Chapter 10. Enaminones as Synthones

  1. Zvi Rappoport Professor
  1. Uwe Kuckländer

Published Online: 20 JUL 2004

DOI: 10.1002/0470024763.ch10

Enamines (1994)

Enamines (1994)

How to Cite

Kuckländer, U. (2004) Enaminones as Synthones, in Enamines (1994) (ed Z. Rappoport), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470024763.ch10

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. Institut für Pharmazeutische Chemie der Heinrich-Heine-Universität Düsseldorf, Universitätsstr. 1, 40225 Düsseldorf 1, Germany

Publication History

  1. Published Online: 20 JUL 2004
  2. Published Print: 31 AUG 1994

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Saul Patai and
  2. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471933397

Online ISBN: 9780470024768

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Summary

This chapter contains sections titled:

  • Introduction

  • β-ketoenamines

    • α-substituted β-ketoenamines (Enaminones)

      • Introduction

      • Reaction with Electrophiles

        • Heterocumulenes

        • Ketones and Aldehydes

        • Carboxylic Acids and Derivatives

        • β-dicarbonyl Compounds and Derivatives

        • α,β-unsaturated Carbonyl Compounds

        • Alkynes and Arynes

        • Quinones

        • Bromine and Nitronium Ion

        • Alkyl, Aryl and Acyl Halides

        • Metal Complexes

        • Anodic Oxidation

      • Reaction with Nucleophiles

        • Aromatic Amines, Indoles and Phenols

        • Hydrazine and Hydroxylamine

        • Hydride and Hydrogen

        • CH-acidic Compounds

      • Reaction with Radicals

      • Cycloaddition

      • Photochemistry

      • Aromatization

    • α-unsubstituted β-ketoenamines (α-aminomethylene Carbonyl Compounds)

      • Introduction

      • Reaction with Electrophiles

        • Quinones and Quinone Imines

        • Ketones

        • β-dicarbonyl Compounds and Derivatives

        • Heterocumulenes

        • Bromine

      • Reaction with Nucleophiles

        • CH-acidic Compounds

        • Activated Aromatic Compounds

        • Aliphatic and Aromatic Amines

        • Nitroketene Aminals

        • Guanidine and Amidines

        • Hydroxylamine and Hydrazines

        • Hydride

      • Cycloaddition

  • β,β-diketoenamines (2-aminoalkylidene 1,3-dicarbonyl Compounds

    • Introduction

    • Reaction with Nucleophiles

      • Hydrazines

      • Hydroxylamine

      • Guanidine and Amidines

      • Aromatic Amines, and Indole and Pyridine Rings

      • CH-acidic Compounds

      • Aqueous Base

    • Reaction with Electrophiles

    • Reaction with Radicals

    • Cycloaddition

    • Pyrolysis

    • Aromatization

  • α-ketoenamines (Enaminones from 1,2-dicarbonyl Compounds)

    • Introduction

    • Reaction with Electrophiles

      • Acetals

      • Acyl Chloride

      • Quinone

    • Reaction with Nucleophiles

      • CH-acidic Compounds

      • Phenol Ether

      • Organometallic Compounds

      • Phenylhydrazine

      • Aqueous Base

    • Cycloaddition

      • Diazenes

      • Nitroalkenes

      • Acetylquinone

      • Phenyl Azide

    • Photochemistry

    • Aromatization

  • Heterofunctional Enaminones

    • Nitroenamines

    • Enaminoimines

    • Enaminothiones

  • Acknowledgement

  • References