8. Aspects of the Synthesis, Structure and Reactivity of Lithium Enolates

  1. Professor Zvi Rappoport2 and
  2. Ilan Marek3
  1. Jean-Yves Valnot and
  2. Jacques Maddaluno

Published Online: 2 JUN 2006

DOI: 10.1002/0470023236.ch8

The Chemistry of Organolithium Compounds, Volume 2

The Chemistry of Organolithium Compounds, Volume 2

How to Cite

Valnot, J.-Y. and Maddaluno, J. (2005) Aspects of the Synthesis, Structure and Reactivity of Lithium Enolates, in The Chemistry of Organolithium Compounds, Volume 2 (eds Z. Rappoport and I. Marek), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470023236.ch8

Editor Information

  1. 2

    The Hebrew University, Jerusalem, Israel

  2. 3

    Technion-Israel Institute of Technology, Haifa, Israel

Author Information

  1. Laboratoire des Fonctions Azotées & Oxygénées Complexes de l'IRCOF, UMR 6014 CNRS, Université de Rouen, F-76821 Mont St Aignan Cedex, France

Publication History

  1. Published Online: 2 JUN 2006
  2. Published Print: 16 DEC 2005

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Professor Saul Patai and
  2. Professor Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780470023211

Online ISBN: 9780470023235

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Keywords:

  • synthesis of lithium enolates;
  • acid–base reaction;
  • direct hydrogen abstraction;
  • pretransition state;
  • thermodynamic enolates;
  • monomer/open-dimer models;
  • nuclear magnetic resonance;
  • quadrupole splitting constant (QSC);
  • chelate-enforced chirality transfer auxiliaries

Summary

This chapter contains sections titled:

  • Introduction

  • Synthesis of Lithium Enolates

  • Structure of Lithium Enolates

  • Reactivity of Lithium Enolates

  • References