Chapter 9. Spatially Resolved Degradation in Heterophasic Polymers From 1D and 2D Spectral–Spatial ESR Imaging Experiments

  1. Dr. Shulamith Schlick D.Sc., M.Sc. Professor member
  1. Shulamith Schlick3 and
  2. Krzysztof Kruczala Faculty of Chemistry1,2

Published Online: 10 APR 2006

DOI: 10.1002/047005350X.ch9

Advanced ESR Methods in Polymer Research

Advanced ESR Methods in Polymer Research

How to Cite

Schlick, S. and Kruczala, K. (2006) Spatially Resolved Degradation in Heterophasic Polymers From 1D and 2D Spectral–Spatial ESR Imaging Experiments, in Advanced ESR Methods in Polymer Research (ed S. Schlick), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/047005350X.ch9

Editor Information

  1. Department of Chemistry and Biochemistry, University of Detroit Mercy, Detroit, Michigan, USA

Author Information

  1. 1

    Jagiellonian University, Cracow, Poland

  2. 2

    University of Detroit Mercy, Detroit, Michigan, USA

  3. 3

    Department of Chemistry and Biochemistry, University of Detroit Mercy, Detroit, Michigan, USA

Publication History

  1. Published Online: 10 APR 2006
  2. Published Print: 15 SEP 2006

ISBN Information

Print ISBN: 9780471731894

Online ISBN: 9780470053508

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Keywords:

  • degradation mechanism and polymer lifetime prediction;
  • diffusion-limited oxidation (DLO) concept;
  • spatially resolved degradation in heterophasic polymers

Summary

This chapter contains sections titled:

  • ESR Imaging (ESRI) as a Nondestructive Method for Spatially Resolved Degradation Studies

  • Experimental Details

  • ESR Spectra of Nitroxides Derived from Hindered Amine Stabilizers in Aged Heterophasic Polymers

  • 1D and 2D Spectral-Spatial ESRI in Aged Heterophasic Polymers

  • Conclusions

  • Acknowledgments

  • References