Chapter 7. The Reactivity of Ionized Enamines in the Gas Phase

  1. Zvi Rappoport Professor
  1. Pierre Longevialle

Published Online: 20 JUL 2004

DOI: 10.1002/0470024763.ch7

Enamines (1994)

Enamines (1994)

How to Cite

Longevialle, P. (1994) The Reactivity of Ionized Enamines in the Gas Phase, in Enamines (1994) (ed Z. Rappoport), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470024763.ch7

Editor Information

  1. The Hebrew University, Jerusalem, Israel

Author Information

  1. Institut de Chimie des Substances Naturelles du Centre National de la Recherche Scientifique, 91190 Gif sur Yvette, France

Publication History

  1. Published Online: 20 JUL 2004
  2. Published Print: 31 AUG 1994

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Saul Patai and
  2. Zvi Rappoport

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471933397

Online ISBN: 9780470024768

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Summary

This chapter contains sections titled:

  • Introduction

  • General Considerations

  • Reactivity of Directly Ionized Enamines

    • Simple Ruptures

      • Allylic Cleavage

      • α-cleavage

      • Vinylic Cleavage of Haloenamines

    • Rearrangements

    • Miscellaneous

      • Retro-Diels–Alder (RDA) Reactions

      • Enamine–Imine Tautomerism

      • Dehydrogenation

  • Ionized Enamines as Reaction Intermediates

    • Rearrangement of Cycloalkylamines

    • Rearrangement of Imines

  • Acknowledgement

  • References