Standard Article

FibreCat

  1. Thomas J. Colacot

Published Online: 15 SEP 2009

DOI: 10.1002/047084289X.rn00968

e-EROS Encyclopedia of Reagents for Organic Synthesis

e-EROS Encyclopedia of Reagents for Organic Synthesis

How to Cite

Colacot, T. J. 2009. FibreCat. e-EROS Encyclopedia of Reagents for Organic Synthesis. .

Author Information

  1. Johnson Matthey Catalysis and Technologies, West Deptford, NJ, USA

Publication History

  1. Published Online: 15 SEP 2009

Chemistry Terms

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Abstract

FibreCat (polypropylene-supported Pd-phosphine complexes)

(reagent used for carbon–carbon coupling reactions such as Suzuki, Heck, Sonogashira, α-arylation of ketones, etc)

Physical Data: needle-shaped fibers (2 mm length).

Solubility: insoluble in H2O, alcohol, ether, CH2Cl2, and most organic solvents.

Form Supplied in: yellow or brown and orange needles of 2 mm length.

Handling, Storage, and Precautions: air stable; however, strage is recommended under nitrogen for better shelf life. Catalysis should be conducted under inert conditions for better activity. Use mask while weighing the fibers.

Toxicity (oral) rat LD50: no data available; however, do not inhale or swallow due to metal and tertiary phosphine content.

Featured Compounds

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  1. 1 - 79
Compound Information
Molecular Weight:121.93
Molecular Formula:C6H7BO2
InChIKey:HXITXNWTGFUOAU-UHFFFAOYSA-N
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Compound Information
Molecular Weight:199.045
Molecular Formula:C8H7BrO
InChIKey:WYECURVXVYPVAT-UHFFFAOYSA-N
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Compound Information
Molecular Weight:196.2445
Molecular Formula:C14H12O
InChIKey:QCZZSANNLWPGEA-UHFFFAOYSA-N
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Compound Information
Molecular Weight:154.2078
Molecular Formula:C12H10
InChIKey:ZUOUZKKEUPVFJK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:224.51
Molecular Formula:C4H6O4Pd
InChIKey:YJVFFLUZDVXJQI-UHFFFAOYSA-L
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Compound Information
Molecular Weight:262.2855
Molecular Formula:C18H15P
InChIKey:RIOQSEWOXXDEQQ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:138.2055
Molecular Formula:CK2O3
InChIKey:BWHMMNNQKKPAPP-UHFFFAOYSA-L
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Compound Information
Molecular Weight:92.1384
Molecular Formula:C7H8
InChIKey:YXFVVABEGXRONW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:575
Molecular Formula:C34H28O2Pd
InChIKey:UKSZBOKPHAQOMP-SVLSSHOZSA-N
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Compound Information
Molecular Weight:365.89
Molecular Formula:C6H10Cl2Pd2
InChIKey:OTBRMLNJALKXGN-UHFFFAOYSA-L
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Compound Information
Molecular Weight:383.57
Molecular Formula:C14H10Cl2N2Pd
InChIKey:WXNOJTUTEXAZLD-UHFFFAOYSA-L
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Compound Information
Molecular Weight:259.43
Molecular Formula:C4H6Cl2N2Pd
InChIKey:RBYGDVHOECIAFC-UHFFFAOYSA-L
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:157.008
Molecular Formula:C6H5Br
InChIKey:QARVLSVVCXYDNA-UHFFFAOYSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:325.8198
Molecular Formula:CCs2O3
InChIKey:FJDQFPXHSGXQBY-UHFFFAOYSA-L
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Compound Information
Molecular Weight:73.0938
Molecular Formula:C3H7NO
InChIKey:ZMXDDKWLCZADIW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:180.2005
Molecular Formula:C10H12O3
InChIKey:IQZLUWLMQNGTIW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:332.3924
Molecular Formula:C22H20O3
InChIKey:OHSIVPFIKMZLGF-UHFFFAOYSA-N
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Compound Information
Molecular Weight:84.1595
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:202.3165
Molecular Formula:C12H27P
InChIKey:BWHDROKFUHTORW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:84.933
Molecular Formula:CH2Cl2
InChIKey:YMWUJEATGCHHMB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:222.3062
Molecular Formula:C14H23P
InChIKey:XOJNEFQLMRCOMS-UHFFFAOYSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:554.379
Molecular Formula:C34H28FeP2
InChIKey:ZIEQNLQJWACVCA-UHFFFAOYSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:622.6724
Molecular Formula:C44H32P2
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:265.374
Molecular Formula:C16H28NP
InChIKey:IQTHEAQKKVAXGV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:710.706
Molecular Formula:C48H47FeP
InChIKey:BXMSFGJSVVZFKL-UHFFFAOYSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:418.314
Molecular Formula:C22H36FeP2
InChIKey:XUUUHBFNNJSDAR-UHFFFAOYSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:187.034
Molecular Formula:C7H7BrO
InChIKey:QJPJQTDYNZXKQF-UHFFFAOYSA-N
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Compound Information
Molecular Weight:184.2338
Molecular Formula:C13H12O
InChIKey:RHDYQUZYHZWTCI-UHFFFAOYSA-N
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Compound Information
Molecular Weight:171.034
Molecular Formula:C7H7Br
InChIKey:QSSXJPIWXQTSIX-UHFFFAOYSA-N
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Compound Information
Molecular Weight:168.2344
Molecular Formula:C13H12
InChIKey:ALLIZEAXNXSFGD-UHFFFAOYSA-N
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Compound Information
Molecular Weight:53.0626
Molecular Formula:C3H3N
InChIKey:NLHHRLWOUZZQLW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:171.1953
Molecular Formula:C11H9NO
InChIKey:UEMPYFVSMFETOF-NSCUHMNNSA-N
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Compound Information
Molecular Weight:48.107
Molecular Formula:CH4S
InChIKey:LSDPWZHWYPCBBB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:99.1311
Molecular Formula:C5H9NO
InChIKey:SECXISVLQFMRJM-UHFFFAOYSA-N
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Compound Information
Molecular Weight:129.1586
Molecular Formula:C9H7N
InChIKey:ZWKNLRXFUTWSOY-QPJJXVBHSA-N
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Compound Information
Molecular Weight:128.169
Molecular Formula:C7H12O2
InChIKey:CQEYYJKEWSMYFG-UHFFFAOYSA-N
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Compound Information
Molecular Weight:204.2649
Molecular Formula:C13H16O2
InChIKey:OHHIVLJVBNCSHV-MDZDMXLPSA-N
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Compound Information
Molecular Weight:100.1158
Molecular Formula:C5H8O2
InChIKey:JIGUQPWFLRLWPJ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:218.2485
Molecular Formula:C13H14O3
InChIKey:ZENGWHBUYJFBQT-RMKNXTFCSA-N
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Compound Information
Molecular Weight:246.3016
Molecular Formula:C15H18O3
InChIKey:KXJMLIJUVXEVKQ-JXMROGBWSA-N
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Compound Information
Molecular Weight:234.2909
Molecular Formula:C14H18O3
InChIKey:QGHSAIVADXXKSX-JXMROGBWSA-N
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Compound Information
Molecular Weight:163.604
Molecular Formula:C9H6ClN
InChIKey:OFUFXTHGZWIDDB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:135.956
Molecular Formula:C7H9BO2
InChIKey:BIWQNIMLAISTBV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:219.2811
Molecular Formula:C16H13N
InChIKey:WOVRXMQYJDFRON-UHFFFAOYSA-N
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Compound Information
Molecular Weight:177.33
Molecular Formula:Cl2Pd
InChIKey:PIBWKRNGBLPSSY-UHFFFAOYSA-L
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Compound Information
Molecular Weight:146.939
Molecular Formula:C7H6BNO2
InChIKey:Not Available
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Compound Information
Molecular Weight:230.264
Molecular Formula:C16H10N2
InChIKey:FPNJMWIRQASAKW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:126.583
Molecular Formula:C7H7Cl
InChIKey:IBSQPLPBRSHTTG-UHFFFAOYSA-N
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Compound Information
Molecular Weight:274.3807
Molecular Formula:C18H27P
InChIKey:VPLLTGLLUHLIHA-UHFFFAOYSA-N
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Compound Information
Molecular Weight:126.583
Molecular Formula:C7H7Cl
InChIKey:Not Available
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Compound Information
Molecular Weight:168.2344
Molecular Formula:C13H12
InChIKey:ZZLCFHIKESPLTH-UHFFFAOYSA-N
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Compound Information
Molecular Weight:113.545
Molecular Formula:C5H4ClN
InChIKey:OKDGRDCXVWSXDC-UHFFFAOYSA-N
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Compound Information
Molecular Weight:155.1959
Molecular Formula:C11H9N
InChIKey:VQGHOUODWALEFC-UHFFFAOYSA-N
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Compound Information
Molecular Weight:154.637
Molecular Formula:C9H11Cl
InChIKey:WDZACGWEPQLKOM-UHFFFAOYSA-N
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Compound Information
Molecular Weight:196.2875
Molecular Formula:C15H16
InChIKey:CDKUYUULLQLNFF-UHFFFAOYSA-N
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Compound Information
Molecular Weight:154.594
Molecular Formula:C8H7ClO
InChIKey:BUZYGTVTZYSBCU-UHFFFAOYSA-N
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Compound Information
Molecular Weight:118.585
Molecular Formula:C4H3ClS
InChIKey:Not Available
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Compound Information
Molecular Weight:160.236
Molecular Formula:C10H8S
InChIKey:PJRGDKFLFAYRBV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:18.0153
Molecular Formula:H2O
InChIKey:XLYOFNOQVPJJNP-UHFFFAOYSA-N
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