4. Intramolecular Carbolithiation Reactions

  1. Professor Zvi Rappoport3 and
  2. Ilan Marek4
  1. Francisco J. Fañanás1 and
  2. Roberto Sanz2

Published Online: 2 JUN 2006

DOI: 10.1002/0470023236.ch4

The Chemistry of Organolithium Compounds, Volume 2

The Chemistry of Organolithium Compounds, Volume 2

How to Cite

Fañanás, F. J. and Sanz, R. (2005) Intramolecular Carbolithiation Reactions, in The Chemistry of Organolithium Compounds, Volume 2 (eds Z. Rappoport and I. Marek), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470023236.ch4

Editor Information

  1. 3

    The Hebrew University, Jerusalem, Israel

  2. 4

    Technion-Israel Institute of Technology, Haifa, Israel

Author Information

  1. 1

    Instituto Universitario de Química Organometálica “Enrique Moles”, Unidad Asociada al CSIC, Universidad de Oviedo, C/Julián Clavería, 8, E-33006 Oviedo, Spain

  2. 2

    Departamento de Química, Facultad de Ciencias, Universidad de Burgos, Plaza Missael Bañuelos s/n, E-09001 Burgos, Spain

Publication History

  1. Published Online: 2 JUN 2006
  2. Published Print: 16 DEC 2005

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Professor Saul Patai and
  2. Professor Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780470023211

Online ISBN: 9780470023235

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Keywords:

  • intramolecular carbolithiation reactions;
  • anionic cyclization reactions;
  • single-electron transfer (SET);
  • single-electron transfer processes;
  • chiral auxiliary approach;
  • enantioselective carbolithiation process;
  • recemization;
  • reductive decyanation cyclizations;
  • endodig cyclization reactions

Summary

This chapter contains sections titled:

  • Introduction

  • General Aspects of Intramolecular Carbolithiation Reactions

  • Carbolithiation Reaction of Unsaturated Alkyllithiums

  • Carbolithiation Reaction of Unsaturated Vinyllithiums and Aryllithiums

  • Conclusions

  • Acknowledgements

  • References