11. Electronic Effects of Hydrazo, Azo and Azoxy Groups

  1. Saul Patai Professor
  1. John Shorter1,2

Published Online: 21 JUL 2004

DOI: 10.1002/0470023503.ch11

The Chemistry of the Hydrazo, Azo and Azoxy Groups, Volume 2

The Chemistry of the Hydrazo, Azo and Azoxy Groups, Volume 2

How to Cite

Shorter, J. (1997) Electronic Effects of Hydrazo, Azo and Azoxy Groups, in The Chemistry of the Hydrazo, Azo and Azoxy Groups, Volume 2 (ed S. Patai), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470023503.ch11

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. 1

    School of Chemistry, University of Hull, Hull HU6 7RX, UK

  2. 2

    29 Esk Terrace, Whitby, North Yorkshire, YO21 1PA, UK

Publication History

  1. Published Online: 21 JUL 2004
  2. Published Print: 25 SEP 1997

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Saul Patai and
  2. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471968856

Online ISBN: 9780470023501

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Summary

This chapter contains sections titled:

  • Introduction: The Scope of This Chapter

  • The Hammett Equation

    • Introduction

    • Multiparameter Extensions

    • The Determination of Substituent Constants from the Application of Modern Experimental and Theoretical Techniques

      • Experimental Techniques

      • Theoretical Techniques

  • The Electronic Effects of the Hydrazino Group NHNH2

  • The Electronic Effects of Azo Groups

    • Introduction

    • Values of σm and σp for the Phenylazo Group

    • Values of equation image for the Phenylazo Group

    • Values of equation image for the Phenylazo Group

    • Values of σI and equation image for the Phenylazo Group

    • Miscellaneous Topics in the Electronic Effects of Azo Groups

      • The t-butylazo and Trifluoromethylazo Groups

      • The Transmission of Electronic Effects through N[DOUBLE BOND]N

  • The Electronic Effects of Azoxy Groups

  • References and Notes