Chapter 4. Pd(0)-Catalyzed Reactions of Allylic Compounds via π-Allylpalladium Complexes

  1. Jiro Tsuji Emeritus Professor

Published Online: 28 JAN 2005

DOI: 10.1002/0470021209.ch4

Palladium Reagents and Catalysts: New Perspectives for the 21st Century

Palladium Reagents and Catalysts: New Perspectives for the 21st Century

How to Cite

Tsuji, J. (2004) Pd(0)-Catalyzed Reactions of Allylic Compounds via π-Allylpalladium Complexes, in Palladium Reagents and Catalysts: New Perspectives for the 21st Century, John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470021209.ch4

Author Information

  1. Tokyo Institute of Technology, Japan

Publication History

  1. Published Online: 28 JAN 2005
  2. Published Print: 23 APR 2004

ISBN Information

Print ISBN: 9780470850329

Online ISBN: 9780470021200

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Keywords:

  • Pd-catalyzed reactions;
  • leaving groups;
  • intramolecular Michael addition

Summary

This chapter contains sections titled:

  • Introduction and Range of Leaving Groups

  • Allylation

  • Reactions with Main Group Organometallic Compounds via Transmetallation

  • Carbonylation Reactions

  • Intramolecular Reactions with Alkenes and Alkynes

  • Hydrogenolysis of Allylic Compounds

  • Allyl Group As a Protecting Group

  • 1,4-elimination

  • Reactions via π-allylpalladium Enolates

  • Pd(0) and Pd(II)-catalyzed Allylic Rearrangement

  • Reactions of 2,3-alkadienyl Derivatives via Methylene-π-allylpalladiums

  • References