Chapter 4. NMR Relaxation by Dipole–Dipole and Quadrupole Interactions

  1. Vladimir I. Bakhmutov

Published Online: 22 AUG 2005

DOI: 10.1002/0470094486.ch4

Practical NMR Relaxation for Chemists

Practical NMR Relaxation for Chemists

How to Cite

Bakhmutov, V. I. (2004) NMR Relaxation by Dipole–Dipole and Quadrupole Interactions, in Practical NMR Relaxation for Chemists, John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470094486.ch4

Author Information

  1. Department of Chemistry, Texas A&M University, College Station, USA

Publication History

  1. Published Online: 22 AUG 2005
  2. Published Print: 26 NOV 2004

ISBN Information

Print ISBN: 9780470094464

Online ISBN: 9780470094488

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Keywords:

  • dipole–dipole interactions;
  • spectral density function;
  • heteronuclear dipolar coupling;
  • Bloembergen–Purcell–Pound form;
  • dipole–dipole NMR relaxation;
  • nuclear Overhauser effect (NOE);
  • Cp irradiation;
  • nuclear quadrupole resonance (NQR) studies;
  • electric field gradients (EFG);
  • Larmor frequency

Summary

This chapter contains sections titled:

  • Intramolecular Dipole–Dipole Relaxation: Homo- and Heteronuclear Dipolar Coupling and the Spectral Density Function

  • How to Reveal the Presence of the Dipolar Mechanism

  • Intermolecular Dipole–Dipole Interactions

  • Electric Field Gradients at Quadrupolar Nuclei

  • Nuclear Quadrupole Coupling Constant as Measure of the Electric Field Gradient

  • Quadrupole Relaxation

  • Bibliography