6. Information from the ESR, ENDOR and NMR Spectra of Radicals Related to Hydrazo, Azo and Azoxy Compounds

  1. Saul Patai Professor
  1. S. F. Nelsen

Published Online: 21 JUL 2004

DOI: 10.1002/0470023503.ch6

The Chemistry of the Hydrazo, Azo and Azoxy Groups, Volume 2

The Chemistry of the Hydrazo, Azo and Azoxy Groups, Volume 2

How to Cite

Nelsen, S. F. (1997) Information from the ESR, ENDOR and NMR Spectra of Radicals Related to Hydrazo, Azo and Azoxy Compounds, in The Chemistry of the Hydrazo, Azo and Azoxy Groups, Volume 2 (ed S. Patai), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470023503.ch6

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. Department of Chemistry, University of Wisconsin, Madison, 1101 University Avenue, Madison, WI 53706-1396, USA

Publication History

  1. Published Online: 21 JUL 2004
  2. Published Print: 25 SEP 1997

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Saul Patai and
  2. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471968856

Online ISBN: 9780470023501

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Summary

This chapter contains sections titled:

  • Introduction

    • Solution Spectra

    • Hybridization and Anisotropic Splittings

  • Tetrasubstituted Hydrazine Cation Radicals: 3e-π NN Bonding

    • Introduction

    • Cation Radicals from Acyclic Hydrazines

    • Cation Radicals from N,N-cycloalkyl and Bicycloalkyl Hydrazines

    • Cation Radicals from Mono-N,N′-cyclic Hydrazines

    • Cation Radicals from Mono-N,N′-bicyclic Hydrazines

    • Cation Radicals from Bis-N,N′-cyclic Hydrazines

    • Bis-hydrazine Cation Radicals

    • Acylated Tetrasubstituted Hydrazine Cation Radicals

  • Hexasubstituted Hydrazine Cation Radicals: 3e-σ NN Bonding

  • Trisubstituted Hydrazine Radicals: Hydrazyls

    • DPPH and Its Analogues

    • Other Hydrazyls

  • Azo Compound Ion Radicals

    • Azo Cation Radicals

    • Azo Anion Radicals

  • Radicals Related to Azoxy and Azodioxy Compounds

    • Diazenoxyl and Related Radicals

    • Diazoalkane Ion Radicals

    • Azodioxide and 2-tetrazene Cation Radicals

    • Diazenyl Radicals

    • Dinitrogen Cation Radical

  • Acknowledgements

  • References