Chapter 24. Synthesis of N-Acylenamines from Carbonyl Compounds and Nitriles

  1. Zvi Rappoport Professor
  1. Serge M. Lukyanov

Published Online: 20 JUL 2004

DOI: 10.1002/0470024763.ch24

Enamines (1994)

Enamines (1994)

How to Cite

Lukyanov, S. M. (1994) Synthesis of N-Acylenamines from Carbonyl Compounds and Nitriles, in Enamines (1994) (ed Z. Rappoport), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470024763.ch24

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. Institute of Physical and Organic Chemistry, Rostov University, 344711 Rostov on Don, Russia

Publication History

  1. Published Online: 20 JUL 2004
  2. Published Print: 31 AUG 1994

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Saul Patai and
  2. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471933397

Online ISBN: 9780470024768

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Summary

This chapter contains sections titled:

  • Introduction

  • Reactionl of Aldehydes with Nitriles

    • Formation of Bis-amides and Amidoalkylation Reagents

    • Syntheses of Heterocyclic Compounds

  • Reaction of Ketones with Nitriles

    • Intramolecular Reactions of Ketonitriles, Cyanoamides and Cyanoesters

    • Intermolecular Reactions of Ketones with Nitriles

      • Protic Acid-catalyzed Reactions of Ketones with Nitriles

      • Aprotic Acid-catalyzed Reactions of Ketones with Nitriles

      • Electrophilic Catalysis by Acyl Cations in Reactions of Ketones with Nitriles

  • Reactions of Nitriles with Carbonyl Compound Derivatives

  • Two Paths for the Reaction of Carbonyl Compounds with Nitriles

    • Reactions of Ketones with Nitrilium Salts?

    • Theoretical Calculations

    • Rearrangements during Formation of N-acylenamines

  • Polyfunctionalized Enamines

  • References