6. Kinetics and Mechanism of Electrodeposition

  1. Milan Paunovic1 and
  2. Mordechay Schlesinger2

Published Online: 21 NOV 2005

DOI: 10.1002/0470009403.ch6

Fundamentals of Electrochemical Deposition, Second Edition

Fundamentals of Electrochemical Deposition, Second Edition

How to Cite

Paunovic, M. and Schlesinger, M. (2006) Kinetics and Mechanism of Electrodeposition, in Fundamentals of Electrochemical Deposition, Second Edition, John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/0470009403.ch6

Author Information

  1. 1

    Formerly with IBM Research Division, Yorktown Heights, NY, USA

  2. 2

    University of Windsor, Windsor, Ontario, Canada

Publication History

  1. Published Online: 21 NOV 2005
  2. Published Print: 17 JUL 2006

ISBN Information

Print ISBN: 9780471712213

Online ISBN: 9780470009406

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Keywords:

  • electrodeposition - kinetics and mechanism;
  • Butler–Volmer equation - high-overpotential approximation;
  • mass transport influence on electrode kinetics

Summary

This chapter contains sections titled:

  • Introduction

  • Relationship between Current and Potential: Butler–Volmer Equation

  • Butler–Volmer Equation: High-Overpotential Approximation

  • Butler–Volmer Equation: Low-Overpotential Approximation

  • Kinetic Derivation of Nernst Equation

  • Influence of Mass Transport on Electrode Kinetics

  • Multistep Reactions

  • Atomistic Aspects of Electrodeposition of Metals

  • Techniques for Study of Electrode Processes

  • Determination of Kinetic Parameters α and i0

  • References and Further Reading

  • Problems