Chapter 13. Acidity and Basicity of Enamines

  1. Zvi Rappoport Professor
  1. Javier Catalán1 and
  2. Francisco Garcia Blanco2

Published Online: 20 JUL 2004

DOI: 10.1002/0470024763.ch13

Enamines (1994)

Enamines (1994)

How to Cite

Catalán, J. and Blanco, F. G. (1994) Acidity and Basicity of Enamines, in Enamines (1994) (ed Z. Rappoport), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470024763.ch13

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. 1

    Departamento de Quimica Fisica Aplicada, Universidad Autonoma de Madrid, Cantoblanco, Madrid 28049, Spain

  2. 2

    Departamento de Quimica Fisica, Facultad de Farmacia, Ins. Pluridisciplinar Universidad Complutense de Madrid, Madrid 28040, Spain

Publication History

  1. Published Online: 20 JUL 2004
  2. Published Print: 31 AUG 1994

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Saul Patai and
  2. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471933397

Online ISBN: 9780470024768

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Summary

This chapter contains sections titled:

  • Introduction

  • Basicity of Enamines

    • Gas-phase Basicity

      • Protonation Site

      • Hydrogen Atom Affinities

      • Analogies with the Basicity of Saturated Amines

      • Ionization Energies

      • Theoretical Calculations

      • Analysis of Intrinsic Effects

      • Conjugation Indicators

    • Condensed-phase Basicity

      • Protonation Site

  • Acidity of Enamines

  • Hydrogen Bonding

    • Enamines with Primary Amino Group

    • Other Types of Enamines

    • Enamines with Secondary Amino Group

    • Solid State Studies

  • References