15. Rearrangements of Hydrazo, Azoxy and Azo Compounds: Kinetic, Product and Isotope Studies

  1. Saul Patai Professor
  1. Robin A. Cox1 and
  2. Erwin Buncel2

Published Online: 21 JUL 2004

DOI: 10.1002/0470023503.ch15

The Chemistry of the Hydrazo, Azo and Azoxy Groups, Volume 2

The Chemistry of the Hydrazo, Azo and Azoxy Groups, Volume 2

How to Cite

Cox, R. A. and Buncel, E. (1997) Rearrangements of Hydrazo, Azoxy and Azo Compounds: Kinetic, Product and Isotope Studies, in The Chemistry of the Hydrazo, Azo and Azoxy Groups, Volume 2 (ed S. Patai), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470023503.ch15

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. 1

    Department of Chemistry, University of Toronto, Toronto, Ontario, Canada M5S 3H6 Fax:1-416978-8775

  2. 2

    Department of Chemistry, Queen's University, Kingston, Ontario, Canada K7L 3N6 Fax 1-613-545-6669

Publication History

  1. Published Online: 21 JUL 2004
  2. Published Print: 25 SEP 1997

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Saul Patai and
  2. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471968856

Online ISBN: 9780470023501

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Summary

This chapter contains sections titled:

  • Introduction

  • Rearrangements of Hydrazo Compounds

    • The Acid-catalyzed Benzidine Rearrangement

      • Synthesis of Labelled Compounds

      • Heavy-atom Isotope Effects

      • Kinetic Studies

    • Related Processes

      • Thermal and Photochemical Benzidine Rearrangements

      • Other Reactions

  • Rearrangements of Azoxy Compounds

    • The Wallach Rearrangement

      • Kinetic Studies

      • Product Studies

    • Related Processes

      • α[RIGHTWARDS ARROW]β Tautomerism

      • Thermal and Photochemical Wallach Rearrangements

      • Other Reactions

  • Rearrangements of Azo Compounds

    • Azo–Hydrazone Tautomerism

    • Azonium–Ammonium Tautomerism

    • CisTrans Isomerism

  • Acknowledgements

  • References