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Tetrabutylammonium peroxydisulfate

  1. Ju-hyeon Lee,
  2. Deepak Bhattarai,
  3. Gyochang Keum

Published Online: 16 SEP 2013

DOI: 10.1002/047084289X.rn01594

e-EROS Encyclopedia of Reagents for Organic Synthesis

e-EROS Encyclopedia of Reagents for Organic Synthesis

How to Cite

Lee, J.-h., Bhattarai, D. and Keum, G. 2013. Tetrabutylammonium peroxydisulfate. e-EROS Encyclopedia of Reagents for Organic Synthesis.

Author Information

  1. Korea Institute of Science and Technology, Seoul, Korea

Publication History

  1. Published Online: 16 SEP 2013

Chemistry Terms

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Abstract

(Tetrabutylammonium peroxydisulfate)

original image

[88505-29-7] C32H72N2O8S2 (MW 434.59)

Alternate Names: (n-Bu4N)2S2O8; (TBA)2S2O8; bis(N,N,N-tributyl-1-butanaminium) peroxydisulfate; bis(tetrabutylammonium) peroxydisulfate; tetrabutylammonium persulfate; N,N,N-tributyl-1-butanaminium salt with peroxydisulfuric acid ([(HO)SO2]2O2) (2:1).

(a radical oxidizing agent for a variety of functional group transformations)

Physical Data: mp 118-120°C(dec).

Solubility: easily soluble in various organic solvents such as dichloromethane, chloroform, acetonitrile, acetone, and methanol in contrast to the poor solubility of known metal peroxydisulfates.

Form Supplied in: white solid.

Preparative Method: commercially available, but it is easily prepared by simple extraction of an aqueous solution of potassium peroxydisulfate and 2 equiv of tertabutylammonium hydrogensulfate1, 2 or metathesis reaction between tetrabutylammonium hydroxide (TBAOH, 1.0 M solution in methanol) and aqueous (NH4)2S2O8.3

Handling, storage, and precautions: stable for several months at room temperature, and can be stored in refrigerator permanently.2

Featured Compounds

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  1. 1 - 63
Compound Information
Molecular Weight:677.053
Molecular Formula:C32H72N2O8S2
InChIKey:Not Available
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Compound Information
Molecular Weight:154.2493
Molecular Formula:C10H18O
InChIKey:GLZPCOQZEFWAFX-JXMROGBWSA-N
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Compound Information
Molecular Weight:152.2334
Molecular Formula:C10H16O
InChIKey:Not Available
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Compound Information
Molecular Weight:78.1118
Molecular Formula:C6H6
InChIKey:UHOVQNZJYSORNB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:122.1644
Molecular Formula:C8H10O
InChIKey:WAPNOHKVXSQRPX-UHFFFAOYSA-N
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Compound Information
Molecular Weight:120.1485
Molecular Formula:C8H8O
InChIKey:KWOLFJPFCHCOCG-UHFFFAOYSA-N
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Compound Information
Molecular Weight:138.1638
Molecular Formula:C8H10O2
InChIKey:MSHFRERJPWKJFX-UHFFFAOYSA-N
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Compound Information
Molecular Weight:133.1473
Molecular Formula:C8H7NO
InChIKey:XDJAAZYHCCRJOK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:79.0553
Molecular Formula:CH5NO3
InChIKey:ATRRKUHOCOJYRX-UHFFFAOYSA-N
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Compound Information
Molecular Weight:302.309
Molecular Formula:C4H4CuNiO8
InChIKey:XZDBFTMNRWRTIQ-UHFFFAOYSA-J
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Compound Information
Molecular Weight:56.1056
Molecular Formula:HKO
InChIKey:KWYUFKZDYYNOTN-UHFFFAOYSA-M
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Compound Information
Molecular Weight:60.095
Molecular Formula:C3H8O
InChIKey:KFZMGEQAYNKOFK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:157.2117
Molecular Formula:C11H11N
InChIKey:XBCAHQUVHHVHHL-UHFFFAOYSA-N
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Compound Information
Molecular Weight:153.18
Molecular Formula:C11H7N
InChIKey:AZKDTTQQTKDXLH-UHFFFAOYSA-N
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Compound Information
Molecular Weight:98.959
Molecular Formula:C2H4Cl2
InChIKey:WSLDOOZREJYCGB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:122.1644
Molecular Formula:C8H10O
InChIKey:Not Available
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Compound Information
Molecular Weight:72.1057
Molecular Formula:C4H8O
InChIKey:WYURNTSHIVDZCO-UHFFFAOYSA-N
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Compound Information
Molecular Weight:192.2542
Molecular Formula:C12H16O2
InChIKey:SUSZBTYLNKEGSB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:140.1797
Molecular Formula:C8H12O2
InChIKey:BADXJIPKFRBFOT-UHFFFAOYSA-N
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Compound Information
Molecular Weight:70.0898
Molecular Formula:C4H6O
InChIKey:JKTCBAGSMQIFNL-UHFFFAOYSA-N
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Compound Information
Molecular Weight:208.2536
Molecular Formula:C12H16O3
InChIKey:WUCGEKAFWRSDOV-WRWORJQWSA-N
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Compound Information
Molecular Weight:98.1423
Molecular Formula:C2H3KO2
InChIKey:Not Available
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Compound Information
Molecular Weight:41.0519
Molecular Formula:C2H3N
InChIKey:WEVYAHXRMPXWCK-UHFFFAOYSA-N
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Compound Information
Molecular Weight:100.1158
Molecular Formula:C5H8O2
InChIKey:MCVVUJPXSBQTRZ-ONEGZZNKSA-N
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Compound Information
Molecular Weight:74.0785
Molecular Formula:C3H6O2
InChIKey:Not Available
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Compound Information
Molecular Weight:174.1944
Molecular Formula:C8H14O4
InChIKey:SKTNFEGIQCIBFC-UHFFFAOYSA-N
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Compound Information
Molecular Weight:196.3291
Molecular Formula:C13H24O
InChIKey:YZDYYQPSQUPRTL-XQQFMLRXSA-N
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Compound Information
Molecular Weight:156.2652
Molecular Formula:C10H20O
InChIKey:NOOLISFMXDJSKH-AEJSXWLSSA-N
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Compound Information
Molecular Weight:56.0633
Molecular Formula:C3H4O
InChIKey:HGINCPLSRVDWNT-UHFFFAOYSA-N
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Compound Information
Molecular Weight:253.80894
Molecular Formula:I2
InChIKey:PNDPGZBMCMUPRI-UHFFFAOYSA-N
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Compound Information
Molecular Weight:18.0153
Molecular Formula:H2O
InChIKey:XLYOFNOQVPJJNP-UHFFFAOYSA-N
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Compound Information
Molecular Weight:586.6317
Molecular Formula:C33H34N2O8
InChIKey:GEFPOYHSZVWVLQ-PYYPWFDZSA-N
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Compound Information
Molecular Weight:284.2652
Molecular Formula:C12H16N2O6
InChIKey:GFDUSNQQMOENLR-PEBGCTIMSA-N
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Compound Information
Molecular Weight:240.3419
Molecular Formula:C13H24N2O2
InChIKey:WVWUDPHPBCXCJP-OWBHPGMISA-N
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Compound Information
Molecular Weight:198.2588
Molecular Formula:C11H18O3
InChIKey:DGHKWIILTIIWPB-UHFFFAOYSA-N
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Compound Information
Molecular Weight:146.1858
Molecular Formula:C10H10O
InChIKey:BWHOZHOGCMHOBV-BQYQJAHWSA-N
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Compound Information
Molecular Weight:162.1852
Molecular Formula:C10H10O2
InChIKey:IGCQIHCZUYCYAA-UHFFFAOYSA-N
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Compound Information
Molecular Weight:34.0147
Molecular Formula:H2O2
InChIKey:MHAJPDPJQMAIIY-UHFFFAOYSA-N
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Compound Information
Molecular Weight:39.9971
Molecular Formula:HNaO
InChIKey:HEMHJVSKTPXQMS-UHFFFAOYSA-M
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Compound Information
Molecular Weight:32.0419
Molecular Formula:CH4O
InChIKey:OKKJLVBELUTLKV-UHFFFAOYSA-N
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Compound Information
Molecular Weight:138.1638
Molecular Formula:C8H10O2
InChIKey:DPZNOMCNRMUKPS-UHFFFAOYSA-N
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Compound Information
Molecular Weight:264.0603
Molecular Formula:C8H9IO2
InChIKey:ZDUYJCKEORTAQE-UHFFFAOYSA-N
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Compound Information
Molecular Weight:96.1271
Molecular Formula:C6H8O
InChIKey:FWFSEYBSWVRWGL-UHFFFAOYSA-N
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Compound Information
Molecular Weight:222.0237
Molecular Formula:C6H7IO
InChIKey:IPFSJCDRYRZTJU-UHFFFAOYSA-N
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Compound Information
Molecular Weight:82.1005
Molecular Formula:C5H6O
InChIKey:Not Available
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Compound Information
Molecular Weight:207.9971
Molecular Formula:C5H5IO
InChIKey:IMUSDFZITNOTLJ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:112.0868
Molecular Formula:C4H4N2O2
InChIKey:ISAKRJDGNUQOIC-UHFFFAOYSA-N
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Compound Information
Molecular Weight:237.9833
Molecular Formula:C4H3IN2O2
InChIKey:KSNXJLQDQOIRIP-UHFFFAOYSA-N
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:Not Available
Molecular Formula:Not Available
InChIKey:Not Available
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Compound Information
Molecular Weight:272.0823
Molecular Formula:C10H9IO
InChIKey:NKKMVOMFNGBDFU-VOTSOKGWSA-N
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Compound Information
Molecular Weight:329.3902
Molecular Formula:C19H23NO4
InChIKey:VQZSDRXKLXBRHJ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:327.3743
Molecular Formula:C19H21NO4
InChIKey:VQDKSJMDSZZJER-UHFFFAOYSA-N
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Compound Information
Molecular Weight:101.9613
Molecular Formula:Al2O3
InChIKey:TWNQGVIAIRXVLR-UHFFFAOYSA-N
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Compound Information
Molecular Weight:321.3731
Molecular Formula:C19H19N3O2
InChIKey:RXFQNYICSYIWBZ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:319.3572
Molecular Formula:C19H17N3O2
InChIKey:IMDIJJJZEUCNTN-UHFFFAOYSA-N
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Compound Information
Molecular Weight:154.186
Molecular Formula:C7H6O2S
InChIKey:NBOMNTLFRHMDEZ-UHFFFAOYSA-N
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Compound Information
Molecular Weight:306.357
Molecular Formula:C14H10O4S2
InChIKey:LBEMXJWGHIEXRA-UHFFFAOYSA-N
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Compound Information
Molecular Weight:350.451
Molecular Formula:C14H22O6S2
InChIKey:ABYFQWZWTAVGKO-KAMPLNKDSA-N
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Compound Information
Molecular Weight:244.2842
Molecular Formula:C12H20O5
InChIKey:AKKRBVFGAWFTRW-SGIHWFKDSA-N
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Compound Information
Molecular Weight:68.0072
Molecular Formula:CHNaO2
InChIKey:Not Available
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Compound Information
Molecular Weight:105.9884
Molecular Formula:CNa2O3
InChIKey:CDBYLPFSWZWCQE-UHFFFAOYSA-L
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Compound Information
Molecular Weight:73.0938
Molecular Formula:C3H7NO
InChIKey:ZMXDDKWLCZADIW-UHFFFAOYSA-N
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