16. Ionic Reactions Involving Hydrazo, Azo and Azoxy Groups

  1. Saul Patai Professor
  1. A. F. Hegarty

Published Online: 22 JUL 2004

DOI: 10.1002/0470023414.ch16

Hydrazo, Azo and Azoxy Groups, Volume 1 and Volume 2 (1975)

Hydrazo, Azo and Azoxy Groups, Volume 1 and Volume 2 (1975)

How to Cite

Hegarty, A. F. (1975) Ionic Reactions Involving Hydrazo, Azo and Azoxy Groups, in Hydrazo, Azo and Azoxy Groups, Volume 1 and Volume 2 (1975) (ed S. Patai), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470023414.ch16

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. Chemistry Department, University College, Cork, Ireland

Publication History

  1. Published Online: 22 JUL 2004
  2. Published Print: 1 JAN 1975

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Saul Patai

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471669241

Online ISBN: 9780470023419

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Summary

This chapter contains sections titled:

  • Introduction

  • Hydrazine Derivatives

    • Acid–Base Reactions

      • Basicity

      • Acidity

    • Alkylation

      • Site of Alkylation

      • Alkylation with Subsequent Cyclization

      • Alkylation of Hydrazo Anions

      • Other Alkylating Agents

      • The α Effect

    • Acylation

      • Site of Acylation

      • Use of Protecting Groups

      • Other Acylating Agents

      • Diacylation

      • Reactions of Hydrazides

    • Reaction with Activated Alkenes and Alkynes

      • Alkenes

      • Alkynes

      • Nucleophilic Aromatic Substitution

    • Reactions with Aldehydes and Ketones

      • Mechanism

      • Reaction with Formaldehyde

      • Reactions of Bifunctional Reagents

      • Reactions of Arylhydrazones

    • Nitrosation

    • Reactions with Aryldiazonium Ions

    • Reactions with Nitro Groups

      • Intramolecular

      • Intermolecular

  • Cyclic Hydrazo Compounds—Diaziridines

  • Azo Compounds

    • Reactions with Acids

      • Basicity

      • Tautomerism

    • Alkylation

    • Reaction with Peracids

    • Electrophilic and Nucleophilic Substitution

    • Intramolecular Reactions

    • Reactions Adjacent to the Azo Group

    • Electrophilic Azo Compounds

  • Azoxy Compounds

    • Acidity and Basicity

    • Reactions in Acid

    • Reactions in Base

    • Electrophilic Substitution

    • Alkylation

  • References