Activating Unreactive Substrates: The Role of Secondary Interactions

Copyright © 2009 Wiley-VCH Verlag GmbH & Co. KGaA

Activating Unreactive Substrates: The Role of Secondary Interactions

Editor(s): Carsten Bolm, F. Ekkehardt Hahn

Published Online: 25 MAY 2009

Print ISBN: 9783527318230

Online ISBN: 9783527625468

DOI: 10.1002/9783527625468

About this Book

Product Information

About The Product

The use of secondary interactions for the activation of non-reactive substrates constitutes a new and modern approach in catalysis.
This first comprehensive treatment of this important research field covers the entire field and reveals the links between the various chemical disciplines. It thus adopts an interdisciplinary approach, making it of interest to the whole chemical community.
A must for organic, inorganic, catalytic and complex chemists, as well as those working with/on organometallics.

Table of contents

    1. You have free access to this content
      Front Matter (pages I–XXII)

    2. Chapter 1

      Chemistry of Metalated Container Molecules (pages 1–15)

      Berthold Kersting

    3. Chapter 2

      The Chemistry of Superbasic Guanidines (pages 17–37)

      Jörg Sundermeyer, Volker Raab, Ekatarina Gaoutchenova, Udo Garrelts, Nuri Abacilar and Klaus Harms

    4. Chapter 3

      Iron Complexes and Dioxygen Activation (pages 39–51)

      Thomas Nebe, Jing-Yuan Xu and Siegfried Schindler

    5. Chapter 4

      Tuning of Structures and Properties of Bispidine Complexes (pages 53–63)

      Peter Comba and Marion Kerscher

    6. Chapter 5

      Novel Phosphorus and Nitrogen Donor Ligands Bearing Secondary Functionalities for Applications in Homogeneous Catalysis (pages 65–88)

      Anna-Katharina Pleier, Yu Sun, Anett Schubert, Dirk Zabel, Claudia May, Andreas Reis, Gotthelf Wolmershäuser and Werner R. Thiel

    7. Chapter 6

      Square-Pyramidal Coordinated Phosphine Iron Fragments: A Tale of the Unexpected (pages 89–102)

      Andreas Grohmann and Stephan Kohl

    8. Chapter 7

      Regioselective Catalytic Activity of Complexes with NH, NR-Substituted Heterocyclic Carbene Ligands (pages 103–122)

      Siegfried R. Waldvogel, Anke Spurg and Prof. Dr. F. Ekkehardt Hahn

    9. Chapter 8

      Functionalized Cycloheptatrienyl-Cyclopentadienyl Sandwich Complexes as Building Blocks in Metallo-Supramolecular Chemistry (pages 123–146)

      Matthias Tamm

    10. Chapter 9

      Monosaccharide Ligands in Organotitanium and Organozirconium Chemistry (pages 147–164)

      Peter Kitaev, Daniela Zeysing and Jürgen Heck

    11. Chapter 10

      Reactions of C[BOND]F Bonds with Titanocene and Zirconocene: From Secondary Interaction via Bond Cleavage to Catalysis (pages 165–182)

      Uwe Rosenthal, Vladimir V. Burlakov, Perdita Arndt, Anke Spannenberg, Ulrike Jäger-Fiedler, Marcus Klahn and Marko Hapke

    12. Chapter 11

      Bisazines in the Coordination Sphere of Early Transition Metals (pages 183–207)

      Ruediger Beckhaus

    13. Chapter 12

      Bifunctional Molecular Systems with Pendant Bis(pentafluorophenyl)boryl Groups: From Intramolecular CH-Activation to Heterolytic Dihydrogen Splitting (pages 209–230)

      Michael Hill, Christoph Herrmann, Patrick Spies, Gerald Kehr, Klaus Bergander, Roland Fröhlich and Gerhard Erker

    14. Chapter 13

      Ruthenium-Containing Polyoxotungstates: Structure and Redox Activity (pages 231–243)

      Ulrich Kortz

    15. Chapter 14

      From NO to Peroxide Activation by Model Iron(III) Complexes (pages 245–272)

      Alicja Franke, Natalya Hessenauer-Ilicheva, Joo-Eun Jee and Rudi van Eldik

    16. Chapter 15

      Synthetic Nitrogen Fixation with Molybdenum and Tungsten Phosphine Complexes: New Developments (pages 273–296)

      Gerald Stephan and Felix Tuczek

    17. Chapter 16

      Directed C[BOND]H Functionalizations (pages 297–312)

      Prof. Dr. Carsten Bolm

    18. Chapter 17

      Development of Novel Ruthenium and Iron Catalysts for Epoxidation with Hydrogen Peroxide (pages 313–337)

      Man Kin Tse, Bianca Bitterlich and Matthias Beller

    19. Chapter 18

      Pentacoordinating Bis(oxazoline) Ligands with Secondary Binding Sites (pages 339–348)

      Caroline A. Schall, Michael Seitz, Anja Kaiser and Oliver Reiser

    20. Chapter 19

      Flavin Photocatalysts with Substrate Binding Sites (pages 349–358)

      Harald Schmaderer, Jiri Svoboda and Burkhard König

    21. Chapter 20

      New Catalytic Cu-, Pd- and Stoichiometric Mg-, Zn-Mediated Bond Activations (pages 359–377)

      Tobias Thaler, Hongjun Ren, Nina Gommermann, Giuliano C. Clososki, Christoph J. Rohbogner, Stefan H. Wunderlich and Paul Knochel

    22. Chapter 21

      From Cobalt(II)-Activated Molecular Oxygen to Hydroxymethyl-Substituted Tetrahydrofurans (pages 379–396)

      Bárbara Menéndez Pérez, Dominik Schuch and Jens Hartung

    23. Chapter 22

      Regiodivergent Epoxide Opening (pages 397–409)

      Andreas Gansäuer, Florian Keller, Chun-An Fan and Peter Karbaum

    24. Chapter 23

      Supramolecular Containers: Host-Guest Chemistry and Reactivity (pages 411–425)

      Markus Albrecht

    25. Chapter 24

      Self-Assembly of Dinuclear Helical Metallosupramolecular Coordination Compounds (pages 427–446)

      Ulf Kiehne, Jens Bunzen and Arne Lützen

    26. You have free access to this content
      Index (pages 447–459)

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