Standard Article

Dicarbonyl(acetylacetonato) Rhodium (I)

  1. Michael J. Zacuto1,
  2. James L. Leighton1,
  3. Bernhard Breit2

Published Online: 16 SEP 2013

DOI: 10.1002/047084289X.rn00024.pub2

e-EROS Encyclopedia of Reagents for Organic Synthesis

e-EROS Encyclopedia of Reagents for Organic Synthesis

How to Cite

Zacuto, M. J., Leighton, J. L. and Breit, B. 2013. Dicarbonyl(acetylacetonato) Rhodium (I). e-EROS Encyclopedia of Reagents for Organic Synthesis. .

Author Information

  1. 1

    Columbia University, New York, NY, USA

  2. 2

    Albert-Ludwigs-Universität Freiburg, Germany

Publication History

  1. Published Online: 16 SEP 2013

Chemistry Terms

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Abstract

original image

[14874-82-9] C7H7O4Rh (MW 258.04)

(catalyst (precatalyst) for various carbonylation reactions, silylcarbocyclizations, conjugate additions to enones, carbamoylstannation, and reduction of aromatic nitro compounds)

Physical Data: mp 155 °C1; IR (CCl4) 2990, 2911, 1553, 1513, 1429, 1374, 1276, 1193, 1126, 1019, 933, 782 cm−1; 1H NMR (CCl4) δ 5.52 (1H), 2.11 (6H).

Solubility: soluble in acetone, benzene, chlorinated solvents; sparingly soluble in MeOH, ether, aliphatic hydrocarbons.

Form Supplied in: dark green crystalline solid; commercially available.

Analysis of Reagent Purity: NMR, IR, mp.

Preparative Methods: prepared from tetracarbonyl-μ-dichlorodirhodium(I).1

Purity: vacuum sublimation at ca. 90°C.1

Handling, Storage, and Precaution: stable in air; best stored in a dry atmosphere.

Featured Compounds

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  1. 1 - 91
Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:28.0101
Molecular Formula:CO
InChIKey:UGFAIRIUMAVXCW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:258.0336
Molecular Formula:C7H7O4Rh
InChIKey:BZCAWKOPWNIDOC-FGSKAQBVSA-M
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Compound Information
Molecular Weight:110.1537
Molecular Formula:C7H10O
InChIKey:NMZZBHNFBRLLRY-UHFFFAOYSA-N
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Compound Information
Molecular Weight:136.2664
Molecular Formula:C8H12Si
InChIKey:Not Available
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Compound Information
Molecular Weight:274.4302
Molecular Formula:C16H22O2Si
InChIKey:SZOYYDDAHSWDGP-FYWRMAATSA-N
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Compound Information
Molecular Weight:92.1384
Molecular Formula:C7H8
InChIKey:YXFVVABEGXRONW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:182.3348
Molecular Formula:C10H18OSi
InChIKey:UCCBCNCIFGEUEW-UWVGGRQHSA-N
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Compound Information
Molecular Weight:210.3449
Molecular Formula:C11H18O2Si
InChIKey:DNBJWJLNLCQPQL-VLFDAMPASA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
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Molecular Weight:Not Available
Molecular Formula:Not Available
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Molecular Weight:Not Available
Molecular Formula:Not Available
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Compound Information
Molecular Weight:78.1118
Molecular Formula:C6H6
InChIKey:UHOVQNZJYSORNB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:238.4411
Molecular Formula:C14H26OSi
InChIKey:WXVOHQDLQVTJEY-UONOGXRCSA-N
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Compound Information
Molecular Weight:216.3172
Molecular Formula:C12H24O3
InChIKey:PFSRWEONLNOQQM-FIQHERPVSA-N
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Compound Information
Molecular Weight:34.0147
Molecular Formula:H2O2
InChIKey:MHAJPDPJQMAIIY-UHFFFAOYSA-N
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Compound Information
Molecular Weight:84.0066
Molecular Formula:CHNaO3
InChIKey:UIIMBOGNXHQVGW-UHFFFAOYSA-M
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Compound Information
Molecular Weight:72.1057
Molecular Formula:C4H8O
InChIKey:WYURNTSHIVDZCO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:32.0419
Molecular Formula:CH4O
InChIKey:OKKJLVBELUTLKV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:448.5061
Molecular Formula:C24H32O8
InChIKey:ZRMZLSQYURCONC-BUHFOSPRSA-N
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Compound Information
Molecular Weight:584.7725
Molecular Formula:C32H44O8Si
InChIKey:AZYHAAHHDWGECQ-YMPLURJOSA-N
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Compound Information
Molecular Weight:336.4657
Molecular Formula:C20H32O4
InChIKey:IKTGGXCQMXIZLC-UHFFFAOYSA-N
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Compound Information
Molecular Weight:364.4758
Molecular Formula:C21H32O5
InChIKey:XSEVHMYCGPUUDB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:127.977
Molecular Formula:C6H13BO2
InChIKey:Not Available
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Compound Information
Molecular Weight:70.0898
Molecular Formula:C4H6O
InChIKey:FUSUHKVFWTUUBE-UHFFFAOYSA-N
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Compound Information
Molecular Weight:154.2493
Molecular Formula:C10H18O
InChIKey:QYPLUMNWWBFAJS-VOTSOKGWSA-N
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Compound Information
Molecular Weight:426.4694
Molecular Formula:C28H28P2
InChIKey:BCJVBDBJSMFBRW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:18.0153
Molecular Formula:H2O
InChIKey:XLYOFNOQVPJJNP-UHFFFAOYSA-N
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Compound Information
Molecular Weight:56.0633
Molecular Formula:C3H4O
InChIKey:HGINCPLSRVDWNT-UHFFFAOYSA-N
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Compound Information
Molecular Weight:142.1558
Molecular Formula:C6H10N2O2
InChIKey:QEMYUHVDLXABFU-UHFFFAOYSA-N
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Compound Information
Molecular Weight:198.2191
Molecular Formula:C9H14N2O3
InChIKey:SJVQLOXTVRANSY-SECBINFHSA-N
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Compound Information
Molecular Weight:82.1436
Molecular Formula:C6H10
InChIKey:CGHIBGNXEGJPQZ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:374.15
Molecular Formula:C16H33NOSn
InChIKey:UFRJHGBLPVTMDZ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:435.35
Molecular Formula:C12H23ClHgO2
InChIKey:VJVUHSOCQWXVQX-IREPQIBFSA-M
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Compound Information
Molecular Weight:228.3279
Molecular Formula:C13H24O3
InChIKey:NGFOWZABEXRSOU-NEPJUHHUSA-N
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Compound Information
Molecular Weight:478.6026
Molecular Formula:C30H39O3P
InChIKey:SZPHBONKPMLMCA-UHFFFAOYSA-N
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Compound Information
Molecular Weight:112.1729
Molecular Formula:C6H12N2
InChIKey:IMNIMPAHZVJRPE-UHFFFAOYSA-N
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Compound Information
Molecular Weight:88.1051
Molecular Formula:C4H8O2
InChIKey:XEKOWRVHYACXOJ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:279.2729
Molecular Formula:C17H14NOP
InChIKey:NSVQJDRZISUWOK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:476.974
Molecular Formula:C29H30ClO2P
InChIKey:VSXJJSJPVSBXJL-SKJXIIFASA-N
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Compound Information
Molecular Weight:507
Molecular Formula:C30H32ClO3P
InChIKey:WTELUTVWYVIPIS-FHMSPPRJSA-N
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Compound Information
Molecular Weight:507
Molecular Formula:C30H32ClO3P
InChIKey:WTELUTVWYVIPIS-WJAVYMJRSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
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Molecular Weight:Not Available
Molecular Formula:Not Available
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Compound Information
Molecular Weight:310.2837
Molecular Formula:C18H15O3P
InChIKey:HVLLSGMXQDNUAL-UHFFFAOYSA-N
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Compound Information
Molecular Weight:263.3752
Molecular Formula:C16H25NO2
InChIKey:LBISDCPXNBKNSN-RIGBYGSGSA-N
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Compound Information
Molecular Weight:200.2747
Molecular Formula:C11H20O3
InChIKey:NLISSOMWDJFLJZ-UJICNMFASA-N
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Compound Information
Molecular Weight:230.3007
Molecular Formula:C12H22O4
InChIKey:YPVSWYXKUHYOHK-PWSUYJOCSA-N
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Compound Information
Molecular Weight:1407.4882
Molecular Formula:C86H72N8O8P2
InChIKey:VCMAARGLPOOFGJ-DGFMTLLGSA-N
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Compound Information
Molecular Weight:212.2854
Molecular Formula:C12H20O3
InChIKey:KANOICQRSIXTJU-OJLMFNQTSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:349.3462
Molecular Formula:C19H17N4OP
InChIKey:YZPVOPZSMHSKBY-UHFFFAOYSA-O
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Compound Information
Molecular Weight:84.933
Molecular Formula:CH2Cl2
InChIKey:YMWUJEATGCHHMB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:315.2538
Molecular Formula:C17H12F2NOP
InChIKey:YFDJEPBCWJXXHZ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:396.3795
Molecular Formula:C20H21N4O3P
InChIKey:SBTFYMKGXJACMQ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:100.1589
Molecular Formula:C6H12O
InChIKey:JARKCYVAAOWBJS-UHFFFAOYSA-N
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Compound Information
Molecular Weight:121.93
Molecular Formula:C6H7BO2
InChIKey:HXITXNWTGFUOAU-UHFFFAOYSA-N
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Compound Information
Molecular Weight:178.2707
Molecular Formula:C12H18O
InChIKey:SVCRDVHXRDRHCP-UHFFFAOYSA-N
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Compound Information
Molecular Weight:1169.3661
Molecular Formula:C78H74O6P2
InChIKey:Not Available
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Compound Information
Molecular Weight:290.295
Molecular Formula:C13H10N2O4S
InChIKey:ONIWOLSJVJURJE-GXDHUFHOSA-N
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Compound Information
Molecular Weight:189.928
Molecular Formula:C7H6BF3O2
InChIKey:ALMFIOZYDASRRC-UHFFFAOYSA-N
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Compound Information
Molecular Weight:436.404
Molecular Formula:C20H15F3N2O4S
InChIKey:YYKKEQGTVAWODS-UHFFFAOYSA-N
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Compound Information
Molecular Weight:88.1051
Molecular Formula:C4H8O2
InChIKey:RYHBNJHYFVUHQT-UHFFFAOYSA-N
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Compound Information
Molecular Weight:160.2878
Molecular Formula:C10H12Si
InChIKey:SSEAMHJAEFEPPK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:216.351
Molecular Formula:C13H16OSi
InChIKey:WKPUJOWLFCOYBC-UHFFFAOYSA-N
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Compound Information
Molecular Weight:116.1598
Molecular Formula:C9H8
InChIKey:GHUURDQYRGVEHX-UHFFFAOYSA-N
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Compound Information
Molecular Weight:135.956
Molecular Formula:C7H9BO2
InChIKey:BIWQNIMLAISTBV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:208.2982
Molecular Formula:C16H16
InChIKey:MRCWYHVGXKPPLZ-WYMLVPIESA-N
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Compound Information
Molecular Weight:112.943
Molecular Formula:C2H2Cl2O
InChIKey:VGCXGMAHQTYDJK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:110.1968
Molecular Formula:C8H14
InChIKey:UMIPWJGWASORKV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:223.139
Molecular Formula:C10H16Cl2O
InChIKey:YSIDEOBOQLSUCE-CLFYSBASSA-N
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Compound Information
Molecular Weight:306.2333
Molecular Formula:C18H15As
InChIKey:Not Available
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Compound Information
Molecular Weight:178.2277
Molecular Formula:C11H14O2
InChIKey:ZVCQQLGWGRTXGC-UHFFFAOYSA-N
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Compound Information
Molecular Weight:111.1418
Molecular Formula:C6H9NO
InChIKey:WHNWPMSKXPGLAX-UHFFFAOYSA-N
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Compound Information
Molecular Weight:289.3694
Molecular Formula:C17H23NO3
InChIKey:WFPPKPQFQVWZIO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:316.2569
Molecular Formula:C18H12F3P
InChIKey:GEPJPYNDFSOARB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:212.2191
Molecular Formula:C14H9FO
InChIKey:CRGHUPHQJTXAAR-UHFFFAOYSA-N
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Compound Information
Molecular Weight:212.2191
Molecular Formula:C14H9FO
InChIKey:NNKOXOJYMOLKIP-UHFFFAOYSA-N
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Compound Information
Molecular Weight:622.6724
Molecular Formula:C44H32P2
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:189.641
Molecular Formula:C11H8ClN
InChIKey:WHXIEVDMCNQVOV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:136.1479
Molecular Formula:C8H8O2
InChIKey:ZRSNZINYAWTAHE-UHFFFAOYSA-N
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Compound Information
Molecular Weight:295.763
Molecular Formula:C18H14ClNO
InChIKey:YAZAGYMWTPPMHB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:401.885
Molecular Formula:C25H20ClNO2
InChIKey:HIGQJNLURVMHPJ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:146.2273
Molecular Formula:C8H18O2
InChIKey:Not Available
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Compound Information
Molecular Weight:112.557
Molecular Formula:C6H5Cl
InChIKey:MVPPADPHJFYWMZ-UHFFFAOYSA-N
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