Silicon Chemistry: From the Atom to Extended Systems

Copyright © 2003 Wiley-VCH Verlag GmbH & Co. KGaA

Silicon Chemistry: From the Atom to Extended Systems

Editor(s): Peter Jutzi, Ulrich Schubert

Published Online: 31 MAY 2007

Print ISBN: 9783527306473

Online ISBN: 9783527610761

DOI: 10.1002/9783527610761

About this Book

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About The Product

The combined results from an international research project involving 40 interdisciplinary groups, providing the latest knowledge from the past few years. Adopting an application-oriented approach, this handy reference is a must-have for every silicon chemist, whether working in inorganic, organic, physical or polymer chemistry, materials science or physics.

Table of contents

    1. You have free access to this content
      Front Matter (pages I–XI)

  2. Part I: Reactive Intermediates in Silicon Chemistry – Synthesis, Characterization, and Kinetic Stabilization

    1. You have free access to this content
      Part Introduction (pages 1–3)

  3. Part I: Reactive Intermediates in Silicon Chemistry - Synthesis, Characterization, and Kinetic Stabilization

    1. Chapter 1

      Investigations on the Reactivity of Atomic Silicon: A Playground for Matrix Isolation Spectroscopy (pages 4–19)

      G. Maier, H. P. Reisenauer, H. Egenolf and J. Glatthaar

    2. Chapter 2

      Reactions with Matrix-Isolated SiO Molecules (pages 20–32)

      Hansgeorg Schnöckel and Ralf Köppe

    3. Chapter 3

      In situ Diagnostics of Amorphous Silicon Thin Film Deposition (pages 33–43)

      H. Stafast, G. Andrä, F. Falk and E. Witkowicz

    4. Chapter 4

      The Gas Phase Oxidation of Silyl Radicals by Molecular Oxygen: Kinetics and Mechanisms (pages 44–57)

      T. Köcher, C. Kerst, G. Friedrichs and F. Temps

    5. Chapter 5

      Oxidation of Matrix-Isolated Silylenes (pages 58–70)

      Wolfram Sander, Holger F. Bettinger, Holger Bornemann, Martin Trommer and Magdalene Zielinski

    6. Chapter 6

      Short-Lived Intermediates with Double Bonds to Silicon: Synthesis by Flash Vacuum Thermolysis, and Spectroscopic Characterization (pages 71–84)

      H. Beckers

    7. Chapter 7

      Kinetic Stabilization of Di-Silenes >Si=Si< and Di-Silynes –Si≡Si– (pages 85–99)

      Nils Wiberg

    8. Chapter 8

      A Tetrasilabuta-1,3-diene and Related Compounds with Conjugated Multiple Bonds (pages 100–113)

      Manfred Weidenbruch

  4. Part II: Si-Si Systems: From Molecular Building Blocks to Extended Networks

    1. Chapter 9

      Chemistry of Metalated Oligosilanes (pages 118–128)

      Roland Fischer, Dieter Frank, Christian Kayser, Christian Mechtler, Judith Baumgartner and Christoph Marschner

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      Part Introduction (pages 115–117)

    3. Chapter 10

      Oligosilyl Substituted Heptaphosphanes – Syntheses, Reactions and Structures (pages 129–138)

      Judith Baumgartner, Vittorio Cappello, Alk Dransfeld and Karl Hassler

    4. Chapter 11

      Polysilanes: Formation, Bonding and Structure (pages 139–158)

      Richard G. Jones

    5. Chapter 12

      Phase Behavior of n-Alkyl-substituted Polysilanes (pages 159–170)

      Christian Mueller, Christine Peter, Holger Frey1 and Claudia Schmidt

    6. Chapter 13

      Structural and Electronic Systematics in Zintl Phases of the Tetrels (pages 171–180)

      Reinhard Nesper

    7. Chapter 14

      Zintl Phases MSi2 (M = Ca, Eu, Sr, Ba) at Very High Pressure (pages 181–193)

      Jürgen Evers and Gilbert Oehlinger

    8. Chapter 15

      Silicon- and Germanium-Based Sheet Polymers and Zintl Phases (pages 194–213)

      Martin S. Brandt, Günther Vogg and Martin Stutzmann

    9. Chapter 16

      Kautsky-Siloxene Analogous Monomers and Oligomers (pages 214–225)

      Harald Stüger

    10. Chapter 17

      Silicon-Based Nanotubes: A Theoretical Investigation (pages 226–241)

      Th. Köhler, G. Seifert and Th. Frauenheim

    11. Chapter 18

      Structure and Reactivity of Solid SiO (pages 242–251)

      Ulrich Schubert and Thomas Wieder

    12. Chapter 19

      Si Nanocrystallites in SiOx Films by Vapour Deposition and Thermal Processing (pages 252–254)

      Herbert Hofmeister and Uwe Kahler

    13. Chapter 20

      Theoretical Treatment of Silicon Clusters (pages 269–280)

      Alexander F. Sax

    14. Chapter 21

      Isomers of Neutral Silicon Clusters (pages 281–292)

      Rolf Schäfer, Michael Rosemeyer, Christian Herwig and Jörg August Becker

    15. Chapter 22

      Investigation of the Influence of Oxidation and HF Attack on the Photoluminescence of Silicon Nanoparticles (pages 293–307)

      F. Huisken, G. Ledoux, O. Guillois and C. Reynaud

    16. Chapter 23

      Localization Phenomena and Photoluminescence from Nano-structured Silicon and from Silicon/Silicon Dioxide Nanocomposites (pages 308–320)

      S. Veprek and D. Azinovic

    17. Chapter 24

      Higher-Coordinate Silicon Compounds with SiO5 and SiO6 Skeletons (pages 324–337)

      Reinhold Tacke and Oliver Seiler

  5. Part III: Si-O Systems: From Molecular Building Blocks to Extended Networks

    1. Chapter 25

      Functionalized Silanols and Silanolates (pages 338–347)

      Susanne Kliem, Clemens Reiche and Uwe Klingebiel

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      Part Introduction (pages 321–323)

    3. Chapter 26

      Transition Metal Fragment Substituted Silanols of Iron and Tungsten – Synthesis, Structure and Condensation Reactions (pages 348–359)

      Wolfgang Malisch, Marco Hofmann, Matthias Vögler, Dirk Schumacher, Andreas Sohns, Holger Bera and Heinrich Jehle

    4. Chapter 27

      Rational Synthesis of Cyclosiloxanes and Molecular Alumo- and Gallosiloxanes (pages 360–371)

      Michael Veith and Andreas Rammo

    5. Chapter 28

      Synthesis, Structure and Reactivity of Novel Oligomeric Titanasiloxanes (pages 372–382)

      Prof. Dr. Peter Jutzi, Hans Martin Lindemann, Jörn-oliver Nolte and Manuela Schneider

    6. Chapter 29

      Metallasilsesquioxanes – Synthetic and Structural Studies (pages 383–394)

      Prof. Frank T. Edelmann

    7. Chapter 30

      Spin-Spin Interaction in Silsesquioxanes and Transition Metal Substitution (pages 395–405)

      Wolfgang W. Schoeller and Dirk Eisner

    8. Chapter 31

      Characterization of Silicon-Containing Polymers by Coupling of HPLC-Separation Methods with MALDI-TOF Mass Spectrometry (pages 406–418)

      Jana Falkenhagen, Ralph-Peter Krüger and Günter Schulz

    9. Chapter 32

      The Stepwise Formation of Si-O-Networks (pages 419–430)

      Michael Binnewies and Nicola Söger

    10. Chapter 33

      Mechanism of Ring and Cage Formation in Siloxanes (pages 431–438)

      Karl Jug

    11. Chapter 34

      Structurally Well-Defined Amphiphilic Polysiloxane Copolymers (pages 439–450)

      Guido Kickelbick, Josef Bauer and Nicola Hüsing

    12. Chapter 35

      Synthesis and Functionalization of Mesostructured Silica-Based Films (pages 451–459)

      Nicola Hüsing, Beatrice Launay and Guido Kickelbick

    13. Chapter 36

      Modification of Ordered Mesostructured Materials during Synthesis (pages 460–474)

      Stephan Altmaier and Peter Behrens

    14. Chapter 37

      Biosilicification – Structure, Regulation of Structure and Model Studies (pages 475–487)

      Carole C. Perry

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      Subject Index (pages 489–494)

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