8. Directing and Activating Effects

  1. Saul Patai Professor
  1. D. A. R. Happer and
  2. J. Vaughan

Published Online: 22 JUL 2004

DOI: 10.1002/0470023414.ch8

Hydrazo, Azo and Azoxy Groups, Volume 1 and Volume 2 (1975)

Hydrazo, Azo and Azoxy Groups, Volume 1 and Volume 2 (1975)

How to Cite

Happer, D. A. R. and Vaughan, J. (1975) Directing and Activating Effects, in Hydrazo, Azo and Azoxy Groups, Volume 1 and Volume 2 (1975) (ed S. Patai), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470023414.ch8

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. University of Canterbury, Christchurch, New Zealand

Publication History

  1. Published Online: 22 JUL 2004
  2. Published Print: 1 JAN 1975

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Saul Patai

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471669241

Online ISBN: 9780470023419

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Summary

This chapter contains sections titled:

  • Introduction

  • Directing and Activating Effects of the Azo Group

    • General Considerations

    • Reactions of Aromatic Side-chains

      • The Phenylazo Substituent

      • The Arylazo Substituent

      • Transmission of Resonance Effects through the Azo Group

    • Electrophilic Aromatic Substitution Reactions in Azo Compounds

      • General Considerations

      • Reactions

    • Other Aromatic Substitution Reactions

      • Nucleophilic Aromatic Substitution

      • Free-radical Substitution

      • Miscellaneous Substitutions

    • Nuclear Magnetic Resonance Spectra of Azo Compounds

    • The Protonated Azo (Azonium) Group as a Substituent

  • Directing and Activating Effects of the Azoxy Group

    • General Considerations

    • Reactions of Aromatic Side-chains

    • Electrophilic Substitution Reactions in Azoxy Compounds

      • General Considerations

      • Substitution in Alkylazoxybenzenes

      • Azoxybenzene and Substituted Azoxybenzenes

      • The Activating Power of the Phenylazoxy Group

    • Other Aromatic Substitution Reactions

      • Nucleophilic Aromatic Substitution

      • Miscellaneous Substitutions

    • Nuclear Magnetic Resonance Spectra of Azoxy Compounds

      • Aliphatic Compounds

      • Aromatic Compounds

  • Directing and Activating Effects of the Hydrazo Group

  • References