Chapter 14. Electrophilic and Nucleophilic Substitution and Addition Reactions of Enamines

  1. Zvi Rappoport Professor
  1. P. W. Hickmott

Published Online: 20 JUL 2004

DOI: 10.1002/0470024763.ch14

Enamines (1994)

Enamines (1994)

How to Cite

Hickmott, P. W. (1994) Electrophilic and Nucleophilic Substitution and Addition Reactions of Enamines, in Enamines (1994) (ed Z. Rappoport), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470024763.ch14

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. University of Natal, Durban, Natal, South Africa

  1. 7 Quentin Smythe Rd, Kloof, Natal 3610, South Africa

Publication History

  1. Published Online: 20 JUL 2004
  2. Published Print: 31 AUG 1994

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Saul Patai and
  2. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471933397

Online ISBN: 9780470024768

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Summary

This chapter contains sections titled:

  • Introduction

  • Protonation

    • Regioselectivity

    • Stereoselectivity

    • Asymmetric Induction

  • Alkylation

    • Reaction with Alkyl Halides

    • Reaction with Electrophilic Alkenes

    • Reaction with Electrophilic Alkynes

    • Arylation

    • Reaction with Aldehydes and Ketones

    • Reaction with Iminium Ions

    • Miscellaneous Alkylating Agents

    • Asymmetric Induction

  • Acylation

    • Reaction with Carboxylic Acid Chlorides, Anhydrides and Ketenes

    • Reaction with Sulphonyl and Sulphenyl Derivatives

    • Reaction with Isocyanates and Isothiocyanates

    • Miscellaneous Acylating Agents

  • Halogenation

  • Carbocyclic Synthesis

    • Three-membered Rings

    • Four-membered Rings

    • Five-membered Rings

    • Six-membered Rings

    • Seven-membered and Larger Rings

  • Miscellaneous Reactions

  • Secondary Enamines

  • References