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Full Paper
Structure and Bonding of Low-Valent (Fischer-Type) and High-Valent (Schrock-Type) Transition Metal Carbene Complexes
Article first published online: 14 DEC 1998
DOI: 10.1002/(SICI)1521-3765(19980807)4:8<1428::AID-CHEM1428>3.0.CO;2-7
© 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany
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Additional Information
How to Cite
Vyboishchikov, S. F. and Frenking, G. (1998), Structure and Bonding of Low-Valent (Fischer-Type) and High-Valent (Schrock-Type) Transition Metal Carbene Complexes. Chem. Eur. J., 4: 1428–1438. doi: 10.1002/(SICI)1521-3765(19980807)4:8<1428::AID-CHEM1428>3.0.CO;2-7
Publication History
- Issue published online: 14 DEC 1998
- Article first published online: 14 DEC 1998
- Manuscript Received: 28 OCT 1997
- Abstract
- References
- Cited By
Keywords:
- Ab initio calculations;
- Carbene complexes;
- Donor–acceptor interactions;
- Metal–ligand interactions;
- Tungsten
Abstract
The nature and reactivity of the metal–carbene bond of 12 Fischer- (1) and Schrock- (2) type carbene complexes of tungsten, both neutral and negatively charged, is investigated. The geometries and tungsten–carbene bond dissociation energies were calculated by use of ab initio methods at the HF, MP2, and CCSD(T) level of theory.