Standard Article

Calcium Hypochlorite

  1. Philip M. Keehn1,
  2. Stephan O. Nwaukwa2,
  3. Amol A. Kulkarni3

Published Online: 16 SEP 2013

DOI: 10.1002/047084289X.rc006.pub2

e-EROS Encyclopedia of Reagents for Organic Synthesis

e-EROS Encyclopedia of Reagents for Organic Synthesis

How to Cite

Keehn, P. M., Nwaukwa, S. O. and Kulkarni, A. A. 2013. Calcium Hypochlorite. e-EROS Encyclopedia of Reagents for Organic Synthesis. .

Author Information

  1. 1

    Ondo State University, Ado-Ekiti, Nigeria

  2. 2

    Brandeis University, Waltham, MA, USA

  3. 3

    Howard University, Washington, DC, USA

Publication History

  1. Published Online: 16 SEP 2013

Chemistry Terms

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Abstract

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[7778-54-3] CaCl2O2 (MW 142.99)

(oxidizing agent for the conversion of alcohols to aldehydes,2 ketones,3 carboxylic acids,4 esters,3 and methyl esters;5 aldehydes to acids6 and t-butyl esters;5 ethers to esters,3 and thioethers to sulfoxides;7 for the C[BOND]C bond cleavage of 1,2-dioxygenated compounds;8 for the chlorination of benzenoid compounds;1 for the conversion of alkenes to chlorohydrins9)

Alternative Names:calcium oxychloride; hypochlorous acid, calcium salt; B-K powder.

Physical Data: mp 100 °C; specific gravity 2.35.

Solubility: insol organic solvents; slightly sol H2O (with decomposition); very sol H2O with a few drops of HOAc; aqueous solutions of acetic acid, acetonitrile, acetone, MeOH, and t-butanol, and biphasic solutions of H2O with EtOAc, CH2Cl2, ether, benzene, and CCl4 are used for oxidations.

Form Supplied in: white or light yellow granular solid with strong chlorine odor; widely available.

Purification: composition is generally 60–70% Ca(OCl)2 [Ca(OCl)2, 65%; NaCl, 15%; H2O, 10%; Ca(OH)2, 4%; CaCO3, 3%; CaClO3, 1.5%; CaCl2, 1%].10

Handling, Storage, and Precautions: commercially available Ca(OCl)2 (65%) is easy to handle and may be stored in a desiccator without substantial decomposition.11 Anhydrous Ca(OCl)2 must be stored in a brown bottle kept away from sunlight and moisture. It explodes when in direct contact with organic material, especially lubrication oils. This reagent should be handled in a fume hood.

Featured Compounds

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  1. 1 - 138
Compound Information
Molecular Weight:142.983
Molecular Formula:CaCl2O2
InChIKey:ZKQDCIXGCQPQNV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:88.1482
Molecular Formula:C5H12O
InChIKey:AMQJEAYHLZJPGS-UHFFFAOYSA-N
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Compound Information
Molecular Weight:172.2646
Molecular Formula:C10H20O2
InChIKey:FGPPDYNPZTUNIU-UHFFFAOYSA-N
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Compound Information
Molecular Weight:41.0519
Molecular Formula:C2H3N
InChIKey:WEVYAHXRMPXWCK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:18.0153
Molecular Formula:H2O
InChIKey:XLYOFNOQVPJJNP-UHFFFAOYSA-N
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Compound Information
Molecular Weight:60.052
Molecular Formula:C2H4O2
InChIKey:QTBSBXVTEAMEQO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:218.2469
Molecular Formula:C10H18O5
InChIKey:WGJOJZRXTABKKH-BZNPZCIMSA-N
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Compound Information
Molecular Weight:32.0419
Molecular Formula:CH4O
InChIKey:OKKJLVBELUTLKV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:246.257
Molecular Formula:C11H18O6
InChIKey:VTRVPRNANKHFEJ-XCWAXFADSA-N
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Compound Information
Molecular Weight:114.1855
Molecular Formula:C7H14O
InChIKey:VSSAZBXXNIABDN-UHFFFAOYSA-N
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Compound Information
Molecular Weight:128.169
Molecular Formula:C7H12O2
InChIKey:Not Available
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Compound Information
Molecular Weight:74.1216
Molecular Formula:C4H10O
InChIKey:DKGAVHZHDRPRBM-UHFFFAOYSA-N
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Compound Information
Molecular Weight:100.1589
Molecular Formula:C6H12O
InChIKey:UNNGUFMVYQJGTD-UHFFFAOYSA-N
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Compound Information
Molecular Weight:116.1583
Molecular Formula:C6H12O2
InChIKey:OXQGTIUCKGYOAA-UHFFFAOYSA-N
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Compound Information
Molecular Weight:140.567
Molecular Formula:C7H5ClO
InChIKey:AVPYQKSLYISFPO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:156.566
Molecular Formula:C7H5ClO2
InChIKey:XRHGYUZYPHTUJZ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:210.3556
Molecular Formula:C14H26O
InChIKey:IAHLRPQGNFWAQX-UHFFFAOYSA-N
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Compound Information
Molecular Weight:208.3398
Molecular Formula:C14H24O
InChIKey:ADDKUKYGCBBLAM-UHFFFAOYSA-N
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Compound Information
Molecular Weight:84.933
Molecular Formula:CH2Cl2
InChIKey:YMWUJEATGCHHMB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:154.2493
Molecular Formula:C10H18O
InChIKey:DTGKSKDOIYIVQL-QXFUBDJGSA-N
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Compound Information
Molecular Weight:152.2334
Molecular Formula:C10H16O
InChIKey:DSSYKIVIOFKYAU-OIBJUYFYSA-N
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Compound Information
Molecular Weight:86.1323
Molecular Formula:C5H10O
InChIKey:XCIXKGXIYUWCLL-UHFFFAOYSA-N
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Compound Information
Molecular Weight:84.1164
Molecular Formula:C5H8O
InChIKey:BGTOWKSIORTVQH-UHFFFAOYSA-N
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Compound Information
Molecular Weight:153.823
Molecular Formula:CCl4
InChIKey:VZGDMQKNWNREIO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:130.2279
Molecular Formula:C8H18O
InChIKey:DURPTKYDGMDSBL-UHFFFAOYSA-N
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Compound Information
Molecular Weight:144.2114
Molecular Formula:C8H16O2
InChIKey:XUPYJHCZDLZNFP-UHFFFAOYSA-N
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Compound Information
Molecular Weight:72.1057
Molecular Formula:C4H8O
InChIKey:WYURNTSHIVDZCO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:86.0892
Molecular Formula:C4H6O2
InChIKey:Not Available
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Compound Information
Molecular Weight:146.294
Molecular Formula:C8H18S
InChIKey:HTIRHQRTDBPHNZ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:162.293
Molecular Formula:C8H18OS
InChIKey:LOWMYOWHQMKBTM-UHFFFAOYSA-N
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Compound Information
Molecular Weight:88.1051
Molecular Formula:C4H8O2
InChIKey:XEKOWRVHYACXOJ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:366.4517
Molecular Formula:C26H22O2
InChIKey:MFEWNFVBWPABCX-UHFFFAOYSA-N
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Compound Information
Molecular Weight:182.2179
Molecular Formula:C13H10O
InChIKey:RWCCWEUUXYIKHB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:138.097
Molecular Formula:C5H7NaO3
InChIKey:PPAYYZDRYXSSMC-UHFFFAOYSA-M
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Compound Information
Molecular Weight:88.1051
Molecular Formula:C4H8O2
InChIKey:FERIUCNNQQJTOY-UHFFFAOYSA-N
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Compound Information
Molecular Weight:196.1999
Molecular Formula:C10H12O4
InChIKey:YIRAEUKOPKEBHB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:150.1314
Molecular Formula:C8H6O3
InChIKey:SATCULPHIDQDRE-UHFFFAOYSA-N
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Compound Information
Molecular Weight:78.1118
Molecular Formula:C6H6
InChIKey:UHOVQNZJYSORNB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:230.645
Molecular Formula:C10H11ClO4
InChIKey:RMOZNWVQKLMABA-UHFFFAOYSA-N
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Compound Information
Molecular Weight:92.1384
Molecular Formula:C7H8
InChIKey:YXFVVABEGXRONW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:126.583
Molecular Formula:C7H7Cl
InChIKey:Not Available
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Compound Information
Molecular Weight:58.0791
Molecular Formula:C3H6O
InChIKey:CSCPPACGZOOCGX-UHFFFAOYSA-N
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Compound Information
Molecular Weight:135.1632
Molecular Formula:C8H9NO
InChIKey:FZERHIULMFGESH-UHFFFAOYSA-N
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Compound Information
Molecular Weight:169.608
Molecular Formula:C8H8ClNO
InChIKey:GGUOCFNAWIODMF-UHFFFAOYSA-N
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Compound Information
Molecular Weight:108.1378
Molecular Formula:C7H8O
InChIKey:RDOXTESZEPMUJZ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:142.583
Molecular Formula:C7H7ClO
InChIKey:YRGAYAGBVIXNAQ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:120.1485
Molecular Formula:C8H8O
InChIKey:FXLOVSHXALFLKQ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:170.593
Molecular Formula:C8H7ClO2
InChIKey:SDKUOEOJAXGCLU-UHFFFAOYSA-N
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Compound Information
Molecular Weight:136.1479
Molecular Formula:C8H8O2
InChIKey:Not Available
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Compound Information
Molecular Weight:170.593
Molecular Formula:C8H7ClO2
InChIKey:HXTWDGGMXZXOIV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:84.1595
Molecular Formula:C6H12
InChIKey:WSSSPWUEQFSQQG-UHFFFAOYSA-N
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Compound Information
Molecular Weight:136.62
Molecular Formula:C6H13ClO
InChIKey:ORMLBVVDWANTSH-UHFFFAOYSA-N
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Compound Information
Molecular Weight:166.3031
Molecular Formula:C12H22
InChIKey:HYPABJGVBDSCIT-UPHRSURJSA-N
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Compound Information
Molecular Weight:218.763
Molecular Formula:C12H23ClO
InChIKey:ZQBSIIHTGXIKHM-UHFFFAOYSA-N
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Compound Information
Molecular Weight:96.1702
Molecular Formula:C7H12
InChIKey:CTMHWPIWNRWQEG-UHFFFAOYSA-N
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Compound Information
Molecular Weight:148.631
Molecular Formula:C7H13ClO
InChIKey:LXJVQOYQFQDGCJ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:84.1595
Molecular Formula:C6H12
InChIKey:Not Available
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Compound Information
Molecular Weight:136.62
Molecular Formula:C6H13ClO
InChIKey:ZZXOPZKZPDCFRL-UHFFFAOYSA-N
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Compound Information
Molecular Weight:151.1195
Molecular Formula:C7H5NO3
InChIKey:ZETIVVHRRQLWFW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:167.1189
Molecular Formula:C7H5NO4
InChIKey:AFPHTEQTJZKQAQ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:322.3282
Molecular Formula:C17H19FO5
InChIKey:YCRMTXNGUKEDMC-GAGVYUBLSA-N
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Compound Information
Molecular Weight:141.939
Molecular Formula:CH3I
InChIKey:INQOMBQAUSQDDS-UHFFFAOYSA-N
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Compound Information
Molecular Weight:140.567
Molecular Formula:C7H5ClO
InChIKey:PASDCCFISLVPSO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:558.5504
Molecular Formula:C32H27FO8
InChIKey:ZQLIICCREMORGO-BDWVSHPJSA-N
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Compound Information
Molecular Weight:156.2453
Molecular Formula:C9H18NO
InChIKey:VUZNLSBZRVZGIK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:119.002
Molecular Formula:BrK
InChIKey:IOLCXVTUBQKXJR-UHFFFAOYSA-M
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Compound Information
Molecular Weight:322.368
Molecular Formula:C16H36BrN
InChIKey:Not Available
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Compound Information
Molecular Weight:100.1151
Molecular Formula:CHKO3
InChIKey:TYJJADVDDVDEDZ-UHFFFAOYSA-M
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Compound Information
Molecular Weight:73.0938
Molecular Formula:C3H7NO
InChIKey:ZMXDDKWLCZADIW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:79.0999
Molecular Formula:C5H5N
InChIKey:Not Available
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Compound Information
Molecular Weight:526.9178
Molecular Formula:C34H70O3
InChIKey:FPANUMIEHBAVHF-WEYITEOPSA-N
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Compound Information
Molecular Weight:540.9013
Molecular Formula:C34H68O4
InChIKey:ZYCZTNSYFHJQGK-SIURAHGXSA-N
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Compound Information
Molecular Weight:276.3508
Molecular Formula:C16H22NO3
InChIKey:DRFYZAIGLPMIOS-UHFFFAOYSA-N
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Compound Information
Molecular Weight:84.0066
Molecular Formula:CHNaO3
InChIKey:UIIMBOGNXHQVGW-UHFFFAOYSA-M
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Compound Information
Molecular Weight:118.1742
Molecular Formula:C6H14O2
InChIKey:YVHAOWGRHCPODY-UHFFFAOYSA-N
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Compound Information
Molecular Weight:380.4181
Molecular Formula:C26H21OP
InChIKey:MZRSAJZDYIISJW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:218.2915
Molecular Formula:C14H18O2
InChIKey:IZBIILHAJJUBNU-UHFFFAOYSA-N
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Compound Information
Molecular Weight:108.1378
Molecular Formula:C7H8O
InChIKey:WVDDGKGOMKODPV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:100.1589
Molecular Formula:C6H12O
InChIKey:Not Available
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Compound Information
Molecular Weight:106.1219
Molecular Formula:C7H6O
InChIKey:HUMNYLRZRPPJDN-UHFFFAOYSA-N
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Compound Information
Molecular Weight:101.9613
Molecular Formula:Al2O3
InChIKey:TWNQGVIAIRXVLR-UHFFFAOYSA-N
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Compound Information
Molecular Weight:80.155
Molecular Formula:C4H8O
InChIKey:Not Available
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Compound Information
Molecular Weight:92.1262
Molecular Formula:C4H6O2
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:339.534
Molecular Formula:C16H37NO4S
InChIKey:SHFJWMWCIHQNCP-UHFFFAOYSA-M
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:222.1576
Molecular Formula:C8H6N4O4
InChIKey:UTMXMYSMOXIBFN-UHFFFAOYSA-N
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Compound Information
Molecular Weight:220.1418
Molecular Formula:C8H4N4O4
InChIKey:UESRQNZMQYMVKM-UHFFFAOYSA-N
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Compound Information
Molecular Weight:301.385
Molecular Formula:C20H19N3
InChIKey:AERMLBOANSQCPP-UHFFFAOYSA-N
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Compound Information
Molecular Weight:297.3532
Molecular Formula:C20H15N3
InChIKey:ZUADNMDNEIWVSE-UHFFFAOYSA-N
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Compound Information
Molecular Weight:238.752
Molecular Formula:C11H23ClO3
InChIKey:RZGNWIKURMOARN-UHFFFAOYSA-N
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Compound Information
Molecular Weight:220.736
Molecular Formula:C11H21ClO2
InChIKey:QKSSIMYMJNDYTD-UHFFFAOYSA-N
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Compound Information
Molecular Weight:211.473
Molecular Formula:C7H5Cl3O
InChIKey:QTAATZDGGZYBDC-UHFFFAOYSA-N
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Compound Information
Molecular Weight:412.092
Molecular Formula:C16H14Cl4O4
InChIKey:XTILCGCXDPSPCK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:263.643
Molecular Formula:C11H9ClF3NO
InChIKey:NYKQLCKADZQGMT-UHFFFAOYSA-N
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Compound Information
Molecular Weight:279.643
Molecular Formula:C11H9ClF3NO2
InChIKey:IILDQQXNUSYLPA-UHFFFAOYSA-N
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Compound Information
Molecular Weight:298.089
Molecular Formula:C11H8Cl2F3NO
InChIKey:KVIMYRSZRIRUKW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:314.088
Molecular Formula:C11H8Cl2F3NO2
InChIKey:MOYVWIIJNAMQLM-UHFFFAOYSA-N
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Compound Information
Molecular Weight:277.67
Molecular Formula:C12H11ClF3NO
InChIKey:POLOUVOJVHOHKQ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:293.669
Molecular Formula:C12H11ClF3NO2
InChIKey:JWXPVEYHVBDEPA-UHFFFAOYSA-N
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Compound Information
Molecular Weight:308.641
Molecular Formula:C11H8ClF3N2O3
InChIKey:KDLRBIHJKQMZJF-UHFFFAOYSA-N
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Compound Information
Molecular Weight:324.64
Molecular Formula:C11H8ClF3N2O4
InChIKey:UIJJOYMWHUXHGE-UHFFFAOYSA-N
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Compound Information
Molecular Weight:308.641
Molecular Formula:C11H8ClF3N2O3
InChIKey:HGOJMPSCQXZWMI-UHFFFAOYSA-N
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Compound Information
Molecular Weight:324.64
Molecular Formula:C11H8ClF3N2O4
InChIKey:LLZCFYOCRIPNFW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:256.298
Molecular Formula:C19H12O
InChIKey:GFMONBJSESZYCV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:272.2974
Molecular Formula:C19H12O2
InChIKey:ACJJXELQAJQSLK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:635.201
Molecular Formula:C36H52ClMnN2O2
InChIKey:LJVAWOSDJSQANR-RUIQGICGSA-K
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Compound Information
Molecular Weight:171.1953
Molecular Formula:C11H9NO
InChIKey:VZOPVKZLLGMDDG-UHFFFAOYSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:358.3851
Molecular Formula:C20H22O6
InChIKey:YOOKPIGRXLTXFP-TYLNLJTHSA-N
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Compound Information
Molecular Weight:392.83
Molecular Formula:C20H21ClO6
InChIKey:IXYWHKVYGVAWAE-FYSXIRJSSA-N
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Compound Information
Molecular Weight:328.288
Molecular Formula:C16H26BrNO
InChIKey:FRBLRBVJFALKDO-HNRFISLBSA-N
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Compound Information
Molecular Weight:362.733
Molecular Formula:C16H25BrClNO
InChIKey:MHXYUBRKAJSMEM-NHXNDTTKSA-N
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Compound Information
Molecular Weight:356.4553
Molecular Formula:C22H28O4
InChIKey:VQVAHOGBDLONFG-PHQMKEISSA-N
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Compound Information
Molecular Weight:390.9
Molecular Formula:C22H27ClO4
InChIKey:MHDNGUJNMDGHHB-PHQMKEISSA-N
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Compound Information
Molecular Weight:138.2069
Molecular Formula:C9H14O
InChIKey:VFEUNYPJZDTDLX-RMKNXTFCSA-N
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Compound Information
Molecular Weight:172.652
Molecular Formula:C9H13ClO
InChIKey:NVWCWTRIILFMAM-XBXARRHUSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:136.169
Molecular Formula:HKO4S
InChIKey:CHKVPAROMQMJNQ-UHFFFAOYSA-M
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:196.309
Molecular Formula:AlCl3CrH4Li
InChIKey:RQPPSWNMCUJFQE-UHFFFAOYSA-K
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Compound Information
Molecular Weight:60.095
Molecular Formula:C3H8O
InChIKey:KFZMGEQAYNKOFK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:166.217
Molecular Formula:C10H14O2
InChIKey:IQBZOAYOGMNFPL-SCZZXKLOSA-N
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Compound Information
Molecular Weight:200.662
Molecular Formula:C10H13ClO2
InChIKey:ZKGYBYJDHKOARW-SCZZXKLOSA-N
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