Standard Article

(S)-Aceto(carbonyl)(cyclopentadienyl)-(triphenylphosphine)iron

  1. Mark E. Welker

Published Online: 15 APR 2001

DOI: 10.1002/047084289X.ra011

e-EROS Encyclopedia of Reagents for Organic Synthesis

e-EROS Encyclopedia of Reagents for Organic Synthesis

How to Cite

Welker, M. E. 2001. (S)-Aceto(carbonyl)(cyclopentadienyl)-(triphenylphosphine)iron. e-EROS Encyclopedia of Reagents for Organic Synthesis. .

Author Information

  1. Wake Forest University, Winston-Salem, NC, USA

Publication History

  1. Published Online: 15 APR 2001

Abstract

original image

[36548-60-4] C26H23FeO2P (MW 454.29)

(chiral acetate enolate equivalent which can be deprotonated with BuLi or LDA in THF at −78°C; the enolate reacts stereoselectively with a variety of achiral, prochiral, and chiral electrophiles to generate functionalized organoiron compounds from which the iron can subsequently be removed 1)

Physical Data: mp 142°C; [α]22 + 288° (c 0.004, C6H6), [α]20 + 160° (c 0.04, C6H6).

Solubility: insol H2O; sol THF, CHCl3,CH2Cl2, acetone.

Form Supplied in: orange solid.

Handling, Storage, and Precautions: can be stored in air for days with little decomposition. The solid is best stored under nitrogen for long periods of time. More air sensitive when in solution, especially chlorinated hydrocarbons. Like all metal carbonyls, it is best handled in a fume hood.

Featured Compounds

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  1. 1 - 62
Compound Information
Molecular Weight:653.525
Molecular Formula:C36H40FeNO5P
InChIKey:MUEVIPAFRRIWNV-FEZJIZSDSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:238.303
Molecular Formula:C12H14O3S
InChIKey:VLHQNZIPSBLCKM-UHFFFAOYSA-N
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Compound Information
Molecular Weight:199.2469
Molecular Formula:C10H17NO3
InChIKey:YDBPZCVWPFMBDH-QMMMGPOBSA-N
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Compound Information
Molecular Weight:118.97
Molecular Formula:Cl2OS
InChIKey:FYSNRJHAOHDILO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:204.737
Molecular Formula:C11H21ClO
InChIKey:XOPLTFUYFXWFGB-OUAUKWLOSA-N
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Compound Information
Molecular Weight:74.1216
Molecular Formula:C4H10O
InChIKey:RTZKZFJDLAIYFH-UHFFFAOYSA-N
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Compound Information
Molecular Weight:704.592
Molecular Formula:C39H37FeO5PS
InChIKey:YCCMZCFPTWQDEE-CTXQUVPRSA-N
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Compound Information
Molecular Weight:21.976
Molecular Formula:CH3Li
InChIKey:Not Available
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Compound Information
Molecular Weight:108.642
Molecular Formula:C3H9ClSi
InChIKey:IJOOHPMOJXWVHK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:454.278
Molecular Formula:C26H23FeO2P
InChIKey:KDGHBSXKTMOCFC-UHFFFAOYSA-N
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Compound Information
Molecular Weight:247.3758
Molecular Formula:C16H25NO
InChIKey:LILYYVIDWDRMNR-ZIAGYGMSSA-N
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Compound Information
Molecular Weight:220.635
Molecular Formula:C12H10ClP
InChIKey:XGRJZXREYAXTGV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:22.98976928
Molecular Formula:HNa
InChIKey:MPMYQQHEHYDOCL-UHFFFAOYSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:552.464
Molecular Formula:C33H37FeO2P
InChIKey:CSKNVWJJHQXTDH-ZMMXZZSYSA-N
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Compound Information
Molecular Weight:34.081
Molecular Formula:H2S
InChIKey:RWSOTUBLDIXVET-UHFFFAOYSA-N
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Compound Information
Molecular Weight:454.278
Molecular Formula:C26H23FeO2P
InChIKey:KDGHBSXKTMOCFC-UHFFFAOYSA-N
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Compound Information
Molecular Weight:171.2368
Molecular Formula:C9H17NO2
InChIKey:XJJBXZIKXFOMLP-ZETCQYMHSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:622.554
Molecular Formula:C37H43FeO3P
InChIKey:MHJHOLADAHJYDU-IEGUEYASSA-N
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Compound Information
Molecular Weight:120.557
Molecular Formula:C4H10AlCl
InChIKey:YNLAOSYQHBDIKW-UHFFFAOYSA-M
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Compound Information
Molecular Weight:552.421
Molecular Formula:C32H33FeO3P
InChIKey:ZYYIRATXQDBLMD-YDSACBPOSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:183.11
Molecular Formula:C5H11BrS
InChIKey:IOOVIEPOANDFGD-UHFFFAOYSA-N
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Compound Information
Molecular Weight:217.285
Molecular Formula:C9H15NO3S
InChIKey:FAKRSMQSSFJEIM-BQBZGAKWSA-N
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Compound Information
Molecular Weight:84.1164
Molecular Formula:C5H8O
InChIKey:QUMSUJWRUHPEEJ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:195.054
Molecular Formula:C6H11BrO2
InChIKey:BNWCETAHAJSBFG-UHFFFAOYSA-N
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Compound Information
Molecular Weight:114.0233
Molecular Formula:C2HF3O2
InChIKey:DTQVDTLACAAQTR-UHFFFAOYSA-N
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Compound Information
Molecular Weight:46.0684
Molecular Formula:C2H6O
InChIKey:LFQSCWFLJHTTHZ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:84.933
Molecular Formula:CH2Cl2
InChIKey:YMWUJEATGCHHMB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:587.469
Molecular Formula:C35H34FeNO2P
InChIKey:KVSDBBIBSOILGQ-WFLPUWFGSA-N
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Compound Information
Molecular Weight:64.055
Molecular Formula:C4H9Li
InChIKey:MZRVEZGGRBJDDB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:168.2328
Molecular Formula:C10H16O2
InChIKey:OUOUWBWADJGCBT-VIFPVBQESA-N
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Compound Information
Molecular Weight:480.316
Molecular Formula:C28H25FeO2P
InChIKey:NIHFFVCILVYABZ-GGMKUFPDSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:159.808
Molecular Formula:Br2
InChIKey:GDTBXPJZTBHREO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:638.452
Molecular Formula:C38H32FeO2P2
InChIKey:DTWGULUYQPBLEP-UHFFFAOYSA-N
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Compound Information
Molecular Weight:570.503
Molecular Formula:C32H35FeO2PS
InChIKey:GPERLQXCPJOPIN-SGDVDTHRSA-N
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Compound Information
Molecular Weight:594.501
Molecular Formula:C35H39FeO3P
InChIKey:VAJDZKTWKROVBN-SRBLSALOSA-N
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Compound Information
Molecular Weight:534.406
Molecular Formula:C32H31FeO2P
InChIKey:GIWOFKJWTDDFDP-KXIXAYKLSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:189.62
Molecular Formula:Cl2Sn
InChIKey:Not Available
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Compound Information
Molecular Weight:130.1418
Molecular Formula:C6H10O3
InChIKey:Not Available
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Compound Information
Molecular Weight:141.1677
Molecular Formula:C7H11NO2
InChIKey:WHRVGBMTDGBUGH-NTSWFWBYSA-N
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Compound Information
Molecular Weight:468.305
Molecular Formula:C27H25FeO2P
InChIKey:ZLGGDXKUBUEBRR-UHFFFAOYSA-N
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Compound Information
Molecular Weight:318.68
Molecular Formula:C4H6HgO4
InChIKey:BRMYZIKAHFEUFJ-UHFFFAOYSA-L
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:584.42
Molecular Formula:C32H33FeO5P
InChIKey:HYLTTYYJCSCBJQ-POFGDTKNSA-N
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Compound Information
Molecular Weight:175.227
Molecular Formula:C11H13NO
InChIKey:LTZANYLTVNPGTG-VIFPVBQESA-N
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Compound Information
Molecular Weight:141.939
Molecular Formula:CH3I
InChIKey:INQOMBQAUSQDDS-UHFFFAOYSA-N
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Compound Information
Molecular Weight:113.086
Molecular Formula:C7H8LiN
InChIKey:ZLRWTBOIOQQDBJ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:526.46
Molecular Formula:C29H31FeO2PSi
InChIKey:OWIDSBADRXOCFH-UHFFFAOYSA-N
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Compound Information
Molecular Weight:107.1531
Molecular Formula:C7H9N
InChIKey:WGQKYBSKWIADBV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:172.202
Molecular Formula:C7H8O3S
InChIKey:JOXIMZWYDAKGHI-UHFFFAOYSA-N
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Compound Information
Molecular Weight:72.1057
Molecular Formula:C4H8O
InChIKey:WYURNTSHIVDZCO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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