Synthesis, Structure, and Physical Properties of the Organic–Inorganic Hybrid Salt (BEDT-TTF)6[PMo12O40]·(4CH3CN·6H2O) (pages 545–550)
Mohamedally Kurmoo, Mario Bonamico, Carlo Bellitto, Vincenzo Fares, Fulvio Federici, Philippe Guionneau, Laurent Ducasse, Hiroshi Kitagawa and Peter Day
Version of Record online: 26 JAN 1999 | DOI: 10.1002/(SICI)1521-4095(199805)10:7<545::AID-ADMA545>3.0.CO;2-M
Magnetic superconductors based on organic–inorganic hybrid salts are actively sought-after materials. Salts of bis(ethylenedithio)tetrathiafulvane (BEDT-TTF) and polyoxometallates, which combine the electronic properties of BEDT-TTF with the magnetic properties of the oxo anion, are promising candidates. The X-ray crystal structure and physical properties of (BEDT-TTF)6[PMo12O40]·(4CH3CN·6H2O), one of the phases isolated on electrocrystallization of the material, are reported. The calculated electronic band structure is also presented.