9. The Transition Metal Chemistry of Azo Compounds

  1. Saul Patai Professor
  1. M. I. Bruce and
  2. B. L. Goodall

Published Online: 22 JUL 2004

DOI: 10.1002/0470023414.ch9

Hydrazo, Azo and Azoxy Groups, Volume 1 and Volume 2 (1975)

Hydrazo, Azo and Azoxy Groups, Volume 1 and Volume 2 (1975)

How to Cite

Bruce, M. I. and Goodall, B. L. (1975) The Transition Metal Chemistry of Azo Compounds, in Hydrazo, Azo and Azoxy Groups, Volume 1 and Volume 2 (1975) (ed S. Patai), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470023414.ch9

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. Department of Inorganic Chemistry, The University, Bristol, England

  1. Department of Physical and Inorganic Chemistry, University of Adelaide, South Australia 5001

Publication History

  1. Published Online: 22 JUL 2004
  2. Published Print: 1 JAN 1975

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Saul Patai

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471669241

Online ISBN: 9780470023419

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Summary

This chapter contains sections titled:

  • Abbreviations

  • Introduction

  • Complexes Involving No Metal–Carbon Interaction

    • Molybdenum

    • Iridium

    • Nickel

    • Platinum

  • Iron Carbonyl Derivatives Containing a Cyclic Fe2N2 System

  • Complexes Containing ortho-metallated Azo Compounds as Ligands

    • General Syntheses

    • Molybdenum

    • Manganese and Rhenium

    • Iron

    • Ruthenium

    • Cobalt

    • Rhodium

    • Iridium

    • Nickel

    • Palladium and Platinum

    • Structures of o-metallated Complexes

    • Reaction Mechanisms

  • Complexes Containing Ligands Related to o-semidine

    • Molybdenum

    • Iron and Ruthenium

    • Cobalt and Rhodium

    • Mechanism of the Metal-promoted o-semidine Rearrangement

  • Organic Syntheses from Azoarenes and Metal Complexes

    • Addition of Unsaturated Molecules to Azoarenes

      • One-carbon Units

      • Two-carbon Units

      • Three-carbon Units

    • Hydrogenation

    • Halogenation

    • Other Reactions Involving Metal–Carbon Bond Cleavage

  • Arylazo and Aryldiimine Complexes of Transition Metals

    • Molybdenum and Tungsten

    • Rhenium

    • Iron

    • Ruthenium and Osmium

    • Cobalt

    • Rhodium

    • Iridium

    • Platinum

    • Azo Complexes, MN[DOUBLE BOND]NM

    • Structures of Arylazo–Metal Complexes

  • Summary and Prognosis

  • References