Standard Article

Methyltrioxorhenium

  1. Andrew Hudson1,
  2. Daniel Betz2,
  3. Fritz E. Kühn2,
  4. Guillermo H. Jiménez-Alemán3,
  5. Wilhelm Boland3

Published Online: 16 SEP 2013

DOI: 10.1002/047084289X.rn00017.pub3

e-EROS Encyclopedia of Reagents for Organic Synthesis

e-EROS Encyclopedia of Reagents for Organic Synthesis

How to Cite

Hudson, A., Betz, D., Kühn, F. E., Jiménez-Alemán, G. H. and Boland, W. 2013. Methyltrioxorhenium. e-EROS Encyclopedia of Reagents for Organic Synthesis. .

Author Information

  1. 1

    Wayne State University, Detroit, Michigan, USA

  2. 2

    Technische Universität München, Garching, Germany

  3. 3

    Max Planck Institute for Chemical Ecology, Jena, Germany

Publication History

  1. Published Online: 16 SEP 2013

Chemistry Terms

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Abstract

original image

[70197-13-6] CH3O3Re (MW 250)

InChI = 1S/CH3.3O.Re/h1H3;;;;

InChIKey = PQTLALPZRPFYIT-UHFFFAOYSA-N

(catalyst in the hydrogen peroxide oxidation of numerous compounds, including the well-studied epoxidation of alkenes.5 Catalyzes 1,3-allylic transpositions,6 the metathesis of alkenes7, 8 and aldehyde olefination9, 10)

Physical Data: thermally stable white solid, mp 111 °C. Hydrolyzed rapidly in basic aqueous solutions but much slower in acidic solutions. Deactivated under photolysis conditions.

Solubility: highly soluble in virtually any solvent from pentane to water.

Form Supplied in: commercially available from Aldrich and Fluka.

Featured Compounds

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  1. 1 - 109
Compound Information
Molecular Weight:249.24
Molecular Formula:CH3O3Re
InChIKey:PQTLALPZRPFYIT-UHFFFAOYSA-N
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Compound Information
Molecular Weight:321.302
Molecular Formula:C4H7O5Re
InChIKey:YXEXMQGCYQKOQV-UHFFFAOYSA-M
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Compound Information
Molecular Weight:139.488
Molecular Formula:C3H6O2Zn
InChIKey:BEUQZEAGWZHFJE-UHFFFAOYSA-M
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Compound Information
Molecular Weight:1134.9843
Molecular Formula:C42H70O35
InChIKey:WHGYBXFWUBPSRW-FOUAGVGXSA-N
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Compound Information
Molecular Weight:1384.224
Molecular Formula:C43H73O38Re
InChIKey:SVMRZOVXFXPKFW-QTVIMXQPSA-N
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Compound Information
Molecular Weight:160.2124
Molecular Formula:C11H12O
InChIKey:Not Available
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Compound Information
Molecular Weight:176.2118
Molecular Formula:C11H12O2
InChIKey:AXWDPRJZZIUQPF-UHFFFAOYSA-N
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Compound Information
Molecular Weight:194.2271
Molecular Formula:C11H14O3
InChIKey:XPERSQUJKVIRHQ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:34.0147
Molecular Formula:H2O2
InChIKey:MHAJPDPJQMAIIY-UHFFFAOYSA-N
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Compound Information
Molecular Weight:82.1038
Molecular Formula:C4H6N2
InChIKey:MCTWTZJPVLRJOU-UHFFFAOYSA-N
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Compound Information
Molecular Weight:84.933
Molecular Formula:CH2Cl2
InChIKey:YMWUJEATGCHHMB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:120.1916
Molecular Formula:C9H12
InChIKey:GWHJZXXIDMPWGX-UHFFFAOYSA-N
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Compound Information
Molecular Weight:150.1745
Molecular Formula:C9H10O2
InChIKey:QIXDHVDGPXBRRD-UHFFFAOYSA-N
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Compound Information
Molecular Weight:426.7174
Molecular Formula:C30H50O
InChIKey:SKPHINUIWICKNQ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:446.7055
Molecular Formula:C29H50O3
InChIKey:MMRJMBZSARWOAY-UHFFFAOYSA-N
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Compound Information
Molecular Weight:46.0684
Molecular Formula:C2H6O
InChIKey:LFQSCWFLJHTTHZ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:126.043
Molecular Formula:Na2O3S
InChIKey:GEHJYWRUCIMESM-UHFFFAOYSA-L
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Compound Information
Molecular Weight:271.162
Molecular Formula:C12H8Cl2OS
InChIKey:KJGYFISADIZFEL-UHFFFAOYSA-N
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Compound Information
Molecular Weight:255.163
Molecular Formula:C12H8Cl2S
InChIKey:MJEPOVIWHVRBIT-UHFFFAOYSA-N
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Compound Information
Molecular Weight:108.2132
Molecular Formula:C6H8Si
InChIKey:PARWUHTVGZSQPD-UHFFFAOYSA-N
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Compound Information
Molecular Weight:72.1057
Molecular Formula:C4H8O
InChIKey:WYURNTSHIVDZCO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:198.3019
Molecular Formula:C12H22O2
InChIKey:KISVAASFGZJBCY-UHFFFAOYSA-N
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Compound Information
Molecular Weight:368.5506
Molecular Formula:C22H40O4
InChIKey:WWPILJGBYYPNPS-ONEGZZNKSA-N
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Compound Information
Molecular Weight:28.0532
Molecular Formula:C2H4
InChIKey:Not Available
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Compound Information
Molecular Weight:136.315
Molecular Formula:Cl2Zn
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:41.0519
Molecular Formula:C2H3N
InChIKey:WEVYAHXRMPXWCK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:94.0699
Molecular Formula:CH6N2O3
InChIKey:AQLJVWUFPCUVLO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:120.1121
Molecular Formula:C5H4N4
InChIKey:KDCGOANMDULRCW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:168.1103
Molecular Formula:C5H4N4O3
InChIKey:YMQIDSRPVXAKBU-UHFFFAOYSA-N
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Compound Information
Molecular Weight:32.0419
Molecular Formula:CH4O
InChIKey:OKKJLVBELUTLKV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:154.557
Molecular Formula:C5H3ClN4
InChIKey:ZKBQDFAWXLTYKS-UHFFFAOYSA-N
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Compound Information
Molecular Weight:202.555
Molecular Formula:C5H3ClN4O3
InChIKey:WHEWUYGTWXIXGL-UHFFFAOYSA-N
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Compound Information
Molecular Weight:199.008
Molecular Formula:C5H3BrN4
InChIKey:CTGFGRDVWBZYNB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:247.006
Molecular Formula:C5H3BrN4O3
InChIKey:FZZXKYQAALYFOI-UHFFFAOYSA-N
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Compound Information
Molecular Weight:134.1386
Molecular Formula:C6H6N4
InChIKey:SYMHUEFSSMBHJA-UHFFFAOYSA-N
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Compound Information
Molecular Weight:182.1368
Molecular Formula:C6H6N4O3
InChIKey:AMOWFJZKOYQJRJ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:119.124
Molecular Formula:C6H5N3
InChIKey:JJTNLWSCFYERCK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:151.1228
Molecular Formula:C6H5N3O2
InChIKey:JSFGDGWRKQBYHA-UHFFFAOYSA-N
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Compound Information
Molecular Weight:153.569
Molecular Formula:C6H4ClN3
InChIKey:BPTCCCTWWAUJRK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:185.568
Molecular Formula:C6H4ClN3O2
InChIKey:MUBYJHIHNVYBEF-UHFFFAOYSA-N
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Compound Information
Molecular Weight:198.02
Molecular Formula:C6H4BrN3
InChIKey:ZFGUUMUJFWDZAB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:230.019
Molecular Formula:C6H4BrN3O2
InChIKey:JIVDZXAQEYOCIT-UHFFFAOYSA-N
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Compound Information
Molecular Weight:133.1506
Molecular Formula:C7H7N3
InChIKey:QWIAHMVNMONKCU-UHFFFAOYSA-N
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Compound Information
Molecular Weight:165.1494
Molecular Formula:C7H7N3O2
InChIKey:KWIMQIZDWCRITL-UHFFFAOYSA-N
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Compound Information
Molecular Weight:119.124
Molecular Formula:C6H5N3
InChIKey:UBOOKRVGOBKDMM-UHFFFAOYSA-N
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Compound Information
Molecular Weight:151.1228
Molecular Formula:C6H5N3O2
InChIKey:GOTJJCIRNYOAAG-UHFFFAOYSA-N
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Compound Information
Molecular Weight:153.569
Molecular Formula:C6H4ClN3
InChIKey:DHJMLXBBZRWBPW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:185.568
Molecular Formula:C6H4ClN3O2
InChIKey:ALIYPEKRYSNNDA-UHFFFAOYSA-N
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Compound Information
Molecular Weight:198.02
Molecular Formula:C6H4BrN3
InChIKey:BHRISABNDGCDRK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:230.019
Molecular Formula:C6H4BrN3O2
InChIKey:IFFNCLKCMRWWDO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:133.1506
Molecular Formula:C7H7N3
InChIKey:HEISWZKHISNNDA-UHFFFAOYSA-N
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Compound Information
Molecular Weight:165.1494
Molecular Formula:C7H7N3O2
InChIKey:BNPFLETUOAHGGX-UHFFFAOYSA-N
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Compound Information
Molecular Weight:118.1359
Molecular Formula:C7H6N2
InChIKey:SRSKXJVMVSSSHB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:134.1353
Molecular Formula:C7H6N2O
InChIKey:OSDNUIVEBSXLNJ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:152.581
Molecular Formula:C7H5ClN2
InChIKey:NGRAFQOJLPCUNE-UHFFFAOYSA-N
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Compound Information
Molecular Weight:168.58
Molecular Formula:C7H5ClN2O
InChIKey:AVICRYMTQDCUFQ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:197.032
Molecular Formula:C7H5BrN2
InChIKey:NSMUYOMTEILLCK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:213.031
Molecular Formula:C7H5BrN2O
InChIKey:KALRICLMHPIGLB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:132.1625
Molecular Formula:C8H8N2
InChIKey:QQBGXQSMYXJUFF-UHFFFAOYSA-N
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Compound Information
Molecular Weight:148.1619
Molecular Formula:C8H8N2O
InChIKey:HBKHCWYANVOWMR-UHFFFAOYSA-N
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Compound Information
Molecular Weight:119.124
Molecular Formula:C6H5N3
InChIKey:GAMYYCRTACQSBR-UHFFFAOYSA-N
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Compound Information
Molecular Weight:151.1228
Molecular Formula:C6H5N3O2
InChIKey:YCVFZEIVEKCRIX-UHFFFAOYSA-N
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Compound Information
Molecular Weight:153.569
Molecular Formula:C6H4ClN3
InChIKey:HAWCUEYFSQKISQ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:185.568
Molecular Formula:C6H4ClN3O2
InChIKey:OECHEDVCTUZZIO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:198.02
Molecular Formula:C6H4BrN3
InChIKey:DEFSPWZHYXXHLB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:230.019
Molecular Formula:C6H4BrN3O2
InChIKey:RECYDUYMPMGWIO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:133.1506
Molecular Formula:C7H7N3
InChIKey:BAEHKMMWUUIOJN-UHFFFAOYSA-N
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Compound Information
Molecular Weight:165.1494
Molecular Formula:C7H7N3O2
InChIKey:KKSXTGFQSIHRQB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:118.1359
Molecular Formula:C7H6N2
InChIKey:MVXVYAKCVDQRLW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:134.1353
Molecular Formula:C7H6N2O
InChIKey:ROGGVUMLTXEIDB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:152.581
Molecular Formula:C7H5ClN2
InChIKey:HNTZVGMWXCFCTA-UHFFFAOYSA-N
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Compound Information
Molecular Weight:168.58
Molecular Formula:C7H5ClN2O
InChIKey:BBEVKNOADIMMDC-UHFFFAOYSA-N
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Compound Information
Molecular Weight:197.032
Molecular Formula:C7H5BrN2
InChIKey:LEZHTYOQWQEBLH-UHFFFAOYSA-N
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Compound Information
Molecular Weight:213.031
Molecular Formula:C7H5BrN2O
InChIKey:HDXRRLLMIBHKSP-UHFFFAOYSA-N
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Compound Information
Molecular Weight:132.1625
Molecular Formula:C8H8N2
InChIKey:KEBIZMQVCXHCGN-UHFFFAOYSA-N
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Compound Information
Molecular Weight:148.1619
Molecular Formula:C8H8N2O
InChIKey:FYYJODCOZLYGJP-UHFFFAOYSA-N
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Compound Information
Molecular Weight:118.1359
Molecular Formula:C7H6N2
InChIKey:HYZJCKYKOHLVJF-UHFFFAOYSA-N
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Compound Information
Molecular Weight:134.1353
Molecular Formula:C7H6N2O
InChIKey:YCRFRHIZRKQEAG-UHFFFAOYSA-N
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Compound Information
Molecular Weight:152.581
Molecular Formula:C7H5ClN2
InChIKey:RPYPMOKNVPZWKZ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:168.58
Molecular Formula:C7H5ClN2O
InChIKey:MYYQPSQASJVXKX-UHFFFAOYSA-N
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Compound Information
Molecular Weight:197.032
Molecular Formula:C7H5BrN2
InChIKey:MUQFMGBYYAOIJK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:213.031
Molecular Formula:C7H5BrN2O
InChIKey:RZAZAVYAZUIGCU-UHFFFAOYSA-N
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Compound Information
Molecular Weight:132.1625
Molecular Formula:C8H8N2
InChIKey:QCXGJTGMGJOYDP-UHFFFAOYSA-N
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Compound Information
Molecular Weight:148.1619
Molecular Formula:C8H8N2O
InChIKey:DLTWGCSOBOEPHX-UHFFFAOYSA-N
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Compound Information
Molecular Weight:154.2493
Molecular Formula:C10H18O
InChIKey:YKFKEYKJGVSEIX-UHFFFAOYSA-N
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Compound Information
Molecular Weight:204.2634
Molecular Formula:C10H20O4
InChIKey:LWGYYSIEPWXJMS-UHFFFAOYSA-N
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Compound Information
Molecular Weight:374.5121
Molecular Formula:C20H38O6
InChIKey:ZQRZVHBHJPLIFK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:316.0158
Molecular Formula:C8H4F3IO2
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:330.0855
Molecular Formula:C10H10F3IO
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Molecular Weight:Not Available
Molecular Formula:Not Available
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Molecular Weight:Not Available
Molecular Formula:Not Available
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Molecular Weight:Not Available
Molecular Formula:Not Available
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Molecular Weight:Not Available
Molecular Formula:Not Available
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Molecular Weight:Not Available
Molecular Formula:Not Available
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Molecular Weight:Not Available
Molecular Formula:Not Available
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Molecular Weight:Not Available
Molecular Formula:Not Available
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Molecular Weight:Not Available
Molecular Formula:Not Available
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Molecular Weight:Not Available
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Molecular Weight:Not Available
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Molecular Weight:Not Available
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