Chapter 8. Internuclear Distances from 1H T1 Relaxation Measurements in Solution

  1. Vladimir I. Bakhmutov

Published Online: 22 AUG 2005

DOI: 10.1002/0470094486.ch8

Practical NMR Relaxation for Chemists

Practical NMR Relaxation for Chemists

How to Cite

Bakhmutov, V. I. (2004) Internuclear Distances from 1H T1 Relaxation Measurements in Solution, in Practical NMR Relaxation for Chemists, John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470094486.ch8

Author Information

  1. Department of Chemistry, Texas A&M University, College Station, USA

Publication History

  1. Published Online: 22 AUG 2005
  2. Published Print: 26 NOV 2004

ISBN Information

Print ISBN: 9780470094464

Online ISBN: 9780470094488

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Keywords:

  • heteronuclear dipolar coupling;
  • dipole–dipole interactions;
  • chemical shift anisotropy;
  • DRAMA and REDOR experiments;
  • rhenium–hydride dipolar coupling;
  • dipolar coupling;
  • isotopic chemical shift;
  • metal–hydride contributions;
  • proton–proton dipole–dipole contributions

Summary

This chapter contains sections titled:

  • X-H Distances: Metal–Hydride Bond Lengths

  • Proton–Proton Distances by Standard 1H T1 Measurements

  • H-H Distances by T1sel/T1bis Measurements

  • H...H Distances in Intermediates

  • Analyzing the Errors in 1H T1 Determinations of Internuclear Distances

  • Bibliography