Chapter 3. Configuration, Conformation and Chiroptical Properties of Enamines

  1. Zvi Rappoport Professor
  1. Otakar Červinka

Published Online: 20 JUL 2004

DOI: 10.1002/0470024763.ch3

Enamines (1994)

Enamines (1994)

How to Cite

Červinka, O. (2004) Configuration, Conformation and Chiroptical Properties of Enamines, in Enamines (1994) (ed Z. Rappoport), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470024763.ch3

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. Department of Organic Chemistry, Institute of Chemical Technology, 166 28 Prague 6, Czech Republic

Publication History

  1. Published Online: 20 JUL 2004
  2. Published Print: 31 AUG 1994

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Saul Patai and
  2. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471933397

Online ISBN: 9780470024768

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Summary

This chapter contains sections titled:

  • Introduction

  • Configuration of Enamines

    • Z- and E-isomers

    • NMR Spectra of Z- and E-isomers

  • Geometrical Parameters of Enamines

  • Crystal Structures of Enamines

  • Conformation of Enamines

    • Internal Rotation about the C[BOND]C and C[BOND]N Bond in Enamines

    • Enamines with High Barrier to Rotation

    • Enamines of Cyclic Ketones

      • 2-substituted Cyclohexanones

      • 3-substituted Cyclohexanones

  • Configuration and Conformation of ‘Push–Pull’ Enamines

    • Enaminoketones and Enaminoesters

    • Nitroenamines

      • Effect of Solvents on Configuration of Nitroenamines

  • Stereochemistry of Metalloenamines

  • Stereochemistry of the Carbon–Nitrogen Double Bond in Enamines

  • Importance of Enamines in Asymmetric Synthesis and Their Chiroptical Properties

    • Optically Active Enamines

    • Chiroptical Properties of Enamines

  • References