Short Communication

New Silyl-Substituted Tin-Nitrogen Heterocubanes: Fourfold Metal-Coordinated Nitrogen and Exceptional Chemical and NMR Properties

  1. Michael Veith,
  2. Michael Opsölder,
  3. Michael Zimmer,
  4. Volker Huch

Article first published online: 23 MAY 2000

DOI: 10.1002/(SICI)1099-0682(200006)2000:6<1143::AID-EJIC1143>3.0.CO;2-Q

Issue

European Journal of Inorganic Chemistry

European Journal of Inorganic Chemistry

Volume 2000, Issue 6, pages 1143–1146, June 2000

Additional Information

How to Cite

Veith, M., Opsölder, M., Zimmer, M. and Huch, V. (2000), New Silyl-Substituted Tin-Nitrogen Heterocubanes: Fourfold Metal-Coordinated Nitrogen and Exceptional Chemical and NMR Properties. European Journal of Inorganic Chemistry, 2000: 1143–1146. doi: 10.1002/(SICI)1099-0682(200006)2000:6<1143::AID-EJIC1143>3.0.CO;2-Q

Author Information

  1. Institut für Anorganische Chemie, Universität des Saarlandes, Postfach 151150, D-66701 Saarbrücken, Germany Fax: (internat.) + 49-681/302-3995

Publication History

  1. Issue published online: 23 MAY 2000
  2. Article first published online: 23 MAY 2000
  3. Manuscript Received: 2 MAR 2000

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Keywords:

  • Tin;
  • Nitrogen;
  • Cage compounds;
  • Cluster compounds;
  • Fourfold metal-coordinated nitrogen

Abstract

The synthesis of new silyl-substituted tin-nitrogen heterocubanes and the structural analysis of [Me3SiNSn]4 is described. A sharp signal in the 14N NMR spectrum and a septet in the 119Sn NMR spectrum are among the interesting properties of this new type of compound with nitrogen surrounded by four (hemi)metals.

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