7. Preparation of Cyclopropyl Derivatives

  1. Zvi Rappoport
  1. Takashi Tsuji and
  2. Shinya Nishida

Published Online: 28 JAN 2005

DOI: 10.1002/0470023449.ch7

Cyclopropyl Group: Volume 1 and Volume 2 (1987)

Cyclopropyl Group: Volume 1 and Volume 2 (1987)

How to Cite

Tsuji, T. and Nishida, S. (1987) Preparation of Cyclopropyl Derivatives, in Cyclopropyl Group: Volume 1 and Volume 2 (1987) (ed Z. Rappoport), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470023449.ch7

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo, Hokkaido 060, Japan

Publication History

  1. Published Online: 28 JAN 2005
  2. Published Print: 28 OCT 1987

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Saul Patai

ISBN Information

Print ISBN: 9780471917380

Online ISBN: 9780470023440

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Summary

This chapter contains sections titled:

  • Introduction

  • 1,3-bond Formation

    • 1,3-elimination of Two Heteroatoms

    • Extrusion Reactions

    • 1,3-elimination of HX; Intramolecular Displacement Reactions

    • Cyclization of Allylic Derivatives

      • γ-substituted Michael Acceptors and Nucleophiles

      • Reactions of Other Allylic Derivatives

    • Cyclization of 3-Butenyl Derivatives

    • Bond Formation between Two Unsaturated Groups

    • Miscellaneous

  • Combination of C2 and C1 Building Blocks

    • Cyclopropanation of Carbon–Carbon Multiple Bonds with Carbenes and Carbenoids

      • Methylene

      • Alkyl-, Alkenyl- and Arylcarbenes

      • Alkenylidenes

      • Monohalo- and Dihalocarbenes

      • Acyl- and Alkoxycarbonylcarbenes

      • Carbenes Containing α-heteroatom(s) Other Than Halogen

    • Cyclopropanation of Michael Acceptors

      • with Ylides

      • with α-halocarbanions and Related Species

    • Cyclopropanation of Active Methylene Compounds

      • with 1,2-Dihaloethanes and Related Compounds

      • with Michael Acceptors Carrying a Leaving Group at the α-carbon Atom

    • Cyclopropanation with Diazo Compounds via 1-Pyrazolines

    • Cyclopropane Formation from Oxiranes

    • Miscellaneous

  • Rearrangement Reactions

    • Ring Contractions of Cyclobutyl Derivatives

    • Other Photochemical and Thermal Rearrangements

  • Transformations of Cyclopropyl Derivatives

    • Organometallics

    • Substitution Reactions

    • Addition Reactions to Cyclopropenes

    • Elimination Reactions

  • References