Standard Article

Ruthenium hydroxide

  1. Deepak Bhattarai,
  2. Ju-hyeon Lee,
  3. Gyochang Keum

Published Online: 16 SEP 2013

DOI: 10.1002/047084289X.rn01593

e-EROS Encyclopedia of Reagents for Organic Synthesis

e-EROS Encyclopedia of Reagents for Organic Synthesis

How to Cite

Bhattarai, D., Lee, J.-h. and Keum, G. 2013. Ruthenium hydroxide. e-EROS Encyclopedia of Reagents for Organic Synthesis. .

Author Information

  1. Korea Institute of Science and Technology, Seoul, Korea

Publication History

  1. Published Online: 16 SEP 2013

Chemistry Terms

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Abstract

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(Ruthenium hydroxide)

[56321-86-9]] Ru(OH)x (MW 152.09)

InChI = 1S/H2O.Ru/h1H2;/q;+1/p-1

InChIKey = MHEUTMDANJLPBI-UHFFFAOYSA-M

(green, reusable, and heterogeneous catalyst for various oxidation, hydrogen transfer, and hydration reactions)

Alternate Names: Ru(OH)x/support [supports: alumina (Al2O3), silica gel (SiO2), titania/anatase (TiO2), magnetite (Fe3O4), ceria (CeO2), and spinel (MgAl2O4)]; [12135-42-1]ruthenium hydroxide, ruthenium trihydroxide Ru(OH)3, Ru(OH)3·nH2O.

Physical Data: dark green powder; bp 100 °C at 760 mmHg; ESR: g = 2.11 (Ru3+); IR: v(OH) 2900∼3700 cm−1.

Solubility: insoluble in most solvents.

Preparative Method: Ru(OH)x/support catalysts can be prepared by the immobilization of RuCl3(or RuCl3·nH2O) on support (Al2O3,1 TiO2,2 Fe3O43)4 in aqueous medium, and subsequent treatment with NaOH (1 M) until the pH is around 13. The mixture is stirred for 1 day, filtered, washed with water, and dried in vacuo. Ru(OH)3 is easily prepared as a black precipitate by adding a slight excess of a sodium hydroxide solution to a hot aqueous solution of ruthenium chloride (RuCl3).5

Featured Compounds

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  1. 1 - 62
Compound Information
Molecular Weight:152.09
Molecular Formula:H3O3Ru
InChIKey:IQPWDKBDQYZOLH-UHFFFAOYSA-K
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Compound Information
Molecular Weight:108.1378
Molecular Formula:C7H8O
InChIKey:WVDDGKGOMKODPV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:106.1219
Molecular Formula:C7H6O
InChIKey:HUMNYLRZRPPJDN-UHFFFAOYSA-N
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Compound Information
Molecular Weight:146.1098
Molecular Formula:C7H5F3
InChIKey:GETTZEONDQJALK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:122.1644
Molecular Formula:C8H10O
InChIKey:WAPNOHKVXSQRPX-UHFFFAOYSA-N
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Compound Information
Molecular Weight:120.1485
Molecular Formula:C8H8O
InChIKey:KWOLFJPFCHCOCG-UHFFFAOYSA-N
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Compound Information
Molecular Weight:92.1384
Molecular Formula:C7H8
InChIKey:YXFVVABEGXRONW-UHFFFAOYSA-N
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Compound Information
Molecular Weight:134.1751
Molecular Formula:C9H10O
InChIKey:OOCCDEMITAIZTP-QPJJXVBHSA-N
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Compound Information
Molecular Weight:132.1592
Molecular Formula:C9H8O
InChIKey:KJPRLNWUNMBNBZ-QPJJXVBHSA-N
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Compound Information
Molecular Weight:130.2279
Molecular Formula:C8H18O
InChIKey:Not Available
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Compound Information
Molecular Weight:128.212
Molecular Formula:C8H16O
InChIKey:ZPVFWPFBNIEHGJ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:109.1259
Molecular Formula:C6H7NO
InChIKey:MVQVNTPHUGQQHK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:107.11
Molecular Formula:C6H5NO
InChIKey:Not Available
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Compound Information
Molecular Weight:138.1638
Molecular Formula:C8H10O2
InChIKey:PWMWNFMRSKOCEY-UHFFFAOYSA-N
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Compound Information
Molecular Weight:46.0684
Molecular Formula:C2H6O
InChIKey:LFQSCWFLJHTTHZ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:60.052
Molecular Formula:C2H4O2
InChIKey:QTBSBXVTEAMEQO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:116.1583
Molecular Formula:C6H12O2
InChIKey:PFURGBBHAOXLIO-PHDIDXHHSA-N
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Compound Information
Molecular Weight:146.1412
Molecular Formula:C6H10O4
InChIKey:WNLRTRBMVRJNCN-UHFFFAOYSA-N
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Compound Information
Molecular Weight:39.9971
Molecular Formula:HNaO
InChIKey:HEMHJVSKTPXQMS-UHFFFAOYSA-M
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Compound Information
Molecular Weight:18.0153
Molecular Formula:H2O
InChIKey:XLYOFNOQVPJJNP-UHFFFAOYSA-N
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Compound Information
Molecular Weight:126.11
Molecular Formula:C6H6O3
InChIKey:Not Available
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Compound Information
Molecular Weight:156.093
Molecular Formula:C6H4O5
InChIKey:CHTHALBTIRVDBM-UHFFFAOYSA-N
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Compound Information
Molecular Weight:103.1213
Molecular Formula:C7H5N
InChIKey:JFDZBHWFFUWGJE-UHFFFAOYSA-N
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Compound Information
Molecular Weight:121.1366
Molecular Formula:C7H7NO
InChIKey:KXDAEFPNCMNJSK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:129.1586
Molecular Formula:C9H7N
InChIKey:ZWKNLRXFUTWSOY-QPJJXVBHSA-N
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Compound Information
Molecular Weight:147.1739
Molecular Formula:C9H9NO
InChIKey:APEJMQOBVMLION-VOTSOKGWSA-N
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Compound Information
Molecular Weight:107.1531
Molecular Formula:C7H9N
InChIKey:WGQKYBSKWIADBV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:197.2756
Molecular Formula:C14H15N
InChIKey:Not Available
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Compound Information
Molecular Weight:195.2597
Molecular Formula:C14H13N
InChIKey:MIYKHJXFICMPOJ-RVDMUPIBSA-N
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Compound Information
Molecular Weight:119.1638
Molecular Formula:C8H9N
InChIKey:LPAGFVYQRIESJQ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:117.1479
Molecular Formula:C8H7N
InChIKey:SIKJAQJRHWYJAI-UHFFFAOYSA-N
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Compound Information
Molecular Weight:17.0305
Molecular Formula:H3N
InChIKey:QGZKDVFQNNGYKY-UHFFFAOYSA-N
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Compound Information
Molecular Weight:72.1057
Molecular Formula:C4H8O
InChIKey:WYURNTSHIVDZCO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:128.212
Molecular Formula:C8H16O
InChIKey:NUJGJRNETVAIRJ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:125.2114
Molecular Formula:C8H15N
InChIKey:YSIMAPNUZAVQER-UHFFFAOYSA-N
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Compound Information
Molecular Weight:93.1265
Molecular Formula:C6H7N
InChIKey:PAYRUJLWNCNPSJ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:183.249
Molecular Formula:C13H13N
InChIKey:Not Available
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Compound Information
Molecular Weight:120.1916
Molecular Formula:C9H12
InChIKey:AUHZEENZYGFFBQ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:181.2331
Molecular Formula:C13H11N
InChIKey:UVEWQKMPXAHFST-SDNWHVSQSA-N
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Compound Information
Molecular Weight:56.1056
Molecular Formula:HKO
InChIKey:KWYUFKZDYYNOTN-UHFFFAOYSA-M
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Compound Information
Molecular Weight:287.3981
Molecular Formula:C21H21N
InChIKey:MXHTZQSKTCCMFG-UHFFFAOYSA-N
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Compound Information
Molecular Weight:60.0553
Molecular Formula:CH4N2O
InChIKey:XSQUKJJJFZCRTK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:225.3288
Molecular Formula:C16H19N
InChIKey:NXLACVVNHYIYJN-UHFFFAOYSA-N
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Compound Information
Molecular Weight:122.1644
Molecular Formula:C8H10O
InChIKey:WAPNOHKVXSQRPX-SSDOTTSWSA-N
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Compound Information
Molecular Weight:60.095
Molecular Formula:C3H8O
InChIKey:KFZMGEQAYNKOFK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:154.2493
Molecular Formula:C10H18O
InChIKey:NEHNMFOYXAPHSD-SNVBAGLBSA-N
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Compound Information
Molecular Weight:156.2652
Molecular Formula:C10H20O
InChIKey:QMVPMAAFGQKVCJ-SNVBAGLBSA-N
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Compound Information
Molecular Weight:128.212
Molecular Formula:C8H16O
InChIKey:VSMOENVRRABVKN-UHFFFAOYSA-N
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Compound Information
Molecular Weight:130.2279
Molecular Formula:C8H18O
InChIKey:NMRPBPVERJPACX-UHFFFAOYSA-N
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Compound Information
Molecular Weight:86.1323
Molecular Formula:C5H10O
InChIKey:VHVMXWZXFBOANQ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:86.1323
Molecular Formula:C5H10O
InChIKey:FDPIMTJIUBPUKL-UHFFFAOYSA-N
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Compound Information
Molecular Weight:44.0095
Molecular Formula:CO2
InChIKey:Not Available
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Compound Information
Molecular Weight:2.01588
Molecular Formula:H2
InChIKey:UFHFLCQGNIYNRP-UHFFFAOYSA-N
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Compound Information
Molecular Weight:46.0254
Molecular Formula:CH2O2
InChIKey:BDAGIHXWWSANSR-UHFFFAOYSA-N
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Compound Information
Molecular Weight:101.19
Molecular Formula:C6H15N
InChIKey:ZMANZCXQSJIPKH-UHFFFAOYSA-N
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Compound Information
Molecular Weight:133.1506
Molecular Formula:C7H7N3
InChIKey:UDLLFLQFQMACJB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:166.1341
Molecular Formula:C7H6N2O3
InChIKey:WTLPAVBACRIHHC-VMPITWQZSA-N
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Compound Information
Molecular Weight:166.1341
Molecular Formula:C7H6N2O3
InChIKey:Not Available
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Compound Information
Molecular Weight:182.2179
Molecular Formula:C13H10O
InChIKey:GJCOSYZMQJWQCA-UHFFFAOYSA-N
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Compound Information
Molecular Weight:196.2014
Molecular Formula:C13H8O2
InChIKey:JNELGWHKGNBSMD-UHFFFAOYSA-N
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Compound Information
Molecular Weight:144.1699
Molecular Formula:C10H8O
InChIKey:JWAZRIHNYRIHIV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:286.324
Molecular Formula:C20H14O2
InChIKey:PPTXVXKCQZKFBN-UHFFFAOYSA-N
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