2. Chiroptical Properties of Cyclopropane Derivatives

  1. Zvi Rappoport
  1. Wolfgang Runge

Published Online: 28 JAN 2005

DOI: 10.1002/0470023449.ch2

Cyclopropyl Group: Volume 1 and Volume 2 (1987)

Cyclopropyl Group: Volume 1 and Volume 2 (1987)

How to Cite

Runge, W. (1987) Chiroptical Properties of Cyclopropane Derivatives, in Cyclopropyl Group: Volume 1 and Volume 2 (1987) (ed Z. Rappoport), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470023449.ch2

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. Institut für Struktur- und Systemforschung, Wormser Str. 5, D-6900 Heidelberg, West Germany

Publication History

  1. Published Online: 28 JAN 2005
  2. Published Print: 28 OCT 1987

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Saul Patai

ISBN Information

Print ISBN: 9780471917380

Online ISBN: 9780470023440



This chapter contains sections titled:

  • Introduction

  • Optical Rotations of Cyclopropanes

    • Semiempirical Descriptions of Optical Rotations of Cyclopropanes by the Triad Theory of Optical Rotations

      • General Principles

      • Parameters for the Calculations of Molar Rotations

      • Calculations of Molar Rotations of Cyclopropanes

        • Cyclopropanes with Two Substituents

        • Cyclopropanes with More Than Two Substituents

        • 1, 1-Diphenylcyclopropanes with Carbonyl Groups

        • Optical Rotatory Dispersion

    • Optical Rotations of Miscellaneous Compounds

      • Alkylidenecyclopropanes and Bicyclic Cyclopropanes

      • Deuterated Cyclopropanes

  • Electronic Circular Dichroism of Cyclopropanes

    • The Cyclopropane Chromophore and the Circular Dichroism of Cyclopropane Hydrocarbons

    • Substituent Effects of the Cyclopropyl Group on the Circular Dichroism of Selected Chromophores

      • Carboxylic Acids and Acid Derivatives

      • Phenylcyclopropanes

      • Vinylcyclopropanes

      • Cyclopropyl Ketones and Aldehydes

        • Octant and Antioctant Behavior of Cyclopropyl Ketones

        • Cyclic Compounds with an α, β-cyclopropyl Ketone Chromophore

        • Non-conjugated Cyclic Cyclopropyl Ketones

        • Open-chain Aldehydes and Ketones

  • Vibrational Circular Dichroism of Cyclopropanes

    • Electronic and Vibrational Circular Dichroism

    • Vibrational Circular Dichroism of Trans-1,2-disubstituted Cyclopropanes

      • C–H Vibrations

      • Functional Group Vibrations

  • References