Communication

Very Stable Phosphiranes

  1. Jürgen Liedtke1,
  2. Sandra Loss1,
  3. Gilles Alcaraz1,
  4. Volker Gramlich2,
  5. Hansjörg Grützmacher1

Article first published online: 26 MAY 1999

DOI: 10.1002/(SICI)1521-3773(19990601)38:11<1623::AID-ANIE1623>3.0.CO;2-K

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 38, Issue 11, pages 1623–1626, June 1, 1999

Additional Information

How to Cite

Liedtke, J., Loss, S., Alcaraz, G., Gramlich, V. and Grützmacher, H. (1999), Very Stable Phosphiranes. Angewandte Chemie International Edition, 38: 1623–1626. doi: 10.1002/(SICI)1521-3773(19990601)38:11<1623::AID-ANIE1623>3.0.CO;2-K

Author Information

  1. 1

    Laboratory for Inorganic Chemistry, ETH-Zentrum, Universitätsstrasse 6, CH-8092 Zürich (Switzerland), Fax: (+41) 1-632-10-90

  2. 2

    Institute of Crystallography, ETH-Zentrum, Sonneggstrasse 5, CH-8092 Zürich (Switzerland)

Publication History

  1. Issue published online: 26 MAY 1999
  2. Article first published online: 26 MAY 1999
  3. Manuscript Received: 27 OCT 1998

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Keywords:

  • Homogeneous catalysis;
  • Phosphorus heterocycles;
  • Platinum;
  • P ligands

Abstract

Zero-valent platinum complexes as precursors for hydrosilylation catalysts have been prepared for the first time with the new BABAR-Phos ligands (the structure of one such complex is depicted). These rather stable phosphiranes can be obtained when the three-membered PC2 ring is incorporated into a polycyclic cage.

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