1521-3773/asset/2002_left.gif?v=1&s=ac6b0d94a94d7ce7a210002b8096b42feffc0bcf)
1521-3773/asset/2002_right.gif?v=1&s=451042aa3415ae3ad0729984d26dee1866aca82e)
Communication
Homoleptic Lanthanide Complexes of Chelating Phosphanamides—An Experimental and Theoretical Study
Article first published online: 14 APR 1999
DOI: 10.1002/(SICI)1521-3773(19990419)38:8<1086::AID-ANIE1086>3.0.CO;2-E
© 1999 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany
1521-3773(19990419)38:8<>1.0.CO;2-O/asset/cover.gif?v=1&s=35be971f08e5ddc196312ea440afeaea60cdb674 "Angewandte Chemie International Edition")
Additional Information
How to Cite
Wetzel, T. G., Dehnen, S. and Roesky, P. W. (1999), Homoleptic Lanthanide Complexes of Chelating Phosphanamides—An Experimental and Theoretical Study. Angew. Chem. Int. Ed., 38: 1086–1088. doi: 10.1002/(SICI)1521-3773(19990419)38:8<1086::AID-ANIE1086>3.0.CO;2-E
Publication History
- Issue published online: 14 APR 1999
- Article first published online: 14 APR 1999
- Manuscript Received: 13 NOV 1998
- Abstract
- Cited By
Keywords:
- Ab initio calculations;
- Chelates;
- Density functional calculations;
- Lanthanides;
- Phosphanamides
Abstract
Four chelating ligands are present in the first phosphanamide complexes of Group 3 metals and the lanthanides (see structure shown). However, these ligands coordinate to form a distorted molecular structure. The compounds were characterized by single-crystal X-ray structure analysis and quantum-mechanical investigations with density functional theory and MP2 methods.