Chapter 12. Behavior of α-Sulfinyl and α-Sulfonyl Carbanions

  1. Professor Saul Patai3,
  2. Zvi Rappoport3 and
  3. Charles Stirling4
  1. Shigeru Oae1 and
  2. Yuzuru Uchida2

Published Online: 3 JUL 2006

DOI: 10.1002/0470034386.ch12

Sulphones and Sulphoxides (1988)

Sulphones and Sulphoxides (1988)

How to Cite

Oae, S. and Uchida, Y. (1988) Behavior of α-Sulfinyl and α-Sulfonyl Carbanions, in Sulphones and Sulphoxides (1988) (eds S. Patai, Z. Rappoport and C. Stirling), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470034386.ch12

Editor Information

  1. 3

    The Hebrew University, Jerusalem, Israel

  2. 4

    University College, Bangor, USA

Author Information

  1. 1

    Okayama University of Science, 1-1 Ridai-cho, Okayama 700, Japan

  2. 2

    Department of Applied Chemistry, Osaka Institute of Technology, Asahi-ku, Osaka 535, Japan

Publication History

  1. Published Online: 3 JUL 2006
  2. Published Print: 30 APR 1988

Book Series:

  1. PATAI'S Chemistry of Functional Groups

Book Series Editors:

  1. Professor Saul Patai

Series Editor Information

  1. The Hebrew University, Jerusalem, Israel

ISBN Information

Print ISBN: 9780471915881

Online ISBN: 9780470034385

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Keywords:

  • stereoelectronic effect of sulfur-containing group;
  • stereochemistry of α-sulfinyl carbanions;
  • α-sulfinyl carbanion reactions;
  • α-sulfonyl carbanion reactions;
  • alkylation and acylation;
  • Ramberg-Backlund reaction;
  • allylic sulfoxide reaction;
  • α-sulfinyl and α-sulfonyl carbanion chemical behavior

Summary

This chapter contains sections titled:

  • Introduction

  • Stereoelectronic Effects of Sulfur-Containing Groups

  • Stereochemistry of α-Sulfinyl Carbanions

  • Stereochemistry of α-Sulfonyl Carbanions

  • Reactions of α-Sulfinyl Carbanions

  • Reactions of α-Sulfonyl Carbanions

  • References