–98)

      Daniel K. Mills, Ivan Font, Patrick J. Farmer, Yui-May Hsiao, Thawatchai Tuntulani, Rizalia M. Buonomo, Dawn C. Goodman, Ghezai Musie, Craig A. Grapperhaus, Michael J. Maguire, Chia-Huei Lai, Michelle L. Hatley, Jason J. Smee, John A. Bellefeuille, Marcetta Y. Darensbourg, Robert D. Hancock, Sheila Eng and Arthur E. Martell

    10. Polydentate Thiolate and Selenolate Ligands, RN(CH2CH2S(Se)-)2, and their Dimeric and MOnonuclear Ni(II) Complexes (pages 98–107)

      Suranjan B. Choudhury, Christian B. Allan, Michael J. Maroney, Alden D. Woodward and C. Robert Lucas

    11. Poly[(Methylthio)Methyl]Borates and Representative Metal Derivatives (pages 108–113)

      Charles G. Riordan, Pinghua Ge, Carl Ohernberg and Wen-Feng Liaw

    12. Polyaza Binucleating Ligands: Obistren and Obisdien (pages 113–120)

      Arthur E. Martell, Dian Chen and Kristen Bowman-James

    13. N,N′-Bis(2-Hydroxybenzyl)Ethylendiamine-N,N′-Diacetic Acid (HBED) (pages 120–122)

      Arthur E. Martell, Ichiro Murase and Kristen Bowman James

    14. N-Tert-Alkyl-anilides as Bulky Anciliary Ligands (pages 123–132)

      Adam R. Johnson, Christopher C. Cummins and Sandro Gambarotta

    15. 1,2-Bis(Dichlorophsophino)-1,2-Dimethylhydrazine and Alkoxy/Aryloxy Derivatives (pages 132–136)

      V. Sreenivasa Reddy, Kattesh V. Katti, Robert H. Neilson and Junmin Ji

    16. Tris[(tert-Butylamino)-Dimethylsilyl]-Methylsilane and its Precursors (pages 136–140)

      Bernd Findeis, Martin Schubart, Lutz H. Gade and Joyce Corey

  4. Part 3: Chapter three TRANSITION METAL COMPLEXES AND PRECURSORS

    1. Facile Synthesis of Isomerically Pure cis-Dichlorodiammineplatinum(II), Cisplatin (pages 141–144)

      Vadim Yu. Kukushikin, Åke Oskarsson, Lars I. Elding, Nicholas Farrell, Stephen Dunham and Stephen J. Lippard

    2. cis-Bis(Benzenacetonitrile)Dichloro-Platinum(II) and trans-Bis(Benzeneaetonitrile)-Dichloroplatinum(II) (pages 144–148)

      Vadim Yu. Kukushkin, Valentina M. Tkachuk, Nikolay V. Vorobiov-Desiatovsky, Stanislav Chaloupka and Luigi M. Venanzi

    3. Platinum(II) Complexes of Dimethyl Sulfide (pages 149–153)

      Geoffrey S. Hill, Michael J. Irwin, Christopher J. Levy, Louis M. Rendina, Richard J. Puddephatt, Richard A. Andersen and Luis Mclean

    4. (2,2′: 6′,2″-Terpyridine)Methylplatinum(II) Chloride and (1,10-Phenanthroline)-Methylchloroplatinum(II) (pages 153–158)

      Raffaello Romeo, Luigi Monsu′ Scolaro, Vincent Catalano and Sudhir Achar

    5. (N,N-chelate)(Olefin) Platinum (O) Complexes (pages 158–162)

      Francesco Ruffo, Augusto De Renzi, Achille Panunzi, Robert G. Bergman and William H. Howard

    6. Dimethylpalladium(II) and Monomethylpalladium(II) Reagents and Complexes (pages 162–172)

      Peter K. Byers, Allan J. Canty, Hong Jin, Dennis Kruis, Bertus A. Markies, Jaap Boersma, Gerard Van Koten, Geoffrey S. Hill, Michael J. Irwin, Louis M. Rendina and Richard J. Puddephatt

    7. 2,4-Pentanedionatogold(I) Complexes and 2,4-Pentanedionatothallium (pages 172–177)

      Jose Vicente, Maria-Teresa Chicote, Rosa M. Dávila, Matthew S. Adrian and John P. Fackler

    8. Tetrakis(Pyridine)Silver(2+)Peroxydisulfate (pages 177–181)

      George B. Kauffman, Richard A. Houghten, Robert E. Likins, Philip L. Posson, R. K. Ray, John P. Fackler and R. Theron Stubbs

    9. One-Pot Synthesis of Tetrahydronium Tris(4,4′-Dicarboxylato-2,2′-Bipyridine)-Ruthenium(II) Dihydrate (pages 181–186)

      M. D. K. Nazeeruddin, K. Kalyanasundaram, M. Grátzel, B. Patrick Sullivan and Kevin Morris

    10. Trichloro[2,2′:6′,2″-Terpyridine]Ruthenium(III) and Phosphine Ligand Derivatives (pages 186–198)

      Carol A. Bessel, Randolph A. Leising, Lisa F. Szczepura, Willie J. Perez, My Hang Vo Huyhn, Kenneth J. Takeuchi, Karen J. Brewer and Sumner W. Jones

    11. Monomeric Tetrahydrofuran-Stabilized Molybdenum(III) Halides (pages 198–203)

      Rinaldo Poli, Steven T. Krueger, Sundeep P. Mattamana, Kim R. Dunbar and Zhao Hanhua

    12. Facial Molybdenum(III) Triammine Complexes (pages 203–207)

      Claus J. H. Jacobsen, Karina K. Klinke, Jens Hyldtoft, Jørgen Villadsen and Rinaldo Poli

    13. High-Valent Mono-(N5-Pentamethylcyclo-Pentadienyl)Vanadium and Molybdenum Complexes (pages 207–214)

      Colin D. Abernethy, Frank Bottomley, Jinhua Chen, Michael F. Kemp, Tammy C. Mallais, Olusola O. Womiloju, Sunita Thyagarajar and Klaus H. Theopold

    14. Monoindenyltrichloride Complexes of Titanium(IV), Zirconium(IV), and Hafnium(IV) (pages 215–221)

      Robert J. Morris, Scott L. Shaw, Jesse M. Jefferis, James J. Storhoff, Dean M. Goedde, Stephen L. Buchwald and Bain Chin

    15. Labile Copper (I) Chloride Complexes: Preparation and Handling (pages 222–228)

      Mikael Hakansson, Sharon Niezgoda and Donald J. Darensbourg

  5. Part 4: Chapter four MAIN GROUP AND TRANSITION METAL CLUSTER COMPOUNDS

    1. 7,8-Dicarbaundecaborane(13) (pages 229–231)

      Gregory G. Hlatky, Donna J. Crowther, Richard F. Jordan and Daniel E. Bowen

    2. Borazine, Polyborazylene, β-Vinylborazine, and Poly(β-Vinylborazine) (pages 232–242)

      Thomas Wideman, Paul J. Fazen, Anne T. Lynch, Kai Su, Edward E. Remsen, Larry G. Sneddon, Tuqiang Chen and Robert T. Paine

    3. Transition Metal Complexes of the Lacunary Heteropolytungstate, [P2W17O61]10- (pages 242–268)

      William J. Randall, David K. Lyon, Peter J. Domaille, Richard G. Finke, Alexander M. Khenkin and And Craig Hill

    4. Bis(triphenylphosphoranylidene)Ammonium μ-Carbonyl-1kC 2kC-Decacarbonyl-lk3C,2k3,3k4C-μ-Hydrido-lK:2k-triangulo-Triruthenate(1-) (pages 268–270)

      Alain Béguin, Jean-Marc Soulié, Georg Süss-Fink, Jerome B. Keister and David J. Bierederman

    5. Dipotassium Undecacarbonyl Trimetallate(2—) Clusters, K2 [M3(co)11] (M = Ru, Os) (pages 270–276)

      Tim J. Coffy, Deborah A. Mccarthy, Edwin P. Boyd, Sheldon G. Shore, D. F. Shriver and R. Eveland

    6. [PPN]2[Ru3(CO)11] and [PPN]2[Os3(CO)11], μ-Nitrido-Bis(Triphenylphosphorus)(1+) Undecacarbonyltriruthenate(2—) and Undecacarbonyltriosmate(2—) (pages 276–280)

      G. B. Karet, E. J. Voss, M. J. Sailor, D. F. Shriver, E. Rosenberg and D. S. Kolwaite

    7. Platinum–ruthenium Carbonyl Cluster Complexes (pages 280–284)

      R. D. Adams, T. S. Barnard, J. E. Cortopassi, W. Wu, Z. Li, J. R. Shapley and Kwangyeal Lee

    8. Tri(μ-carbonyl)Nonacarbonyltetrarhodium, Rh4(μ-CO)3(CO)9 (pages 284–287)

      P. H. Serp, P. H. Kalck, R. Feurer, R. Morancho, Kwang Yeol Lee and John R. Shapley

    9. High Nuclearity Hydridodecaruthenium Clusters (pages 287–293)

      Marie P. Cifuentes, Mark G. Humphrey, John R. Shapley and Kwangyeol Lee

  6. Part 5: Chapter five MAIN GROUP AND TRANSITION METAL HYDRIDES

    1. Dichlorodihydro(N,N,N′,N′, -Teraethyl-1,2-Ethanediamine-N,N′)Silicon (pages 294–297)

      Steven D. Kloos, Philip Boudjouk, Li Guo and Claire A. Tessier

    2. Tricarbonyl(Hydrido) [1,2-Bis (Diphenyl-phosphino)Ethane]Manganese as Precursor to Labile Site Derivatives (pages 298–302)

      Milton Orchin, Sandosh K. Mandal, Julian Feldman, Way-Zen Lee and Donald J. Darensbourg

    3. Pentahydridobis(Tricyclohexylphosphine)-Iridium(V) and Trihydridotris(Triphenylphos-phine)Iridium(III) (pages 303–308)

      Susanne Brinkmann, Robert H. Morris, Ravindranath Ramachandran, Sung-Han Park, Robert H. Crabtree, Ben P. Patel and Bradford J. Pistorio

  7. Part 6: Chapter six TITANIUM(III) CHLORIDE

    1. An Active form of Titanium(III) Chloride (pages 309–310)

      Ann R. Hermes, Gregory S. Girolami and Richard A. Andersen

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      Contributer Index (pages 311–313)

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      Subject Index (pages 314–322)

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      Formula Index (pages 223–327)

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      Chemical Abstracts Service Registry Number Index (pages 328–331)

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