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(11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]-dinaphtho[2,1-d: 1′,2′-f][1,3,2]dioxaphosphepin-4-oxide, [(R)-TRIP] & (11bS)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]-dinaphtho[2,1-d: 1′,2′-f][1,3,2]dioxaphosphepin-4-oxide, [(S)-TRIP]

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  1. Douglas K. Hutchinson

Published Online: 16 SEP 2013

DOI: 10.1002/047084289X.rn01614

e-EROS Encyclopedia of Reagents for Organic Synthesis

e-EROS Encyclopedia of Reagents for Organic Synthesis

COMPOUND RECORD : (R)-2,6-Bis[(2,4,6-triisopropyl)phenyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ol 4-oxide-tert-butyl-(S)-valine


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Summary

Compound Information

FormulaC59H76NO6P
Molecular Weight926.2116
SynonymsNot available

Structure Descriptors

SMILES:[H][N+]([H])([H])[C@@H](C(C)C)C(=O)OC(C)(C)C.CC(C)C1=CC(C(C)C)=C(C(=C1)C(C)C)C1=CC2=C(C=CC=C2)C2=C1OP([O-])(=O)OC1=C2C2=C(C=CC=C2)C=C1C1=C(C=C(C=C1C(C)C)C(C)C)C(C)C
InChI:1S/C50H57O4P.C9H19NO2/c1-27(2)35-23-39(29(5)6)45(40(24-35)30(7)8)43-21-33-17-13-15-19-37(33)47-48-38-20-16-14-18-34(38)22-44(50(48)54-55(51,52)53-49(43)47)46-41(31(9)10)25-36(28(3)4)26-42(46)32(11)12;1-6(2)7(10)8(11)12-9(3,4)5/h13-32H,1-12H3,(H,51,52);6-7H,10H2,1-5H3/t;7-/m.0/s1
InChIKey:VABVHNTYDCLWIP-ZLTKDMPESA-N

Other articles that contain this structure:

  1. Diethyl 1,4-Dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate

    Encyclopedia of Reagents for Organic Synthesis

    William S. Bechara and André B. Charette

    Published Online : 15 MAR 2011, DOI: 10.1002/047084289X.rn01318