Chapter 9. Deuterium Quadrupole Coupling Constants from 2H T1 Relaxation Measurements in Solution

  1. Vladimir I. Bakhmutov

Published Online: 22 AUG 2005

DOI: 10.1002/0470094486.ch9

Practical NMR Relaxation for Chemists

Practical NMR Relaxation for Chemists

How to Cite

Bakhmutov, V. I. (2004) Deuterium Quadrupole Coupling Constants from 2H T1 Relaxation Measurements in Solution, in Practical NMR Relaxation for Chemists, John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/0470094486.ch9

Author Information

  1. Department of Chemistry, Texas A&M University, College Station, USA

Publication History

  1. Published Online: 22 AUG 2005
  2. Published Print: 26 NOV 2004

ISBN Information

Print ISBN: 9780470094464

Online ISBN: 9780470094488

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Keywords:

  • quadrupolar nuclei;
  • nuclear quadrupole coupling constants;
  • full line shape analysis;
  • Stokes–Einstein–Debye model;
  • deuterium relaxation;
  • molecular tumbling;
  • organic glassforming liquid;
  • symmetric Fuoss–Kirkwood correlation time distribution;
  • Vogel–Fulcher–Tamman (VFT) equation

Summary

This chapter contains sections titled:

  • How to Determine DQCC Values

  • DQCC Values from 2H T1 Measurements in Solution (Fast Motion Regime)

  • DQCC Values via 2H T1min Measurements in Solution

  • Errors in DQCC Determinations

  • Bibliography